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What structures for myrcene are consistent with the facts

Discussion:

Ozonolysis of Myrcene

Myrcene, C₁₀H1_6, a terpene, absorbs three moles of hydrogen to form C₁₀H₂₂. Upon ozonolysis myrcene yields the two compounds shown in the first attached

313_Mycrene yields.JPG

1. What structures for myrcene are consistent with the facts?

2. Based on the isoprene rule (naturally occurring terpenes are made up of isoprene segments) what is the most likely structurefor myrcene?

Dihydromyrcene C₁₀H₁₈, formed from myrcene absorbs 2 moles of hydrogen to form C₁₀H₂₂. Upon cleavage with KMnO₄, dihydromyrcene yields the structures showin in.

855_dihydromyrcene yields.JPG

3. Keeping in mind the isoprene rule what is the most likely structure for dihydromyrcene?

4. Is it surprising that a compound of this structure is formed by reduction of myrcene? Explain

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