1. The work function of potassium is 3.68 x 10-19 J.
a. What is the minimum frequency of light needed to eject electrons from the metal?
b. Calculate the kinetic energy of the ejected electrons when light of frequency equal to 8.62 x 1014 s-1 is used for irradiation.
2. Thermal neutrons are neutrons that move at speeds comparable to those of air molecules at room temperature. These neutrons are most effective in initiating a nuclear chain reaction among 235U isotopes. Calculate the wavelength (in nm) associated with a beam of neutrons moving at 7.00 x 102 m/s (mass of neutron = 1.675 x 10-27 kg)
3. The blue color of the sky results from the scattering of sunlight by air molecules. The blue light has a frequency of about 7.5 x 1014 Hz.
a. Calculate the wavelength. in nm. associated with this radiation
b. Calculate the energy, in joules, of a single photon associated with this freauency
4. When an intense beam of green light is directed onto a copper surface, no electrons are ejected. What will happen if the green light is replaced with red light?
5. The velocity of an electron that is emitted from a metallic surface by a photon is 3.6 x 103 km.s-1. What is the wavelength of the ejected electron?
6. Alarm systems employ the photoelectric effect. Typically, a light beam is aimed at a sample of Na, producing a photoelectric current. An intruder blocks the beam, thereby turning off the current, and triggering the alarm. Given that the work function of Na is 4.41 x 10-19 J particle-1, what is the longest wavelength of light (in nm) that can be used in the alarm system?
7. A certain cation Xn+ has an electron configuration of [Ar]3d5. Answer the following:
a) What type of element is X?
b) The reaction of X with chlorine gas proceeds as following:
2X(s) + 3Cl2(g) -> 2XCl3(s)
Given this, determine n+
c) Now that you know the charge of the cation, determine the identity of X.
8. Draw the lewis dot structure give the molecular shape
Moleule
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Lewis structure
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Electronic geometry
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Molecular geometry (shape)
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SeH2
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9. Give the full ground state electron configuration and the abbreviated noble gas) configuration for the following elements and or ions:
a) C
b) Se2+
c) Fe
d) P
e) Tc
f) Cr
g) Cu
h) Ho
g) Cr+
h) CI-
10. Which of the following combinations of quantum numbers are allowed for an electron? Which are not? What would you change to make the ones that are not possible be possible?
a n=2 /=2 mi=1 ms =1/2
b. n=3 1=1 mi=0 ms =-1/2
c. n=5 1=1 mi=2 ms =1/2
d. n=4 /=-1 mi=0 ms =1/2
11. Label the orbital described by each of the following sets of quantum numbers
a. n=4 1=1 4 orbital_________
b. n=2 1=04 orbital_______
c. n=6 1=34 orbital_______
d. n=51=24 orbital
12. What are the principal (n) and orbital angular momentum (1) for each of the following:
a. 6p n = l =
b. 3d n = l =
c. 2p n = l =
d. 5 f n = l =
e. 2 s n = l =
f. 6 f n = l =
g. 4 d n = l =
h. 5 p n = l =
13. How many electrons can have the following quantum numbers in an atom:
a. n = 2,1=1
b. n = 5,1=3, m1=-1
c. n = 2,1=1, mi=0
d. n = 7
14. The 3 quantum numbers for an electron in a hydrogen atom in a certain state are n=4, 1=2, The electron is located in what type of orbital?