What is the justification for not using eigenfunctions, Physics

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What is the justification for not using eigenfunctions

In studying the residual Coulomb interaction, eigenfunctions are used which are antisymmetric with respect to exchange of the labels of pairs of optically active electrons. What is the justification for not using eigenfunctions which are antisymmetric with respect to the exchange of labels for any pair of electrons in the atom?

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Physics: What is the justification for not using eigenfunctions

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