A 0.003525-mol sample of an organic compound was burned in oxygen in a bomb calorimeter. The temperature of the calorimeter increased from 24.5oC to 26.7oC. If the heat capacity of the calorimeter is 4.46 kJ (oC)-1, then what is the constant volume heat of combustion of this compound, in kilojoules per mole? (Remember to include a "+" or "-" sign in your answer, as appropriate.)