Question: The Lennard-Jones model predicts the potential energy V (r) of a two-atom molecule as a function of the distance r between the atoms to be
V(r) = (A/r12) - (B/r6), r > 0
where A and B are positive constants.
(a) Evaluate limr→0+ V (r), and interpret your answer.
(b) Find the critical point of V (r). Is it a local maximum or local minimum?
(c) The inter-atomic force is given by F(r) = -V'(r). At what distance r is the inter-atomic force zero? (This is called the equilibrium size of the molecule.)
(d) Describe how the parameters A and B affect the equilibrium size of the molecule.