Problem on aromatics and grignards


Assignment:

Q1. Give the structures of all possible products when 3-bromopentane reacts by the E2 mechanism.

Q2. Ethers and alcohols can be isomeric. Write the structures, and give names for all possible isomers with the molecular formula C4H10O.

Q3. Using a Grignard reagent and the appropriate aldehyde or ketone, show how each of the following can be prepared.
a. 2-pentanol                          b. 3-phenyl-3-hexanol

Q4. Give the structure of each product

a.

645_pairs of acids.JPG

b. CH3CH2CH2CH2OH
Jones’
 →
Reagent

c. 2-butanone + HCN

Q5. In each of the following pairs of acids, which would be expected to be stronger, and why?

a. p-BrC6H4CO2H or       m-BrC6H4CO2H
b. b. CH3CH2CHBrCO2H orCH2BrCH2CH2CO2H

Q6. Write out all the steps in the mechanism for ammonolysis of butyl benzoate.

Q7. Complete the following equations.

1272_dimethylamine.JPG

 Q8. Tell which is the stronger base and why: ammonia or dimethylamine?

Provide complete and step by step solution for the question and show calculations and use formulas.

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Chemistry: Problem on aromatics and grignards
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