Response to the following problem:
(a) A measure of the result of an adiabatic Joule free expansion is provided by the louie coefficient η = (∂T/∂V)U .
Show that η = - (1/CV) ((βT/k) - P) .
(b) A measure of the result of the Joule-Thomson expansion (adiabatic throttling process or isenthalpic expansion) is provided by the Joule- Thomson coefficient η = (∂T/∂P)H .
Show that η = - V/CP (βT - 1) .