In a purity check for industrial diamonds, a 11.25 carat (1 carat = 0.2000 g) diamond is heated to 74.21°C and immersed in 27.30 g of water in a constant-pressure calorimeter. The initial temperature of the water is 27.20°C. Calculate ?T of the water and of the diamond (cdiamond = 0.519 J/g·K).
Twater _____ K
Tdiamond ______ K