Questions:
1. Consider the following data: expect a BeF2 molecule to be linear but an SF2 molecule to be angular.
Solubility in Water Melting
(kg/kg H2O, 25oC) Point (oC)
NaF 0.042 988
NaCl 0.357 801
NaBr 1.16 755
Nai 1.84 651
a) Explain the decreasing melting point from NaF to Nai.
b) Explain the increasing solubility in the same order.
c) Cesium fluoride has a melting point of 682oC and a solubility of 3.67 kg/kg H2O at 25oC. Explain the difference between the properties of CsF and NaF.
2. What test would determine whether a solid substance contains ionic bonds?
3. a) Explain why graphite is soft and has a high melting point.
b) Explain why diamond is hard and has a high melting point.
c) Why is diamond a poor conductor of an electric current and graphite a good conductor?
4. Answer the following questions using the information in the table.
Element
|
Melting point (°C)
|
Boiling point (°C)
|
Molar volume at STP (L)
|
A
|
-189
|
-186
|
22.4
|
B
|
-100
|
-35
|
22.4
|
C
|
-7
|
58
|
2.6 x 10-2
|
D
|
30
|
2240
|
1.2 x 10-2
|
E
|
44
|
280
|
1.7 x 10-2
|
F
|
660
|
2450
|
1.0 x 10-2
|
G
|
3410
|
5930
|
1.0 x 10-2
|
a) Which elements are likely to be metals?
b) Which elements are gases at STP?
c) Which element is most likely to be a non-metallic solid?
d) Which elements are likely to conduct well in the solid form?