Problem 1: Draw the following molecules and indicate if they are chiral and circle the tetrahedral stereo-centers.
a. Methylcylcohexane
b. 2-Methylcyclohexanone
c. 5-Bromodecane
d. 2-amino-3-hydroxybutanoic acid
e. 4-Methyl-1-hexene
Problem 2: Label the following as aldohexose, aldopentose, ketopentose, ketohexose, etc
Problem 3: Draw all the stereo-isomers for 2a. as enantiomeric pairs.
Problem 4: Given the Fisher projection of the carbohydrates (shown below), draw both the alpha and beta anomers for the corresponding Haworth projections.
Problem 5: Draw the corresponding Fisher projection and indicate if the compound is D or L. (Hint: assumes the -OH group at carbon 5 on the fisher projection forms the bond with carbon 1 observed on the Haworth projection).
Problem 6: For the following carbohydrate molecules, determine if they are α or β (and circle the OH group in question).
Problem 7: Consider the following polysaccharide:
a) What is the linkage between each sugar unit?
b) Hydrolysis is the process of converting polysaccharides into its monosaccharides. Draw the products upon hydrolysis?
Problem 8: Consider the following polysaccharide:
a) What is the linkage between each sugar unit?
b) Draw the products upon hydrolysis?
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