Response to the following problem:
(a) Show that in a Joule-Thomson expansion, no temperature change occurs if (∂v/∂T)P = v/T
(b) Show that μcP = T((∂v/∂T)P -v
In the region of moderate pressures, the equation of state of 1mol of gas may be written
Pv = RT + B’P + C’P2 ,
where the second and third virial coefficients B and C are functions of T only. (c) Show that, as the pressure approaches zero,
μcP → T(dB’/dT) - B’
(d) Show that the equation of the inversion curve is P = B’ -T(dB’/dT)/C’ - T(dC’/dT) .