Determine the region of moderate pressures


Response to the following problem:

(a) Show that in a Joule-Thomson expansion, no temperature change occurs if  (∂v/∂T)P = v/T

(b) Show that μcP = T((∂v/∂T)P -v

In the region of moderate pressures, the equation of state of 1mol of gas may be written

Pv = RT + B’P + C’P2  ,

where the second and third virial coefficients B and C are functions of T only. (c) Show that, as the pressure approaches zero,

μcP → T(dB’/dT) - B’

(d) Show that the equation of the inversion curve is P = B’ -T(dB’/dT)/C’ - T(dC’/dT) .

 

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Engineering Mathematics: Determine the region of moderate pressures
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