Calculating cell potential and reduction potentials


Assignment:

Question 1. Consider the following reaction at 25o C, [Al3+] = 2.0 M and [Zn2+] = 1.0M

2 Al (s) + 3 Zn2+ (aq) à 3 Zn (s) + 2 Al3+ (aq)

a) Predict if the cell potential, Ecell > Eocell or Ecell < Eocell. Explain why.

b) Calculate Eocell given the half-reduction potentials.

Zn2+ (aq) + 2 e- à Zn (s)                                Eo = -0.76 V

Al3+ (aq) + 3 e- à Al (s)                                 Eo = -1.66 V

c) How many electrons are transferred in the reaction?

d)   Calculate Ecell for the reaction using the Nernst equation.

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Chemistry: Calculating cell potential and reduction potentials
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