Introduction to Stereogenic Nitrogen
A close inspection of the pseudoephedrine and ephedrine isomers suggests that other stereogenic center, the nitrogen, is present. As defined before, in shape single-bonded nitrogen is pyramidal, with the non-bonding electron pair pointing to the not occupied corner of a tetrahedral region. Its configuration is chiral because the nitrogen in these compounds is bonded to three distinct groups. The non-identical mirror-image configurations are demonstrated in the picture that is displayed below (the molecule's remainder is represented by R, and the electron pair is represented in yellow color). There would be four additional stereoisomers of pseudoephedrine and ephedrine if these configurations were stable. Though, pyramidal nitrogen is usually not configurationally stable. It fastly inverts its configuration (equilibrium arrows) by passing from a planar, sp2-hybridized transition state, leading to the mixture of interconverting R and S configurations. A 50:50 (racemic) mixture of R and S configurations would present at equilibrium if the nitrogen atom were the only chiral center in the molecule. A mixture of diastereomers will result if another chiral center is present, as in the ephedrin isomers. In any event nitrogen groups like this, if exist in a compound, do not contribute to isolable stereoisomers.
Email based Stoichiometry Homework Help -Assignment Help
Tutors at the www.tutorsglobe.com are committed to provide the best quality Stoichiometry homework help - assignment help. They use their experience, as they have solved thousands of the Stoichiometry assignments, which may help you to solve your complex Stoichiometry homework. You can find solutions for all the topics come under the Stoichiometry. The dedicated tutors provide eminence work on your Organic Chemistry homework help and devoted to provide K-12 level Chemistry to college level chemistry help before the deadline mentioned by the student. Stoichiometry homework help is available here for the students of school, college and university. TutorsGlobe assure for the best quality compliance to your homework. Compromise with quality is not in our dictionary. If we feel that we are not able to provide the homework help as per the deadline or given instruction by the student, we refund the money of the student without any delay.
Qualified and Experienced Stoichiometry Tutors at www.tutorsglobe.com
Tutors at the www.tutorsglobe.com take pledge to provide full satisfaction and assurance in Stoichiometry homework help. Students are getting Chemistry homework help services across the globe with 100% satisfaction. We value all our service-users. We provide email based Stoichiometry homework help - assignment help. You can join us to ask queries 24x7 with live, experienced and qualified Chemistry tutors specialized in Stoichiometry.
Don’t hesitate to avail the impeccable Gender in Health and Body Assignment Help service from the qualified tutors at low prices to score high.
Equivalent Impedance Transforms tutorial all along with the key concepts of 3-Element Networks, Equivalent Circuit, Thevenin's equivalent, Extra Element Theorem, Felici's Law and Foster's Reactance Theorem
are assignments and coursework your biggest nightmare? avail aerospace engineering assignment help to secure maximum marks.
tutorsglobe.com laws of mendel assignment help-homework help by online mendels laws of inheritance tutors
tutorsglobe.com morphology of eumycotic granules assignment help-homework help by online mycetoma tutors
www.tutorsglobe.com offers theory of unemployment & types of unemployment, economics assignment help - homework help and writing assignments.
tutorsglobe.com advantages of capitalist economy assignment help-homework help by online capitalist economy tutors
Reactions of Quinolines tutorial all along with the key concepts of Physical and Chemical Properties of Quinoline, Electrophilic Substitution, Nucleophilic Addition/Substitution of of Quinoline
www.tutorsglobe.com offers graphical design notation homework help, assignment help, case study, writing homework help, online tutoring assistance by computer science tutors.
tutorsglobe.com significance of natural vegetative propagation assignment help-homework help by online natural methods of vegetative propagation tutors
tutorsglobe.com nitrogen molecule assignment help-homework help by online molecular orbital energy level diagrams tutors
Dividends are paid out of the revenue reserves and should be subtracted from these reserves (generally retained earnings) while preparing the statement of financial position.
Theory and lecture notes of Extreme Situations-Financial Crises all along with the key concepts of extreme situations: financial crises, Lenders of Last Resort, Deposit Insurance and Moral Hazard. Tutorsglobe offers homework help, assignment help and tutor’s assistance on Extreme Situations-Financial Crises.
www.tutorsglobe.com offers system analysis of the existing system homework help, assignment help, case study, writing homework help, online tutoring assistance by computer science tutors.
What is Issue Control? explain Pricing of Issues, A Material Requisition Note is prepared through the department that is in requirement of the material and sent to the stores department.
1958659
Questions Asked
3689
Tutors
1476908
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!