Introduction to Occurrence of Aldehydes and Ketones
Natural Products
Aldehydes and ketones are broad spread in nature, frequently combined with other functional groups. Illustration is displayed in the diagram. The compounds in the top row are found mainly in plants or microorganisms; those in the bottom row have animal origins. These molecular structures are all chiral, by the exception of the first three compounds (top row). When chiral compounds are found in nature they are generally enantiomerically pure, even though distinct sources may yield distinct enantiomers. For instance, carvone is found as its levorotatory (R)-enantiomer in spearmint oil, where, caraway seeds consist of the dextrorotatory (S)-enantiomer. Note: the aldehyde function is frequently written as -CHO in condensed or complex formulas.
Other nomenclature rules:
Prefix (dione, trione, etc.); position numbers must be employed for each ketone group.
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