Introduction of Nomenclature Ethers
Ethers are compounds that having two aryl or alkyl groups bonded to an oxygen atom, like in the formula R1-O-R2. The ether functional group does not have a feature IUPAC nomenclature suffix, so it is essential to entitled it as a substituent. To do like this, common alkoxy substituents are given names derived from their alkyl component, as displayed in the table below. Illustrations of ether nomenclature are provided on the left below. Simple ethers are given general names wherein the alkyl groups bonded to the oxygen are termed in alphabetical order followed by the word "ether". The top left illustration displays the common name in blue under the IUPAC name. Several simple ethers are symmetrical, in that the two alkyl substituents are similar. These are entitled as "dialkyl ethers". Illustrations are: CH3CH2OCH2CH3, diethyl ether (sometimes referred to as ether), and CH3OCH2CH2OCH3, ethylene glycol dimethyl ether (glyme).
Sulfides are the sulfur analogs of ethers (R-S-R'). For an instance, (CH3)3C-S-CH3 is tert-butyl methyl sulfide. Sulfides are than ethers, chemically more reactive, reflecting greater nucleophilicity of sulfur relative to oxygen.
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