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  Xenon Fluoride Compounds

Xenon Fluoride Compounds:

Xenon made three binary Fluorides XeF2, XeF4, and XeF6 by direct union of elements under suitable experimental conditions.

Properties:

XeF2, XeF4 and XeF6 are colorless crystalline solids subliming eagerly at 298K. They are powerful fluorinating agents. They are eagerly hydrolysed by even traces of water. For illustration.

2XeF2 + 2 H2O → 2Xe + 4HF + O2

Structure:

The structure of three xenon fluorides can be inferred from VSEPR theory. XeF2 and XeF4 contain linear and square planar structure correspondingly. XeF6, contain 7 electron pairs (i.e., 6 bonding and one lone pair) and therefore encompass a distorted octahedral structure in the gas phase.

1226_xenon fluorides.jpg

 

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