What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Provide solution of this question. 1.0 gm of pure calcium carbonate was found to need 50 ml of dilute HCL for complete reaction. The strength of the HCL solution is specified by : (a) 4 N (b) 2 N (c) 0.4 N (d) 0.2 N
Choose the right answer from following. The amount of NaOH in gms in 250cm3 of a0.100M NaOH solution would be : (a) 4 gm (b) 2 gm (c) 1 gm (d) 2.5 gm
The osmotic pressure of a 5% solution of cane sugar at 150oC is (mol. wt. of cane sugar = 342)(a) 4 atm (b) 3.4 atm (c) 5.07 atm (d) 2.45 atmAnswer: (c) Π = (5 x 0.0821 x 1000 x 423)/(342 x 100) = 5.07 atm
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The colligative properties of a solution depend on: (a) Nature of solute particles present in it (b) Nature of solvent used (c) Number of solute particles present in it (d) Number of moles of solvent only
Give me answer of this question. The formula weight of H2SO4 is 98. The weight of the acid in 400mi of solution is: (a)2.45g (b) 3.92g (c) 4.90g (d) 9.8g
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Mole fraction of any solution is equavalent to: (a) No. of moles of solute/ volume of solution in litter (b) no. of gram equivalent of solute/volume of solution in litters (c) no. of moles of solute/ Mass of solvent in kg (d) no. of moles of any
Explain DNA organic in brief?
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