What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Particles of quartz are packed by:(i) Electrical attraction forces (ii) Vander Waal's forces (iii) Covalent bond forces (iv) Strong electrostatic force of attraction Answer: (iii)
The pressure-temperature relation for solid-vapor or liquid vapor equilibrium is expressed by the Clausis-Clapeyron equation.We now obtain an expression for the pressure-temperature dependence of the state of equilibrium between two phases. To be specific,
4) The addition of S2- ion to Fe(OH)2(s). Explain why the addition of S2- ion to Cr(OH)3(s) does not result in the formation of Cr2S3(s).
Choose the right answer from following. The molality of 90% H2SO4 solution is: [density=1.8 gm/ml] (a)1.8 (b) 48.4 (c) 9.18 (d) 94.6
Many enzyme catalyzed reactions obeys a complex rate equation that can be written as the total quantity of enzyme and the whole amount of substrate in the reaction system. Many rate equations that are more complex than first and se
Methane containing 4 mol% N2 is flowing through a pipeline at 105.1 kpa and 22 °C. To check this flow rate, N2 at the same temperature and pressure are introduced to the pipeline at the rate of 2.83 m3/min. At the end of the pipe (
Whether HCl is a base or an acid? Briefly state your comments?
IN GAS PHASE, BASICITIES OF THE AMINES IS JUST OPPOSITE TO BASICITY OF AMINES IN AQEUOUS PHASE .. EXPLAIN
Carbon compounds containing more than one halogen atom are called polyhalogen compounds. Most of these compounds are valuable in industry and agriculture. Some important polyhalogen compounds are described as follows: Q : Solution problem What is the correct What is the correct answer. To made a solution of concentration of 0.03 g/ml of AgNO3, what quantity of AgNO3 must be added in 60 ml of solution: (a) 1.8 (b) 0.8 (c) 0.18 (d) None of these
What is the correct answer. To made a solution of concentration of 0.03 g/ml of AgNO3, what quantity of AgNO3 must be added in 60 ml of solution: (a) 1.8 (b) 0.8 (c) 0.18 (d) None of these
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