What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
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a) Air flowing at 1 m3/s enters an adiabatic compressor at 20°C and 1 bar. It exits at 200°C. The isentropic efficiency of the compressor is 80%. Calculate the exit pressure and the power required. b) Steam enter
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The first method begins with a well defined layer, or boundary, of solution near the center of rotation and tracks the movement of this layer to the outside of the cell as a function of time. Such a method is termed a sedimentary velocity experiment. A
Choose the right answer from following. Molar concentration (M) of any solution : a) No. of moles of solute/Volume of solution in litre (b) No. of gram equivalent of solute / volume of solution in litre (c) No. of moles os solute/ Mass of solvent in kg (
The equilibrium constant can be treated as a particular type of molecular distribution. Consider the simplest gas-phase reaction, one in which molecules of A are converted to molecules of B. the reaction, described by the equation Q : Determining concentration in ppm A 500 A 500 gm tooth paste sample has 0.2g fluoride concentration. Determine the concentration of F in terms of ppm level: (a) 250 (b) 200 (c) 400 (d) 1000Answer: (c) F-ions in ppm = (0.2/500) x 106 = 400
A 500 gm tooth paste sample has 0.2g fluoride concentration. Determine the concentration of F in terms of ppm level: (a) 250 (b) 200 (c) 400 (d) 1000Answer: (c) F-ions in ppm = (0.2/500) x 106 = 400
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