What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Drugs are broadly classified into following types depending on the purpose for which they are used. 1. Antipyretics
Help me to go through this problem. When 7.1gm Na2SO4 (molecular mass 142) dissolves in 100ml H2O , the molarity of the solution is: (a) 2.0 M (b) 1.0 M (c) 0.5 M (d) 0.05 M
Help me to solve this problem. What is the molality of a solution which contains 18 g of glucose (C6,H12, O6) in 250 g of water: (a) 4.0 m (b) 0.4 m (c) 4.2 m (d) 0.8 m
brief discription of relative lowering of vapour pressure
Give me answer of this question. The volume of water to be added to 100cm3 of 0.5 N N H2SO4 to get decinormal concentration is : (a) 400 cm3 (b) 500cm3 (c) 450cm3 (d)100cm3
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solutio
what are the most important inorganic molecular substances for living beings?
Carbon compounds containing more than one halogen atom are called polyhalogen compounds. Most of these compounds are valuable in industry and agriculture. Some important polyhalogen compounds are described as follows: Q : Death cap musrooms the death cap the death cap mushroom based on your knowledge of the biochemistry of dna and rna
the death cap mushroom based on your knowledge of the biochemistry of dna and rna
Can someone please help me in getting through this problem. Which of the given concentration factor is affected by the change in temperature: (1) Molarity (2) Molality (3) Mole fraction (4) Weight fraction
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