What are homogenous catalyst? Give few examples.
When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are: SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst. Oxidization of CO by O2 in the presence of NO as catalyst. Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst Hydrolysis of esters using H2SO4 as catalyst Hydrolysis of sucrose in the presence of dilute sulphuric acid. Mechanism of homogeneous catalysis As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2. In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.
Choose the right answer from following. At 300 K, when a solute is added to a solvent its vapour pressure over the mercury reduces from 50 mm to 45 mm. The value of mole fraction of solute will be: (a)0.005 (b)0.010 (c)0.100 (d)0.900
Particles of quartz are packed by:(i) Electrical attraction forces (ii) Vander Waal's forces (iii) Covalent bond forces (iv) Strong electrostatic force of attraction Answer: (iii)
The objective of this work is to separate a binary mixture and to cool down the bottom product for storage. (Check table below to see which mixture you are asked to study). 100 kmol of feed containing 10 mol percent of the lighter component enters a continuous distillation column at the m
Select the right answer of the question. Molecular weight of urea is 60. A solution of urea containing 6g urea in one litre is : (a)1 molar (b)1.5 molar (c) 0.1 molar (d) 0.01 molar
A 500 gm tooth paste sample has 0.2g fluoride concentration. Determine the concentration of F in terms of ppm level: (a) 250 (b) 200 (c) 400 (d) 1000Answer: (c) F-ions in ppm = (0.2/500) x 106 = 400
Help me to solve this question. Which of the following is incorrect: (a) Relative lowering of vapour pressure is independent (b)The vapour pressure is a colligative property (c)Vapour pressure of a solution is lower than the vapour pressure of the solvent (d)The
Choose the right answer from following. The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000 g of water is 0.00713. The molecular weight of the substance will be: (a) 18.0 (b) 342 (c) 60 (d) 180
Write a short note on the IUPAC name of the benzene?
Laws of Chemical Combination- In order to understand the composition of the compounds, it is necessary to have a theory which accounts for both qualitative and quantitative observations during chem
On passing H2S gas through a particular solution of Cu+ and Zn+2 ions, first CuS is precipitated because : (a)Solubility product of CuS is equal to the ionic product of ZnS (b) Solubility product of CuS is equal to the solubility product
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