--%>
Assignment Help - homework help

What are homogenous catalyst? Give few examples.

When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are:
    
SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst.

2141_homogenous catalyst.png 
    
Oxidization of CO by O2 in the presence of NO as catalyst.

1497_homogenous catalyst1.png 
    
Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst

1588_homogenous catalyst2.png 
    
Hydrolysis of esters using H2SO4 as catalyst

2088_homogenous catalyst3.png 
    
Hydrolysis of sucrose in the presence of dilute sulphuric acid.

84_homogenous catalyst4.png 

Mechanism of homogeneous catalysis 

As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2.
 
In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.

1574_homogenous catalyst5.png

   Related Questions in Chemistry

  • Q : Extensive property Choose the right

    Choose the right answer from following. Which one of the following is an extensive property: (a) Molar volume (b) Molarity (c) Number of moles (d) Mole fraction

    		•
  • Q : Problem on physical and thermodynamic

    The shells of marine organisms contain calcium carbonate CaCO3, largely in a crystalline form known as calcite. There is a second crystalline form of calcium carbonate known as aragonite. Physical and thermodynamic properties of calcite and aragonite at 298

    		•
  • Q : Particles of quartz Particles of quartz

    Particles of quartz are packed by:(i) Electrical attraction forces  (ii) Vander Waal's forces  (iii) Covalent bond forces  (iv) Strong electrostatic force of attraction Answer: (iii)

    		•
  • Q : Determining mole fraction of water in

    A mixture has 18 g water and 414 g ethanol. What is the mole fraction of water in mixture (suppose ideal behaviour of mixture): (i) 0.1  (ii) 0.4  (iii) 0.7  (iv) 0.9 Choose the right answer from abo

    		•
  • Q : Calculation of molecular weight Provide

    Provide solution of this question. In an experiment, 1 g of a non-volatile solute was dissolved in 100 g of acetone (mol. mass = 58) at 298K. The vapour pressure of the solution was found to be 192.5 mm Hg. The molecular weight of the solute is (vapour pressure of ace

    		•
  • Q : Raoults law Give me answer of this

    Give me answer of this question. Provide solution of this question. Which one of the following is the expression of Raoult's law: (a) P-P1/P = n/n+N (b) P1-P/P = N/ N+n (c)P-P2/P1= N/ N-n (d) P1-P/P2= N-n/N

    		•
  • Q : Question of vapour pressure Choose the

    Choose the right answer from following. Vapour pressure of a solution is: (a) Directly proportional to the mole fraction of the solvent (b) Inversely proportional to the mole fraction of the solute (c) Inversely proportional to the mole fraction of the solvent (d

    		•
  • Q : The Liver Is Responsible For Much Of

    The Liver Is Responsible For Much Of The Pentose Phosphate Activity Explain

    		•
  • Q : Theory of one dimensional motion For

    For motion in one dimension, the distribution of the molecules over quantum states, speeds, and energies can be deduced.Here we show that the energy of a macroscopic gas sample can be described on the basis of our knowledge of the quantum states allowed to

    		•
  • Q : Molarity of the final mixture Can

    Can someone please help me in getting through this problem. Two solutions of a substance (that is, non electrolyte) are mixed in the given manner 480 ml of 1.5M first solution + 520 ml of 1.2M second solution. Determine the molarity of the final mixture

    		•