--%>
Assignment Help - homework help

What are homogenous catalyst? Give few examples.

When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are:
    
SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst.

2141_homogenous catalyst.png 
    
Oxidization of CO by O2 in the presence of NO as catalyst.

1497_homogenous catalyst1.png 
    
Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst

1588_homogenous catalyst2.png 
    
Hydrolysis of esters using H2SO4 as catalyst

2088_homogenous catalyst3.png 
    
Hydrolysis of sucrose in the presence of dilute sulphuric acid.

84_homogenous catalyst4.png 

Mechanism of homogeneous catalysis 

As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2.
 
In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.

1574_homogenous catalyst5.png

   Related Questions in Chemistry

  • Q : Problem on physical and thermodynamic

    The shells of marine organisms contain calcium carbonate CaCO3, largely in a crystalline form known as calcite. There is a second crystalline form of calcium carbonate known as aragonite. Physical and thermodynamic properties of calcite and aragonite at 298

    		•
  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

    		•
  • Q : Explain alcohols and phenols in organic

    Alcohols and phenols are the compounds

    		•
  • Q : Solubility product On passing H 2 S gas

    On passing H2S gas through a particular solution of Cu+ and Zn+2 ions, first CuS is precipitated because : (a)Solubility product of CuS is equal to the ionic product of ZnS (b) Solubility product of CuS is equal to the solubility product

    		•
  • Q : Equimolar solutions Select the right

    Select the right answer of the question. Equimolar solutions in the same solvent have : (a)Same boiling point but different freezing point (b) Same freezing point but different boiling poin (c)Same boiling and same freezing points (d) Different boiling and differe

    		•
  • Q : What are ion selective electrodes? Ion

    Ion Selective Electrodes An ion selective membrane can be used to form an electrochemical cell whose emf depends on the concentration of that ion. Before we proceed to an important application of emf measurements, brie

    		•
  • Q : Problem on relative volatility In

    In vapor-liquid equilibrium the relative volatility αij is defined to be the ratio of the separation or K factor for species i to that for species j, that is,  αij = Ki/Kj

    		•
  • Q : Describe Transformation Matrices. Each

    Each symmetry operation can be represented by a transformation matrix.You have seen what happens when a molecule is subjected to the symmetry operation that corresponds to any of the symmetry elements of the point group to which the molecule belongs. The m

    		•
  • Q : Liquid surfaces The surface between a

    The surface between a liquid and a vapour distinguishes these fluids. The surface tension of liquids can be looked upon as that the property which draws a liquid together and forms a liquid vapour interface, therefore, distinguishing liquids from gases.<

    		•
  • Q : Eutectic Formation In some two

    In some two component, solid liquid systems, a eutectic mixture forms.Consider, now a two component system at some fixed pressure, where the temperature range treated is such as to include formation of one or more solid phases. A simple behavior is shown b

    		•