What are homogenous catalyst? Give few examples.
When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are: SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst. Oxidization of CO by O2 in the presence of NO as catalyst. Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst Hydrolysis of esters using H2SO4 as catalyst Hydrolysis of sucrose in the presence of dilute sulphuric acid. Mechanism of homogeneous catalysis As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2. In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.
Choose the right answer from following. If 0.50 mol of CaCl2 is mixed with 0.20 mol of Na3PO4, the maximum number of moles of Ca3 (PO2)2 which can be formed: (a) 0.70 (b) 0.50 (c) 0.20 (d) 0.10
Orthosubstituted anilines are generally weaker bases than aniline irrespective of the electron releasing or electron withdrawing nature of the substituent. This is known as ortho effect and may probably be due to combined electronic and steric factors.The overall basic strength of ort
Provide solution of this question. Which of the following concentration factor is affected by change in temperature : (a)Molarity (b) Molality (c)Mole fraction (d)Weight fraction
This is a very important aspect of Physical Chemistry in which knowledge of the size, shape, rigidity and electronic structure of molecules deduced from the experimental methods treated here goes hand in hand with the theoretical approaches of chemical reactions. Spec
In some two component, solid liquid systems, a solid compound forms.In systems in which the components have an interaction for such other, a solid state compound of the two compounds of the two components can form.Formic acid and formaide form a solid state, one-to-one com
Illustrate what is protein in Chemistry?
Separation by distillation can be described with a boiling point diagram. The important process of distillation can now be investigated. From the boiling point diagram one can see that if a small amount of vapour were removed from a liquid of composit
Alcohols and phenols are the compounds
The boiling point of 0.1 molal aqueous solution of urea is 100.18oC at 1 atm. The molal elevation constant of water is: (a) 1.8 (b) 0.18 (c) 18 (d) 18.6Answer: (a) Kb
The adsorption of infrared radiation by diatomic molecules increases the vibrational energy fo molecules and gives information about the force constant for the "spring" of the molecule.;The molecular motion that has the next larger energy level spacing aft
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