--%>

What are halogen oxoacids?

Fluorine yields only one oxyacid, hypofluorous acid (HOF). Chlorine, bromine and iodine form four series of acids with formulae: HOX, HXO2, HXO3 and HXO4, although many of these are known only in solutions or as salts.
    
The Hypohalous acids HOCl, HOBr and HOI are weak acids and are only formed in aqueous solutions by disproportionation of the halogen of the halogen water

X2 + H21402_Phosphorus trichloride.png  HOX + HX (X = Cl, Br, I)

Salts of these acids are known as hypohalites, e.g. bleaching powder, CaOCl2 is a common example of this category.
    
The halic acids HClO3 and HBrO3 are also known as solutions, but iodic acid HIO3 exists as a white solid. Thus, the stability of acids increases with increase in atomic number of the halogen. These acids act as strong oxidizing agents, e.g. these oxidize halides to give halogens in acid medium.

OX3- + 5X- + 6H+  1402_Phosphorus trichloride.png  3X2 + 3H2O

The salts of these are called halates. Amongst the halates, sodium chlorate (NaClO3and potassium chlorate (KClO3are prepared on industrial scale. It is also known as 'Berthelot salt'. NaClO3 is a powerful weed killer, whilst KClO3 is used in fireworks and matches.
    
Perhalic acid i.e. perchloric, periodic acids as well as their salts perchlorates and periodates are known to exist. The perhalates (MXO4)are prepared by the electrolytic oxidation of the corresponding halates, MXO3.

4ClO3 1402_Phosphorus trichloride.png  Cl+ 3ClO4-

The disproportionation of BrO3- to BrO4- is unfavorable, therefore per bromates are obtained only by oxidation of BrO3- by F2 in basic solution.

BrO3- + F2 + 2OH-  1402_Phosphorus trichloride.png  BrO4+ 2F- + H2O

Acidic character of oxyacids: the variation in the acidic character of the halogen acids in different oxidation states are summarized below:
    
The acid strength of oxyacid of the same halogen increases with the increase in oxidation number of the halogen. For example, among the different oxyacids of chlorine the acidic character follows the order

HOCl < HClO2 < HClO3 < HClO4

Reason: the acid strength can be explained on the basis Lowry-Bronsted concept that conjucate base of weak and is strong and conjugate base of strong acid is weaker.

   Related Questions in Chemistry

  • Q : Normality how 0.5N HCL is prepared for

    how 0.5N HCL is prepared for 10 littre solution

  • Q : Define Bond Energies - Bond Charges

    Energy changes in some chemical reactions can be used to deduce the energies of chemical bonds. Our understanding of the molecular basis of thermodynamic properties is extended when we ask why the enthalpy change for a reaction is what it is. We deduce,

  • Q : Molar concentration Choose the right

    Choose the right answer from following. Molar concentration (M) of any solution : a) No. of moles of solute/Volume of solution in litre (b) No. of gram equivalent of solute / volume of solution in litre (c) No. of moles os solute/ Mass of solvent in kg  (

  • Q : Explain Ionic Bond with examples. The

    The bonding in ionic molecules can be described with a coulombic attractive term.For some diatomic molecules we take quite a different approach from that used in preceding sections to describe the bonding. Ionic bonds are interpreted in terms of the coulom

  • Q : What do you mean by the term enzymes

    What do you mean by the term enzymes? Briefly illustrate it.

  • Q : Facts on evaporation Illustrate the 3

    Illustrate the 3 facts on evaporation?

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

  • Q : Question related to colligative

    The colligative properties of a solution depend on: (a) Nature of solute particles present in it (b) Nature of solvent used (c) Number of solute particles present in it (d) Number of moles of solvent only

  • Q : What do you mean by the term Organic

    What do you mean by the term Organic Chemistry? Briefly define the term?

  • Q : Molarity of acid solution If 20ml of

    If 20ml of 0.4N, NaoH solution completely neutralises 40ml of a dibasic acid. The molarity of the acid solution is: (a) 0.1M (b) 0.2M  (c) 0.3M (d) 0.4M Choose the right answer fron above.