--%>

What are halogen oxoacids?

Fluorine yields only one oxyacid, hypofluorous acid (HOF). Chlorine, bromine and iodine form four series of acids with formulae: HOX, HXO2, HXO3 and HXO4, although many of these are known only in solutions or as salts.
    
The Hypohalous acids HOCl, HOBr and HOI are weak acids and are only formed in aqueous solutions by disproportionation of the halogen of the halogen water

X2 + H21402_Phosphorus trichloride.png  HOX + HX (X = Cl, Br, I)

Salts of these acids are known as hypohalites, e.g. bleaching powder, CaOCl2 is a common example of this category.
    
The halic acids HClO3 and HBrO3 are also known as solutions, but iodic acid HIO3 exists as a white solid. Thus, the stability of acids increases with increase in atomic number of the halogen. These acids act as strong oxidizing agents, e.g. these oxidize halides to give halogens in acid medium.

OX3- + 5X- + 6H+  1402_Phosphorus trichloride.png  3X2 + 3H2O

The salts of these are called halates. Amongst the halates, sodium chlorate (NaClO3and potassium chlorate (KClO3are prepared on industrial scale. It is also known as 'Berthelot salt'. NaClO3 is a powerful weed killer, whilst KClO3 is used in fireworks and matches.
    
Perhalic acid i.e. perchloric, periodic acids as well as their salts perchlorates and periodates are known to exist. The perhalates (MXO4)are prepared by the electrolytic oxidation of the corresponding halates, MXO3.

4ClO3 1402_Phosphorus trichloride.png  Cl+ 3ClO4-

The disproportionation of BrO3- to BrO4- is unfavorable, therefore per bromates are obtained only by oxidation of BrO3- by F2 in basic solution.

BrO3- + F2 + 2OH-  1402_Phosphorus trichloride.png  BrO4+ 2F- + H2O

Acidic character of oxyacids: the variation in the acidic character of the halogen acids in different oxidation states are summarized below:
    
The acid strength of oxyacid of the same halogen increases with the increase in oxidation number of the halogen. For example, among the different oxyacids of chlorine the acidic character follows the order

HOCl < HClO2 < HClO3 < HClO4

Reason: the acid strength can be explained on the basis Lowry-Bronsted concept that conjucate base of weak and is strong and conjugate base of strong acid is weaker.

   Related Questions in Chemistry

  • Q : Problem on molarity-normality-molality

    Can someone please help me in getting through this problem. The solution ofAl2(SO4)3 d = 1.253gm/m comprise 22% salt by weight. The molarity, normality and molality of the solution is: (1) 0.805 M, 4.83 N, 0.825 M (2)

  • Q : Problem on mole fraction of glucose

    Provide solution of this question. While 1.80gm glucose dissolve in 90 of H2O , the mole fraction of glucose is: (a) 0.00399 (b) 0.00199 (c) 0.0199 (d) 0.998

  • Q : Calculating molarity of a solution

    Select the right answer of the question .The molarity of a 0.2 N N2Co3 solution will be: (a) 0.05 M (b) 0.2 M (c) 0.1 M (d)0.4 M

  • Q : P block bif3 is ionic while other

    bif3 is ionic while other trihalides are covalent in nature

  • Q : Molar mass of solute The boiling point

    The boiling point of benzene is 353.23 K. If 1.80 gm of a non-volatile solute was dissolved in 90 gm of benzene, the boiling point is increased to 354.11 K. Then the molar mass of the solute is: (a) 5.8g mol-1  (b)

  • Q : Question of vapour pressure Choose the

    Choose the right answer from following. Vapour pressure of a solution is: (a) Directly proportional to the mole fraction of the solvent (b) Inversely proportional to the mole fraction of the solute (c) Inversely proportional to the mole fraction of the solvent (d

  • Q : Real vapour pressure Choose the right

    Choose the right answer from following. The pressure under which liquid and vapour can coexist at equilibrium is called the : (a) Limiting vapour pressure (b) Real vapour pressure (c) Normal vapour pressure (d) Saturated vapour pressure

  • Q : Question based on strength of solution

    Help me to go through this problem. On dissolving 1 mole of each of the following acids in 1 litre water, the acid which does not give a solution of strength 1N is: (a) HCl (b) Perchloric acid (c) HNO3 (d) Phosphoric acid

  • Q : Explain the polymers and its types.

    Polymers are the chief products of modern chemical industry which form the backbone of present society. Daily life without the discovery and varied applications of polymers would not have been easier and colourful. The materials made of polymers find multifarious uses and applications in all walk

  • Q : Macromolecules what are condensation

    what are condensation polymerization give in with 2 examples