--%>

What are halogen oxoacids?

Fluorine yields only one oxyacid, hypofluorous acid (HOF). Chlorine, bromine and iodine form four series of acids with formulae: HOX, HXO2, HXO3 and HXO4, although many of these are known only in solutions or as salts.
    
The Hypohalous acids HOCl, HOBr and HOI are weak acids and are only formed in aqueous solutions by disproportionation of the halogen of the halogen water

X2 + H21402_Phosphorus trichloride.png  HOX + HX (X = Cl, Br, I)

Salts of these acids are known as hypohalites, e.g. bleaching powder, CaOCl2 is a common example of this category.
    
The halic acids HClO3 and HBrO3 are also known as solutions, but iodic acid HIO3 exists as a white solid. Thus, the stability of acids increases with increase in atomic number of the halogen. These acids act as strong oxidizing agents, e.g. these oxidize halides to give halogens in acid medium.

OX3- + 5X- + 6H+  1402_Phosphorus trichloride.png  3X2 + 3H2O

The salts of these are called halates. Amongst the halates, sodium chlorate (NaClO3and potassium chlorate (KClO3are prepared on industrial scale. It is also known as 'Berthelot salt'. NaClO3 is a powerful weed killer, whilst KClO3 is used in fireworks and matches.
    
Perhalic acid i.e. perchloric, periodic acids as well as their salts perchlorates and periodates are known to exist. The perhalates (MXO4)are prepared by the electrolytic oxidation of the corresponding halates, MXO3.

4ClO3 1402_Phosphorus trichloride.png  Cl+ 3ClO4-

The disproportionation of BrO3- to BrO4- is unfavorable, therefore per bromates are obtained only by oxidation of BrO3- by F2 in basic solution.

BrO3- + F2 + 2OH-  1402_Phosphorus trichloride.png  BrO4+ 2F- + H2O

Acidic character of oxyacids: the variation in the acidic character of the halogen acids in different oxidation states are summarized below:
    
The acid strength of oxyacid of the same halogen increases with the increase in oxidation number of the halogen. For example, among the different oxyacids of chlorine the acidic character follows the order

HOCl < HClO2 < HClO3 < HClO4

Reason: the acid strength can be explained on the basis Lowry-Bronsted concept that conjucate base of weak and is strong and conjugate base of strong acid is weaker.

   Related Questions in Chemistry

  • Q : Volume of solution containing solute

    What volume of solution contains 0.1 mole of the solute: (a) 100ml (b) 125ml  (c) 500ml (d) 62.5ml Choose the right answer from above.

  • Q : Explain Polyatomic Vibrational Spectra

    Polyatomic molecules vibrate in a number of ways, and some of these vibrations can be studied by infrared absorption spectroscopy and some by Raman spectroscopy. The characters of transformation matrices for all 3n translation rotation vibration motio

  • Q : Calculate molarity of a solution

    Provide solution of this question. Molarity of a solution prepared by dissolving 75.5 g of pure KOH in 540 ml solution is: (a) 3.05 M (b) 1.35 M (c) 2.50 M (d) 4.50 M

  • Q : Finding Normality Can someone please

    Can someone please help me in getting through this problem. Concentrated H2SO4 has a density of 1.98 gm/ml and is 98% H2SO4 by weight. The normality is: (a) 2 N  (b) 19.8 N  (c) 39.6 N  (d) 98

  • Q : Sugar solution The solution of sugar in

    The solution of sugar in water comprises: (i) Free atoms (ii) Free ions (iii) Free molecules (iv) Free atom and molecules. Choose the right answer from the above.

  • Q : Wavelengths which the human eye can see

    Briefly state the wavelengths which the human eye can see?

  • Q : What is laser and explain its working?

    Laser action relies on a non-Boltzmann population inversion formed by the absorption of radiation and vibrational deactivation that forms a long lived excited electronic state. An excited state molecule can move to a lower energy state or return to the

  • Q : Normality how 0.5N HCL is prepared for

    how 0.5N HCL is prepared for 10 littre solution

  • Q : Question on Mole fraction Mole fraction

    Mole fraction of any solution is equavalent to: (a) No. of moles of solute/ volume of solution in litter (b) no. of gram equivalent of solute/volume of solution in litters (c) no. of  moles of solute/ Mass of solvent in kg (d) no. of moles of any

  • Q : Molarity what is the molarity of the

    what is the molarity of the solution prepared by dissolving 75.5 g of pure KOH in 540 ml of solution