--%>

What are halogen oxoacids?

Fluorine yields only one oxyacid, hypofluorous acid (HOF). Chlorine, bromine and iodine form four series of acids with formulae: HOX, HXO2, HXO3 and HXO4, although many of these are known only in solutions or as salts.
    
The Hypohalous acids HOCl, HOBr and HOI are weak acids and are only formed in aqueous solutions by disproportionation of the halogen of the halogen water

X2 + H21402_Phosphorus trichloride.png  HOX + HX (X = Cl, Br, I)

Salts of these acids are known as hypohalites, e.g. bleaching powder, CaOCl2 is a common example of this category.
    
The halic acids HClO3 and HBrO3 are also known as solutions, but iodic acid HIO3 exists as a white solid. Thus, the stability of acids increases with increase in atomic number of the halogen. These acids act as strong oxidizing agents, e.g. these oxidize halides to give halogens in acid medium.

OX3- + 5X- + 6H+  1402_Phosphorus trichloride.png  3X2 + 3H2O

The salts of these are called halates. Amongst the halates, sodium chlorate (NaClO3and potassium chlorate (KClO3are prepared on industrial scale. It is also known as 'Berthelot salt'. NaClO3 is a powerful weed killer, whilst KClO3 is used in fireworks and matches.
    
Perhalic acid i.e. perchloric, periodic acids as well as their salts perchlorates and periodates are known to exist. The perhalates (MXO4)are prepared by the electrolytic oxidation of the corresponding halates, MXO3.

4ClO3 1402_Phosphorus trichloride.png  Cl+ 3ClO4-

The disproportionation of BrO3- to BrO4- is unfavorable, therefore per bromates are obtained only by oxidation of BrO3- by F2 in basic solution.

BrO3- + F2 + 2OH-  1402_Phosphorus trichloride.png  BrO4+ 2F- + H2O

Acidic character of oxyacids: the variation in the acidic character of the halogen acids in different oxidation states are summarized below:
    
The acid strength of oxyacid of the same halogen increases with the increase in oxidation number of the halogen. For example, among the different oxyacids of chlorine the acidic character follows the order

HOCl < HClO2 < HClO3 < HClO4

Reason: the acid strength can be explained on the basis Lowry-Bronsted concept that conjucate base of weak and is strong and conjugate base of strong acid is weaker.

   Related Questions in Chemistry

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

  • Q : What are haloalkanes and haloarenes and

    Alkyl halides or haloalkanes are the compounds in which a halogen is bonded to an alkyl group. They have the general formula RX (where R is alkyl grou

  • Q : M ive me answer of this question. When

    ive me answer of this question. When mercuric iodide is added to the aqueous solution of potassium iodide, the: (a) Freezing point is raised (b) Freezing point is lowered (c) Freezing point does not change (d) Boiling point does not change

  • Q : Problem on thermodynamic equilibrium In

    In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst: The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410&d

  • Q : Forms a molecule to an organic molecule

    Briefly state what forms a molecule to an organic molecule?

  • Q : Degree of dissociation The degree of

    The degree of dissociation of Ca(No3)2 in a dilute aqueous solution containing 14g of the salt per 200g of water 100oc is 70 percent. If the vapor pressure of water at 100oc is 760 cm. Calculate the vapor pr

  • Q : Number of moles present in water

    Provide solution of this question. How many moles of water are present in 180 of water: (a)1 mole (b)18 mole (c)10 mole (d)100 mole

  • Q : Polymers comparison of biodegradable

    comparison of biodegradable and non-biodegradable polymers

  • Q : Concentration of Sodium chloride

    Provide solution of this question. If 25 ml of 0.25 M NaCl solution is diluted with water to a volume of 500ml the new concentration of the solution is : (a) 0.167 M (b) 0.0125 M (c) 0.833 M (d) 0.0167 M

  • Q : Negative deviation Which one of the

    Which one of the following non-ideal solutions shows the negative deviation: (a) CH3COCH3 + CS2   (b) C6H6 + CH3COCH3   (c) CCl4 + CHCl3