--%>

What are halogen oxoacids?

Fluorine yields only one oxyacid, hypofluorous acid (HOF). Chlorine, bromine and iodine form four series of acids with formulae: HOX, HXO2, HXO3 and HXO4, although many of these are known only in solutions or as salts.
    
The Hypohalous acids HOCl, HOBr and HOI are weak acids and are only formed in aqueous solutions by disproportionation of the halogen of the halogen water

X2 + H21402_Phosphorus trichloride.png  HOX + HX (X = Cl, Br, I)

Salts of these acids are known as hypohalites, e.g. bleaching powder, CaOCl2 is a common example of this category.
    
The halic acids HClO3 and HBrO3 are also known as solutions, but iodic acid HIO3 exists as a white solid. Thus, the stability of acids increases with increase in atomic number of the halogen. These acids act as strong oxidizing agents, e.g. these oxidize halides to give halogens in acid medium.

OX3- + 5X- + 6H+  1402_Phosphorus trichloride.png  3X2 + 3H2O

The salts of these are called halates. Amongst the halates, sodium chlorate (NaClO3and potassium chlorate (KClO3are prepared on industrial scale. It is also known as 'Berthelot salt'. NaClO3 is a powerful weed killer, whilst KClO3 is used in fireworks and matches.
    
Perhalic acid i.e. perchloric, periodic acids as well as their salts perchlorates and periodates are known to exist. The perhalates (MXO4)are prepared by the electrolytic oxidation of the corresponding halates, MXO3.

4ClO3 1402_Phosphorus trichloride.png  Cl+ 3ClO4-

The disproportionation of BrO3- to BrO4- is unfavorable, therefore per bromates are obtained only by oxidation of BrO3- by F2 in basic solution.

BrO3- + F2 + 2OH-  1402_Phosphorus trichloride.png  BrO4+ 2F- + H2O

Acidic character of oxyacids: the variation in the acidic character of the halogen acids in different oxidation states are summarized below:
    
The acid strength of oxyacid of the same halogen increases with the increase in oxidation number of the halogen. For example, among the different oxyacids of chlorine the acidic character follows the order

HOCl < HClO2 < HClO3 < HClO4

Reason: the acid strength can be explained on the basis Lowry-Bronsted concept that conjucate base of weak and is strong and conjugate base of strong acid is weaker.

   Related Questions in Chemistry

  • Q : Analytical chemistry 37% weight of HCl

    37% weight of HCl and density is 1.1g/ml. find molarity of HCl

  • Q : Problem on decinormal strength Can

    Can someone please help me in getting through this problem. How many grams of dibasic acid (having mol. wt. 200) must be present in 100ml  of its aqueous solution to provide decinormal strength: (i) 1g  (ii)2g  (iii) 10g  (iv) 20g<

  • Q : Explain solid in liquid solutions. The

    The French chemist Francois Marie Raoult (1886) carried out a series of experiments to study the vapour pressure of a number of binary solutions. On the basis of the results of the experiments, he proposed a generalization called Raoult's law which states that, <

  • Q : Molarity of acid solution If 20ml of

    If 20ml of 0.4N, NaoH solution completely neutralises 40ml of a dibasic acid. The molarity of the acid solution is: (a) 0.1M (b) 0.2M  (c) 0.3M (d) 0.4M Choose the right answer fron above.

  • Q : Why medications include the hcl Why do

    Why do various medications include the hcl? Describe briefly?

  • Q : Calculating number of moles from

    Choose the right answer from following. If 0.50 mol of CaCl2 is mixed with 0.20 mol of Na3PO4, the maximum number of moles of Ca3 (PO2)2 which can be formed: (a) 0.70 (b) 0.50 (c) 0.20 (d) 0.10

  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

  • Q : How haloalkanes are prepared from

    Alkyl halides can be prepared from alkanes through substitution and from alkenes through addition of halogen acids or through allylic substitution.    From alkanesWhen alkanes are treated with halogens, chlo

  • Q : Question based on relative lowering of

    Give me answer of this question. When a non-volatile solute is dissolved in a solvent, the relative lowering of vapour pressure is equal to: (a) Mole fraction of solute (b) Mole fraction of solvent (c) Concentration of the solute in grams per litre

  • Q : Mass percent Help me to go through this

    Help me to go through this problem. 10 grams of a solute is dissolved in 90 grams of a solvent. Its mass percent in solution is : (a) 0.01 (b) 11.1 (c)10 (d) 9