--%>

What are halogen oxoacids?

Fluorine yields only one oxyacid, hypofluorous acid (HOF). Chlorine, bromine and iodine form four series of acids with formulae: HOX, HXO2, HXO3 and HXO4, although many of these are known only in solutions or as salts.
    
The Hypohalous acids HOCl, HOBr and HOI are weak acids and are only formed in aqueous solutions by disproportionation of the halogen of the halogen water

X2 + H21402_Phosphorus trichloride.png  HOX + HX (X = Cl, Br, I)

Salts of these acids are known as hypohalites, e.g. bleaching powder, CaOCl2 is a common example of this category.
    
The halic acids HClO3 and HBrO3 are also known as solutions, but iodic acid HIO3 exists as a white solid. Thus, the stability of acids increases with increase in atomic number of the halogen. These acids act as strong oxidizing agents, e.g. these oxidize halides to give halogens in acid medium.

OX3- + 5X- + 6H+  1402_Phosphorus trichloride.png  3X2 + 3H2O

The salts of these are called halates. Amongst the halates, sodium chlorate (NaClO3and potassium chlorate (KClO3are prepared on industrial scale. It is also known as 'Berthelot salt'. NaClO3 is a powerful weed killer, whilst KClO3 is used in fireworks and matches.
    
Perhalic acid i.e. perchloric, periodic acids as well as their salts perchlorates and periodates are known to exist. The perhalates (MXO4)are prepared by the electrolytic oxidation of the corresponding halates, MXO3.

4ClO3 1402_Phosphorus trichloride.png  Cl+ 3ClO4-

The disproportionation of BrO3- to BrO4- is unfavorable, therefore per bromates are obtained only by oxidation of BrO3- by F2 in basic solution.

BrO3- + F2 + 2OH-  1402_Phosphorus trichloride.png  BrO4+ 2F- + H2O

Acidic character of oxyacids: the variation in the acidic character of the halogen acids in different oxidation states are summarized below:
    
The acid strength of oxyacid of the same halogen increases with the increase in oxidation number of the halogen. For example, among the different oxyacids of chlorine the acidic character follows the order

HOCl < HClO2 < HClO3 < HClO4

Reason: the acid strength can be explained on the basis Lowry-Bronsted concept that conjucate base of weak and is strong and conjugate base of strong acid is weaker.

   Related Questions in Chemistry

  • Q : Solution problem What is the correct

    What is the correct answer. To made a solution of concentration of 0.03 g/ml of AgNO3, what quantity of AgNO3 must be added in 60 ml of solution: (a) 1.8  (b) 0.8  (c) 0.18  (d) None of these

  • Q : Nuclear Magnetic Resonance The nuclear

    The nuclear states produced by a magnetic field are studied in nuclear magnetic resonance spectroscopy.The frequency of the radiation that corresponds to the nuclear magnetic energy level spacings and the weakness of the radiation absorption that must be e

  • Q : Moles of HCl present in .70 L of a .33

    Detail the moles of HCl which are present in .70 L of a .33 M HCl solution?

  • Q : Molarity of Sodium hydroxide Select the

    Select the right answer of the question. Molarity of 4% NaOH solution is : (a) 0.1M (b) 0.5M (c) 0.01M (d) 0.05M

  • Q : Why medications include the hcl Why do

    Why do various medications include the hcl? Describe briefly?

  • Q : What are isotonic and hypotonic

    The two solutions which are having equivalent osmotic pressure are called isotonic solutions. The isotonic solutions at the same temperature also have same molar concentration. If we have solutions having different osmotic pressures then the solution having different

  • Q : Homework Silicon has three naturally

    Silicon has three naturally occurring isotopes. 28Si, mass = 27.976927; 29Si, mass = 28.976495; 30Si, mass = 29.973770 and 3.10% abundance. What is the abundance of 28Si?

  • Q : Organic and inorganic chemistry Write

    Write down a short note on the differences between the organic and inorganic chemistry?

  • Q : Diffusion Molecular View When the

    When the diffusion process is treated as the movement of particles through a solvent the diffusion coefficient can be related to the effective size of diffusing particles and the viscosity of the medium.To see how the experimental coefficients can be treat

  • Q : Problem associated to vapour pressure

    Provide solution of this question. 60 gm of Urea (Mol. wt 60) was dissolved in 9.9 moles, of water. If the vapour pressure of pure water is P0 , the vapour pressure of solution is:(a) 0.10P0 (b) 1.10P0 (c) 0.90P0 (d) 0.99P0