--%>

What are halogen oxoacids?

Fluorine yields only one oxyacid, hypofluorous acid (HOF). Chlorine, bromine and iodine form four series of acids with formulae: HOX, HXO2, HXO3 and HXO4, although many of these are known only in solutions or as salts.
    
The Hypohalous acids HOCl, HOBr and HOI are weak acids and are only formed in aqueous solutions by disproportionation of the halogen of the halogen water

X2 + H21402_Phosphorus trichloride.png  HOX + HX (X = Cl, Br, I)

Salts of these acids are known as hypohalites, e.g. bleaching powder, CaOCl2 is a common example of this category.
    
The halic acids HClO3 and HBrO3 are also known as solutions, but iodic acid HIO3 exists as a white solid. Thus, the stability of acids increases with increase in atomic number of the halogen. These acids act as strong oxidizing agents, e.g. these oxidize halides to give halogens in acid medium.

OX3- + 5X- + 6H+  1402_Phosphorus trichloride.png  3X2 + 3H2O

The salts of these are called halates. Amongst the halates, sodium chlorate (NaClO3and potassium chlorate (KClO3are prepared on industrial scale. It is also known as 'Berthelot salt'. NaClO3 is a powerful weed killer, whilst KClO3 is used in fireworks and matches.
    
Perhalic acid i.e. perchloric, periodic acids as well as their salts perchlorates and periodates are known to exist. The perhalates (MXO4)are prepared by the electrolytic oxidation of the corresponding halates, MXO3.

4ClO3 1402_Phosphorus trichloride.png  Cl+ 3ClO4-

The disproportionation of BrO3- to BrO4- is unfavorable, therefore per bromates are obtained only by oxidation of BrO3- by F2 in basic solution.

BrO3- + F2 + 2OH-  1402_Phosphorus trichloride.png  BrO4+ 2F- + H2O

Acidic character of oxyacids: the variation in the acidic character of the halogen acids in different oxidation states are summarized below:
    
The acid strength of oxyacid of the same halogen increases with the increase in oxidation number of the halogen. For example, among the different oxyacids of chlorine the acidic character follows the order

HOCl < HClO2 < HClO3 < HClO4

Reason: the acid strength can be explained on the basis Lowry-Bronsted concept that conjucate base of weak and is strong and conjugate base of strong acid is weaker.

   Related Questions in Chemistry

  • Q : Explain the catalyst definition and

    Catalyst is a substance which accelerates the rate of a chemical reaction without undergoing any change in its chemical composition or mass during the reaction. The phenomenon of increasing the rate of a reaction with the help of a catalyst is known as catalysis.

  • Q : Molecular substances what are the most

    what are the most important inorganic molecular substances for living beings?

  • Q : Composition of the vapour Choose the

    Choose the right answer from following. An ideal solution was obtained by mixing methanol and ethanol. If the partial vapour pressure of methanol and ethanol are 2.619KPa and 4.556KPa respectively, the composition of the vapour (in terms of mole fraction) will be: (

  • Q : Pressure and power for adiabatic

    a) Air flowing at 1 m3/s enters an adiabatic compressor at 20°C and 1 bar. It exits at 200°C. The isentropic efficiency of the compressor is 80%. Calculate the exit pressure and the power required. b) Steam enter

  • Q : Unit of mole fraction Provide solution

    Provide solution of this question. Unit of mole fraction is: (a) Moles/litre (b) Moles/litre2 (c) Moles-litre (d) Dimensionless

  • Q : Nuclear Magnetic Resonance The nuclear

    The nuclear states produced by a magnetic field are studied in nuclear magnetic resonance spectroscopy.The frequency of the radiation that corresponds to the nuclear magnetic energy level spacings and the weakness of the radiation absorption that must be e

  • Q : Application of colligative properties

    Choose the right answer from following. Colligative properties are used for the determination of: (a) Molar Mass (b) Equivalent weight (c) Arrangement of molecules (d) Melting point and boiling point (d) Both (a) and (b)  

  • Q : Problem on decinormal strength Can

    Can someone please help me in getting through this problem. How many grams of dibasic acid (having mol. wt. 200) must be present in 100ml  of its aqueous solution to provide decinormal strength: (i) 1g  (ii)2g  (iii) 10g  (iv) 20g<

  • Q : Structure of a DNA molecule Elaborate

    Elaborate the structure of a DNA molecule?

  • Q : Molarity in Nacl The molarity of 0.006

    The molarity of 0.006 mole of NaCl in 100 solutions will be: (i) 0.6 (ii) 0.06 (iii) 0.006 (iv) 0.066 (v) None of theseChoose the right answer from above.Answer: The right answer is (ii) M = n/ v(