--%>

What are haloalkanes and haloarenes and its properties?

Alkyl halides or haloalkanes are the compounds in which a halogen is bonded to an alkyl group. They have the general formula RX (where R is alkyl group, CnH2n+1 and X is halogen atom). These may be obtained from an alkane by replacement of one hydrogen atom by a halogen atom.

693_haloalkanes.png 

849_haloalkanes1.png 

Alkyl halides are classified as primary, secondary and tertiary alkyl halides depending on whether the halogen atom is attached to a primary, secondary or tertiary carbon atom respectively. For example,

2145_haloalkanes2.png 
     
Halogen derivatives of unsaturated hydrocarbons: replacement of some hydrogen atom in alkenes or alkynes by some halogen atom yields this type of halogen compounds. Some ordinary examples are listed below:

1273_haloalkanes3.png 

    
Aromatic halogen compound or haloarenes are the halogen compounds which contain at least one aromatic ring. Halogen derivatives of aromatic compounds can of two kinds:
    
Aryl halides: in these compounds, the halogen atom is directly combined to the carbon of benzene nucleus. They are also called nuclear substitution derivatives.
    
Aralkyl halides: in this type of compounds, halogen atom is linked to the carbon atom of the side chain. They are also called side chain substitution derivatives. 

The side chain derivatives are very similar to aliphatic halogen derivatives i.e. haloalkanes.
    
The halides in which halogen atom is attached to an sp3-hybridised carbon atom next to a carbon-carbon double bond are known as allylic halides.
    
The halides in which halogen atom is attached to one of the carbon atoms of a carbon-carbon double bond (C=C) are known as vinylic halides.
    
The halides in which halogen atom is attached to a carbon atom next to aromatic ring are known as benzylic halides.
    
In alkyl halides, allyl halides and benzyl halides halogen atom is bonded to an sp3 hybridized carbon atom.

Alkyl, allylic and benzylic halides may be further be classified as primary, secondary and tertiary halides.

In aryl halides and vinyl halides halogens atom is bonded to an sp2 hybridized carbon atom.

   Related Questions in Chemistry

  • Q : Number of moles present in water

    Provide solution of this question. How many moles of water are present in 180 of water: (a)1 mole (b)18 mole (c)10 mole (d)100 mole

  • Q : Haloalkene with the help of polarity of

    with the help of polarity of c-x bond show that aryl halides are less reactive than alkyl halides

  • Q : Donnan Membrane Equilibria The electric

    The electric charge acquired by macromolecules affects the equilibrium set up across a semipermeable membrane.Laboratory studies of macromolecule solutions as in osmotic pressure and dialysis studies confine the macromolecules to one compartment while allo

  • Q : Molarity of the final mixture Can

    Can someone please help me in getting through this problem. Two solutions of a substance (that is, non electrolyte) are mixed in the given manner 480 ml of 1.5M first solution + 520 ml of 1.2M second solution. Determine the molarity of the final mixture

  • Q : Define Bond Energies - Bond Charges

    Energy changes in some chemical reactions can be used to deduce the energies of chemical bonds. Our understanding of the molecular basis of thermodynamic properties is extended when we ask why the enthalpy change for a reaction is what it is. We deduce,

  • Q : Strength of any solution Give me answer

    Give me answer of this question. A solution contains 1.2046 x 1024 hydrochloric acid molecules in one dm3 of the solution. The strength of the solution is: (a) 6 N (b) 2 N (c) 4 N (d) 8 N

  • Q : Schrodinger equation with particle in a

    Three dimensional applications of the Schrodinger equation are introduced by the particle-in-a-box problem.So far only a one-dimensional problem has been solved by application of the Schrodinger equation. Now the allowed energies and the probability functi

  • Q : Molecular energies and speeds The

    The average translational kinetic energies and speeds of the molecules of a gas can be calculated.The result that the kinetic energy of 1 mol of the molecules of a gas is equal to 3/2 RT can be used to obtain numerical values for the

  • Q : Describe physical adsorption and its

    When the forces of attraction existing between adsorbate and adsorbent are van der Waal's forces, the adsorption is called physical adsorption. This type of adsorption is also known as physisorption or van der Waal's adsorption. Since the forces existing between adsorbent and adsorbate are very w

  • Q : Concentration of Barium chloride Give

    Give me answer of this question. If 5.0gm of BaCl2 is present in 106 gm solution, the concentration is: (a)1 ppm (b)5 ppm (c)50 ppm (d)1000 ppm