--%>
Assignment Help - homework help

What are condensation polymers? Give examples.

These types of polymers are formed as a result of condensation reaction between monomer units. Some common examples are being discussed here:


1. Polyesters
2047_condensation polymers.png 

(i) Terelene: It is a polymer obtained by the condensation reaction between ethylene glycol and terephthalic acid

Characteristics and uses: Terelene is resistant to the action of chemical and biological substances and also to abrasion. It has a less moisture absorbing capacity. As such it is widely used in making wash and wear fabrics. The polyster textile fabrics made from the polymer are marketed under the trade name Terelene or Dacron.

It is used as a blend with cotton and wool in clothing. It is also utilized in seat belts and sails. The polymer is also used as mylar in the preparation of films, magnetic recording tapes and for packing frazen food. Dacron (and Teflon) tubes are god substitutes for human blood vessels in heart by-pass operations.

(ii) Glyptic or Alkyd Resin: Glyptal is a common name of all polymers prepared by condensation of di-basic acids, and polyhydric alcohols. The simplest glyptal is poly (ethylene glycol phthalate) which is obtained by the condensation of ethylene glycol and pthlatic acid.

Characteristics and uses: these are three dimensional cross-linked polymers. Poly (ethylene glycol phthalate) dissolves in suitable solvents and the solution on evaporation leaves a tough and non-flexible film. Therefore, it is utilized in:

2. Polyamides
1162_condensation polymers1.png 


1. Nylon-6, 6: It is a polymer of adipic acid (1, 6-hexaneioic acid) and hexamethylene diamine (1, 6-diaminohexane)
 


Characteristics and uses: Nylon-66 (read as nylon-six-six) can be cast into a sheet or fibres by spinning devices. Nylon fibres generally have high tensile strength. They are hard and resistant to abrasion. They are also somewhat elastic in nature. Nylon finds uses in: producing bristles and brushes, carpets and fabrics in textile industry, elastic hosiery in the shape of crinkled nylon.

2. Nylon 6, 10: It is a polymer of hexamethylene diamine (six carbon atoms) and sebacoyl chloride (ten carbon atoms)
818_condensation polymer3.png 


3. Nylon-6 (or Perlon): It is prepared from the monomer caprolactum. Caprolactum is obtained from cyclohexane according to the reaction sequence given below:

Caprolactum on heating with traces of water hydrolyses to 6-amino caproic acid which on continued heating undergoes self-condensation and polymerises to give nylon-6.

Nylon-6 finds uses in the manufacture of tyre cords, fabrics and ropes.

 

 

 

 

 

 

   Related Questions in Chemistry

  • Q : Problems related to entropy change A)

    A) Two compartments each of 1 m3 capacity are joined by a valve and insulated from the surroundings and from one another. One compartment has saturated steam at 683.6 kPa and the other contains steam at the same temperature but at a pressure of 101.3 kPa. T

    		•
  • Q : Molar mass of compound The freezing

    The freezing point of a solution having 4.8 g of a compound in 60 g of benzene is 4.48. Determine the molar mass of the compound (Kf = 5.1 Km-1) , (freezing point of  benzene = 5.5oC)          &n

    		•
  • Q : Question based on mole concept Help me

    Help me to solve this Question. The number of moles of SO2Cl2 in 13.5 gm is in is : (a) 0.1 (b) 0.2 (c) 0.3 (d) 0.4

    		•
  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

    		•
  • Q : Molar concentration Choose the right

    Choose the right answer from following. Molar concentration (M) of any solution : a) No. of moles of solute/Volume of solution in litre (b) No. of gram equivalent of solute / volume of solution in litre (c) No. of moles os solute/ Mass of solvent in kg  (

    		•
  • Q : Coordination number of a cation The

    The coordination number of a cation engaging a tetrahedral hole is: (a) 6  (b) 8  (c) 12  (d) 4 Answer: (d) The co-ordination number of a cation occupying a tetrahedral hole is 4.

    		•
  • Q : How alkyl group reactions takes place?

    Halogenations: ethers react with chlorine and bromine to give substitution products. The extent of halogenations depends upon the conditions of reacti

    		•
  • Q : Simulate the column in HYSYS The

    The objective of this work is to separate a binary mixture and to cool down the bottom product for storage. (Check table below to see which mixture you are asked to study). 100 kmol of feed containing 10 mol percent of the lighter component enters a continuous distillation column at the m

    		•
  • Q : How molecule-molecule collisions takes

    An extension of the kinetic molecular theory of gases recognizes that molecules have an appreciable size and deals with molecule-molecule collisions. We begin studies of elementary reactions by investigating the collisions b

    		•
  • Q : P block why BiF3 is ionic whereas other

    why BiF3 is ionic whereas other trihalides are covalent in nature?

    		•