--%>

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Explain Polyatomic Vibrational Spectra

    Polyatomic molecules vibrate in a number of ways, and some of these vibrations can be studied by infrared absorption spectroscopy and some by Raman spectroscopy. The characters of transformation matrices for all 3n translation rotation vibration motio

  • Q : Molarity of the final mixture Can

    Can someone please help me in getting through this problem. Two solutions of a substance (that is, non electrolyte) are mixed in the given manner 480 ml of 1.5M first solution + 520 ml of 1.2M second solution. Determine the molarity of the final mixture

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

  • Q : What is depression in freezing point?

    Freezing point of a substance is the temperature at which solid and liquid phases of the substance coexist. It is defined as the temperature at which its solid and liquid phases have the same vapour pressure. The freezing point o

  • Q : Isotonic Solutions Which one of the

    Which one of the following pairs of solutions can we expect to be isotonic at the same temperature:(i) 0.1M Urea and 0.1M Nacl  (ii) 0.1M Urea and 0.2M Mgcl2  (iii) 0.1M Nacl and 0.1M Na2SO4  (iv) 0.1M Ca(NO3<

  • Q : Define Bond Energies - Bond Charges

    Energy changes in some chemical reactions can be used to deduce the energies of chemical bonds. Our understanding of the molecular basis of thermodynamic properties is extended when we ask why the enthalpy change for a reaction is what it is. We deduce,

  • Q : Mole fraction of hydrogen Give me

    Give me answer of this question. In a mixture of 1 gm H2 and 8 gm O2 , the mole fraction of hydrogen is: (a) 0.667 (b) 0.5 (c) 0.33 (d) None of these

  • Q : Quastion of finding vapour pressure

    Vapour pressure of CCl425Degree C at is 143mm of Hg0.5gm of a non-volatile solute (mol. wt. = 65) is dissolved in 100ml CCl4 .Find the vapour pressure of the solution (Density of CCl4 = = 1.58g /cm2): (a)141.43mm (b)

  • Q : Problem on normality Help me to solve

    Help me to solve this problem. 0.5 M of H2AO4 is diluted from 1 lire to 10 litre, normality of resulting solution is : (a)1 N (b) 0.1 N (c)10 N (d)11 N

  • Q : Vapour pressure over mercury Choose the

    Choose the right answer from following. At 300 K, when a solute is added to a solvent its vapour pressure over the mercury reduces from 50 mm to 45 mm. The value of mole fraction of solute will be: (a)0.005 (b)0.010 (c)0.100 (d)0.900