--%>
Assignment Help - homework help

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Problem on mol fraction of naphthalene

    At 20°C the solubility of solid naphthalene in hexane is 0.09 mol/mol of solution. Use this information and the data below to estimate the following for this system: a) The mol fraction of naphthalene in the vapour phase in equ

    		•
  • Q : Real vapour pressure Choose the right

    Choose the right answer from following. The pressure under which liquid and vapour can coexist at equilibrium is called the : (a) Limiting vapour pressure (b) Real vapour pressure (c) Normal vapour pressure (d) Saturated vapour pressure

    		•
  • Q : Problem on thermodynamic equilibrium In

    In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst: The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410&d

    		•
  • Q : Problem related to molarity Provide

    Provide solution of this question. Increasing the temperature of an aqueous solution will cause: (a) Decrease in molality (b) Decrease in molarity (c) Decrease in mole fraction (d) Decrease in % w/w

    		•
  • Q : Electrochemistry ( electrolysis of

    1. Define Faraday's first law of electrolysis 2. define Faraday's second law of electrolysis

    		•
  • Q : Calculate PH value for a acetic acid 1.

    1. A solution of 0.100 M acetic acid is prepared. a) What is its pH value? b) If 20% of the initial acetic acid is converted to the acetate form by titration with NaOH, what is the resultant pH?

    		•
  • Q : What is chemisorption or chemical

    When the forces of attraction existing between adsorbate particles and adsorbent almost of the same strength as chemical bonds, the adsorption is called chemical adsorption. This type of adsorption is also known as chemisorptions. Since forces of attraction existing b

    		•
  • Q : Henry law question Answer the following

    Answer the following qustion. The definition “The mass of a gas dissolved in a particular mass of a solvent at any temperature is proportional to the pressure of gas over the solvent” is: (i) Dalton’s Law of Parti

    		•
  • Q : Molarity of the final mixture Can

    Can someone please help me in getting through this problem. Two solutions of a substance (that is, non electrolyte) are mixed in the given manner 480 ml of 1.5M first solution + 520 ml of 1.2M second solution. Determine the molarity of the final mixture

    		•
  • Q : Forms a molecule to an organic molecule

    Briefly state what forms a molecule to an organic molecule?

    		•