--%>

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Question related to molarity Help me to

    Help me to go through this problem. Molarity of a solution containing 1g NaOH in 250ml of solution: (a) 0.1M (b) 1M (c) 0.01M (d) 0.001M

  • Q : Molar and Volumetric flow rate problem

    Cyclohexane (C6H12) is produced by mixing Benzene and hydrogen. A process including a reactor, separator, and recycle stream is used to produce Cyclohexane. The fresh feed contains 260L/min C6H6 with 950 L/min of H2

  • Q : Explain the mechanism of Enzyme

    A mechanism for enzyme-catalyzed reactions that leads to the typical rate equation for these reactions can be described.A variety of rate equations are required to portray the rates of enzymes catalyzed reagents and physical conditions that are encountered

  • Q : Define tripod and its use Illustrate a

    Illustrate a tripod? And how it’s used?

  • Q : Describe physical adsorption and its

    When the forces of attraction existing between adsorbate and adsorbent are van der Waal's forces, the adsorption is called physical adsorption. This type of adsorption is also known as physisorption or van der Waal's adsorption. Since the forces existing between adsorbent and adsorbate are very w

  • Q : Number of moles of potassium chloride

    Choose the right answer from following. The number of moles of KCL in 1000ml of 3 molar solution is: (a)1 (b)2 (c)3 (d)1.5

  • Q : Colligative properties give atleast two

    give atleast two application of following colligative properties

  • Q : Units of Measurement Unit of

      Unit of measurement- These are also some systems for units:      (1) 

  • Q : Mole fraction of benzene Choose the

    Choose the right answer from following. In a solution of 8.7g benzene C6H6 and 46.0 gm toluene ,(C6, H5, CH3) the mole fraction of benzene in this solution is: (a)1/6 (b)1/5 (c)1/2 (d)1/3

  • Q : Modern periodic table and Mendeleevs

    Differentiate between the modern periodic table and Mendeleevs table?