--%>

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Precipitation problem On passing H 2 S 

    On passing H2S  gas through a solution of Cu+ and Zn+2 ions, CuS is precipitated first because: (i) Solubility product of CuS is equal to the ionic product of ZnS (ii) Solubility product of CuS is equal to the solubility product o

  • Q : Volume hydrogen peroxide Choose the

    Choose the right answer from following. The normality of 10 lit. volume hydrogen peroxide is: (a) 0.176 (b) 3.52 (c) 1.78 (d) 0.88 (e)17.8

  • Q : Problem on molality Select the right

    Select the right answer of the question. Calculate the molality of 1 litre solution of 93% H2SO4 (weight/volume). The density of the solution is 1.84 g /ml : (a) 10.43 (b) 20.36 (c) 12.05 (d) 14.05

  • Q : Whether HCl is a base or an acid

    Whether HCl is a base or an acid? Briefly state your comments?

  • Q : Dissolving Group IV Carbonate Explain

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid.

  • Q : What are Ethers and its types? Ethers

    Ethers are the compounds with general formula or CnH2n+

  • Q : Chem Silicon has three naturally

    Silicon has three naturally occurring isotopes. 28Si, mass = 27.976927; 29Si, mass = 28.976495; 30Si, mass = 29.973770 and 3.10% abundance. What is the abundance of 28Si?

  • Q : Relationship between Pressure and

    The pressure-temperature relation for solid-vapor or liquid vapor equilibrium is expressed by the Clausis-Clapeyron equation.We now obtain an expression for the pressure-temperature dependence of the state of equilibrium between two phases. To be specific,

  • Q : What is laser and explain its working?

    Laser action relies on a non-Boltzmann population inversion formed by the absorption of radiation and vibrational deactivation that forms a long lived excited electronic state. An excited state molecule can move to a lower energy state or return to the

  • Q : Which is polar HCl or HF Which one is

    Which one is polar HCl or HF?