--%>

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Amines arrange in decreasing order of

    arrange in decreasing order of basicity pi pyridine,pyridine,pyrrole, morphine

  • Q : Extensive property Choose the right

    Choose the right answer from following. Which one of the following is an extensive property: (a) Molar volume (b) Molarity (c) Number of moles (d) Mole fraction

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

  • Q : Calculating weight of acid Give me

    Give me answer of this question. The formula weight of H2SO4 is 98. The weight of the acid in 400mi of solution is: (a)2.45g (b) 3.92g (c) 4.90g (d) 9.8g

  • Q : Effect on vapour pressure of dissolving

    Give me answer of this question. When a substance is dissolved in a solvent the vapour pressure of the solvent is decreased. This results in: (a) An increase in the b.p. of the solution (b) A decrease in the b.p. of the solvent (c) The solution having a higher fr

  • Q : Mole 2.0gram of dolomite is heated to a

    2.0gram of dolomite is heated to a constant weight of 1.0g. Calculate the total volume of CO2 produced at STP by this reation

  • Q : What are diazonium salts? The diazonium

    The diazonium salts are represented by the general formula ArN2 +X where X- ion may be anion such as (Cl) ¨, B ¨r, HSO

  • Q : Liquid Vapour Free Energies The free

    The free energy of a component of a liquid solution is equal to its free energy in the equilibrium vapour.Partial molal free energies let us deal with the free energy of the components of a solution. We use these free energies, or simpler concentration ter

  • Q : Problem on normality Help me to solve

    Help me to solve this problem. 0.5 M of H2AO4 is diluted from 1 lire to 10 litre, normality of resulting solution is : (a)1 N (b) 0.1 N (c)10 N (d)11 N

  • Q : Colligative property related question

    Select the right answer of the question. Which of the following is not a colligative property : (a) Osmotic pressure (b) Elevation in B.P (c) Vapour pressure (d) Depression in freezing point