--%>
Assignment Help - homework help

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : What are different mechanisms for

    Nucleophilic substitution reactions in halides containing  - X bond may take place through either of the two different mechanisms,S<

    		•
  • Q : Colligative properties give atleast two

    give atleast two application of following colligative properties

    		•
  • Q : Explain Solid Compound Formation. In

    In some two component, solid liquid systems, a solid compound forms.In systems in which the components have an interaction for such other, a solid state compound of the two compounds of the two components can form.Formic acid and formaide form a solid state, one-to-one com

    		•
  • Q : Calculating total number of moles

    Choose the right answer from following. While 90 gm of water is mixed with 300 gm of acetic acid. The total number of moles will be: (a)5 (b)10 (c)15 (d)20

    		•
  • Q : Molarity what is the molarity of the

    what is the molarity of the solution prepared by dissolving 75.5 g of pure KOH in 540 ml of solution

    		•
  • Q : Mole fraction of Carbon dioxide Choose

    Choose the right answer from following. If we take 44g of CO2 and 14g of N2 what will be mole fraction of CO2 in the mixture: (a) 1/5 (b) 1/3 (c) 2/3 (d) 1/4

    		•
  • Q : Question 6 A student was analyzing an

    A student was analyzing an unknown containing only Group IV cations. When the unknown was treated with 3M (NH4)2CO3 solution, a white precipitate formed. Because the acetic acid bottle was empty, the student used 6M HCl to dissolve the precipitate. Following the procedure of this experiment, the stu

    		•
  • Q : How to calculate solutions ionic

    Transference numbers and molar conductors can be used to calculate ionic mobilities. This tables under is giving the transference numbers for positive ions at 25 degree C and the values obtained by extrapolation to infinite dilution:

    Q : How alkyl group reactions takes place?

    Halogenations: ethers react with chlorine and bromine to give substitution products. The extent of halogenations depends upon the conditions of reacti

    		•
  • Q : Formula of diesel Write a short note on

    Write a short note on the formula of diesel, petrol and also CNG?

    		•