--%>
Assignment Help - homework help

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Dipole moment direction for the methanol

    Briefly describe the dipole moment direction for the methanol?

    		•
  • Q : What are condensation polymers? Give

    These types of polymers are formed as a result of condensation reaction between monomer units. Some common examples are being discussed here: 1. Polyesters 2047_condensat</span></p> </div> <!-- /comment-box --> </li> </td> </tr><tr> <td> <li> <div class=

    Q : What is depression in freezing point?

    Freezing point of a substance is the temperature at which solid and liquid phases of the substance coexist. It is defined as the temperature at which its solid and liquid phases have the same vapour pressure. The freezing point o

    		•
  • Q : Molarity of cane sugar solution 171 g

    171 g of cane sugar (C12H22O11)  is dissolved in one litre of water. Find the molarity of the solution: (i) 2.0 M (ii) 1.0 M (iii) 0.5 M (iv) 0.25 M Choose the right answer from above.

    		•
  • Q : Production of alcoholic drinks give all

    give all physical aspects in the production of alcohol

    		•
  • Q : Problem on endothermic or exothermic At

    At low temperatures, mixtures of water and methane can form a hydrate (i.e. a solid containing trapped methane). Hydrates are potentially a very large source of underground trapped methane in the pole regions but are a nuisance when they form in pipelines and block th

    		•
  • Q : Functions of centrioles Describe

    Describe briefly the functions of centrioles?

    		•
  • Q : Number of electrons in the benzene

    Describe the number of electrons in the benzene? Write a short note on it?

    		•
  • Q : Non-ideal Gases Fugacity The fugacity

    The fugacity is a pressure like quantity that is used to treat the free energy of nonideal gases.Now we begin the steps that allow us to relate free energy changes to the equilibrium constant of real, nonideal gases. The thermodynamic reaction 

    		•
  • Q : Sugar solution The solution of sugar in

    The solution of sugar in water comprises: (i) Free atoms (ii) Free ions (iii) Free molecules (iv) Free atom and molecules. Choose the right answer from the above.

    		•