--%>

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Define Bond Energies - Bond Charges

    Energy changes in some chemical reactions can be used to deduce the energies of chemical bonds. Our understanding of the molecular basis of thermodynamic properties is extended when we ask why the enthalpy change for a reaction is what it is. We deduce,

  • Q : Molecular Properties Symmetry Molecular

    Molecular orbitals and molecular motions belong to certain symmetry species of the point group of the molecule.Examples of the special ways in which vectors or functions can be affected by symmetry operations are illustrated here. All wave functions soluti

  • Q : What is schrodinger wave equation? The

    The Schrodinger wave equation generalizes the fitting-in-of-waves procedure.The waves that "fit" into the region to which the particle is contained can be recognized "by inspection" only for a few simple systems. For other problem a mathematical procedure

  • Q : Why acetic has less conductivity than

    Illustrate the reason, why acetic has less conductivity than Hcl?

  • Q : Solutions The normality of 10 lit.

    The normality of 10 lit. volume hydrogen peroxide is: (a) 0.176 (b) 3.52 (c) 1.78 (d) 0.88 (e)17.8

  • Q : What are electromotive force in

    The main objective of this particular aspect of Physical Chemistry is to examine the relation between free energies and the mechanical energy of electromotive force of electrochemical cells. The ionic components of aqueous solutions can be treated on the basis of the

  • Q : Describe various systems for

    Common system According to this system, the individual members are named according to alkyl groups att

  • Q : Colligative properties give atleast two

    give atleast two application of following colligative properties

  • Q : Problem on bubble point The following

    The following mixture of hydrocarbons is obtained as one stream in a petroleum refinery.

    Q : Polyhalogen compounds we need 10

    we need 10 examples for the polyhalogen compounds....please help me....need it urgently...