--%>

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Molecular weight of substance The

    The boiling point of a solution of 0.11 gm of a substance in 15 gm of ether was found to be 0.1oC higher than that of the pure ether. The molecular weight of the substance will be (Kb = 2.16)       (a) 148 &nbs

  • Q : Haloalkane how haloalkane can be

    how haloalkane can be prepared by refluxing alcohol with hydrohalic acids

  • Q : What is electrolysis? Explain with

    Passage of a current through a solution can produce an electrolysis reaction.Much additional information on the properties of the ions in an aqueous solution can be obtained from studies of the passage of a direct current (dc) through a cell containing a s

  • Q : Partial vapour pressure of volatile

    Choose the right answer from following. For a solution of volatile liquids the partial vapour pressure of each component in solution is directly proportional to: (a) Molarity (b) Mole fraction (c) Molality (d) Normality

  • Q : Finding Normality Can someone please

    Can someone please help me in getting through this problem. Concentrated H2SO4 has a density of 1.98 gm/ml and is 98% H2SO4 by weight. The normality is: (a) 2 N  (b) 19.8 N  (c) 39.6 N  (d) 98

  • Q : Significance of the organic chemistry

    Describe some of the significance of the organic chemistry in brief?

  • Q : Reason for medications contain hcl What

    What is the reason behind this that some medications contain hcl?

  • Q : Explain reactions of carbonyl oxygen

    In these reaction oxygen atom of carbonyl group is replaced by either one divalent group or two monovalent groups. Reaction by ammonia derivatives: aldehydes and ketones react with a number of ammonia derivatives such as hydroxylaminem hydrazine, semicarbazide etc. in weak acidic medium.

  • Q : Mole fraction of Carbon dioxide Choose

    Choose the right answer from following. If we take 44g of CO2 and 14g of N2 what will be mole fraction of CO2 in the mixture: (a) 1/5 (b) 1/3 (c) 2/3 (d) 1/4

  • Q : Molarity A solution has volume 200ml

    A solution has volume 200ml and molarity 0.1.if it is diluted 5times then calculate the molarity of reasulying solution and the amount of water added to it.