--%>

Problem on thermodynamic equilibrium

In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst:

The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410°C with the following composition:

N2     79 vol%
SO2   10 vol%
O2     11 vol%

a) If the reactor exit stream is at thermodynamic equilibrium, what is the temperature and composition of the gas?

b) What will be the effect of each of the following changes on the equilibrium conversion? Will the conversion increase, decrease or remain the same? Why?

i) an increase in the reactor inlet temperature.
ii) an increase in the operating pressure.

Data:

Δh°rxn at 298 K = -98.923 kJ/mol
Δg°rxn = -98.893 + 0.0941 T(K) kJ/mol

2472_ques2.jpg

   Related Questions in Chemistry

  • Q : Molecular weight of substance The

    The boiling point of a solution of 0.11 gm of a substance in 15 gm of ether was found to be 0.1oC higher than that of the pure ether. The molecular weight of the substance will be (Kb = 2.16)       (a) 148 &nbs

  • Q : Molecular Diameters The excluded volume

    The excluded volume b, introduced by vander Wall's as an empirical correction term, can be related to the size gas molecules. To do so, we assume the excluded volume is the result of the pairwise coming together of molecules. This assumption is justified when b values

  • Q : Molarity based question Help me to

    Help me to solve this problem. 4.0 gm of NaOH are contained in one decilitre of solution. Its molarity would be: (a) 4 M (b)2 M (c)1 M (d)1.5 M

  • Q : What are various structure based

    This classification of polymers is based upon how the monomeric units are linked together. Based on their structure, the polymers are classified as: 1. Linear polymers: these are the polymers in which monomeric units are linked together to form long straight c

  • Q : Molarity 20mol of hcl solution requires

    20mol of hcl solution requires 19.85ml of 0.01 M NAOH solution for complete neutralisation. the molarity of hcl solution

  • Q : Molality of Sulfuric acid Choose the

    Choose the right answer from following. The molality of 90% H2SO4 solution is: [density=1.8 gm/ml]  (a)1.8 (b) 48.4 (c) 9.18 (d) 94.6

  • Q : Entropy is entropy on moleculare basis

    is entropy on moleculare basis relates to the tras.,vib.,and rotational motions?

  • Q : Neutralisation of phosphorous acids

    Provide solution of this question. To neutralise completely 20 mL of 0.1 M aqueous solution of phosphorous acid (H3 PO3) the volume of 0.1 M aqueous KOH solution required is: (a) 40 mL (b) 20 mL (c) 10 mL (d) 60 mL

  • Q : Describe characteristics of halides and

    Halides characteristics

  • Q : Facts on evaporation Illustrate the 3

    Illustrate the 3 facts on evaporation?