--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : What is Elevation in boiling point? The

    The boiling of a liquid may be defused by the temperature at which its vapour pressure which is equal to atmospheric pressure. The effect of addition in a non-volatile solute on the boiling point shown and its solution containing non-volatile solute with tempe

    		•
  • Q : Molarity Give me answer of this

    Give me answer of this question. If 20ml of 0.4N, NaoH solution completely neutralises 40ml of a dibasic acid. The molarity of the acid solution is:(a) 0.1M (b) 0.2M (c)0.3M (d)0.4M

    		•
  • Q : Explain Ionic Bond with examples. The

    The bonding in ionic molecules can be described with a coulombic attractive term.For some diatomic molecules we take quite a different approach from that used in preceding sections to describe the bonding. Ionic bonds are interpreted in terms of the coulom

    		•
  • Q : Number of electrons in the benzene

    Describe the number of electrons in the benzene? Write a short note on it?

    		•
  • Q : Strength of the Hydrochloric acid

    Provide solution of this question. 1.0 gm of pure calcium carbonate was found to need 50 ml of dilute HCL for complete reaction. The strength of the HCL solution is specified by : (a) 4 N (b) 2 N (c) 0.4 N (d) 0.2 N

    		•
  • Q : P block bif3 is ionic while other

    bif3 is ionic while other trihalides are covalent in nature

    		•
  • Q : Explain the mechanism of Enzyme

    A mechanism for enzyme-catalyzed reactions that leads to the typical rate equation for these reactions can be described.A variety of rate equations are required to portray the rates of enzymes catalyzed reagents and physical conditions that are encountered

    		•
  • Q : What are electromotive force in

    The main objective of this particular aspect of Physical Chemistry is to examine the relation between free energies and the mechanical energy of electromotive force of electrochemical cells. The ionic components of aqueous solutions can be treated on the basis of the

    		•
  • Q : What are isotonic and hypotonic

    The two solutions which are having equivalent osmotic pressure are called isotonic solutions. The isotonic solutions at the same temperature also have same molar concentration. If we have solutions having different osmotic pressures then the solution having different

    		•
  • Q : How alkyl group reactions takes place?

    Halogenations: ethers react with chlorine and bromine to give substitution products. The extent of halogenations depends upon the conditions of reacti

    		•