--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Calculating Formulae Superphosphate has

    Superphosphate has the formula CaH4(PO4)2 H2O, what is the calculation to get the percentage of Phosphorus, I need to show the calculation. I know it is 30.9737622 u in weight and 2 atoms of the formula, but not sure how to work the calculation backwards.

    		•
  • Q : Vapour pressure of the pure hydrocarbons

    Give me answer of this question. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of the pure hydrocarbons at 20°C are 440 mmHg for pentane and 120 mmHg for hexane. The mole fraction of pentane in the vapour phase would be: (a) 0.549 (b)

    		•
  • Q : Molar concentration Choose the right

    Choose the right answer from following. Molar concentration (M) of any solution : a) No. of moles of solute/Volume of solution in litre (b) No. of gram equivalent of solute / volume of solution in litre (c) No. of moles os solute/ Mass of solvent in kg  (

    		•
  • Q : Describe various systems for

    Common system According to this system, the individual members are named according to alkyl groups att

    		•
  • Q : Calculating total number of moles

    Choose the right answer from following. While 90 gm of water is mixed with 300 gm of acetic acid. The total number of moles will be: (a)5 (b)10 (c)15 (d)20

    		•
  • Q : F-centres If a electron is present in

    If a electron is present in place of anion in a crystal lattice, then it is termed as: (a) Frenkel defect  (b) Schottky defect  (c) Interstitial defects (d) F-centre Answer: (d) When electrons are trapped in anion vacancies, thes

    		•
  • Q : Thermodynamics I) Sulphur dioxide (SO2)

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267

    		•
  • Q : Group IV Cations Chromium(III)

    Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer.

    		•
  • Q : Colligative properties give atleast two

    give atleast two application of following colligative properties

    		•
  • Q : Molar mass of compound The freezing

    The freezing point of a solution having 4.8 g of a compound in 60 g of benzene is 4.48. Determine the molar mass of the compound (Kf = 5.1 Km-1) , (freezing point of  benzene = 5.5oC)          &n

    		•