--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Meaning of molality of a solution The

    The molality of a solution will be: (i) Number of moles of solute per 1000 ml of solvent (ii) Number of moles of solute per 1000 gm of solvent (iii) Number of moles of solute per 1000 ml of solution (iv) Number of gram equivalents of solute per 1000 m

    		•
  • Q : Functions of centrioles Describe

    Describe briefly the functions of centrioles?

    		•
  • Q : Question of vapour pressure Choose the

    Choose the right answer from following. Vapour pressure of a solution is: (a) Directly proportional to the mole fraction of the solvent (b) Inversely proportional to the mole fraction of the solute (c) Inversely proportional to the mole fraction of the solvent (d

    		•
  • Q : Organic and inorganic substances living

    living beings are made up of organic and inorganic substances.according to their complexity of their molecules how can ach of these substances be classified?

    		•
  • Q : Theory of three dimensional motion

    Partition function; that the translational energy of 1 mol of molecules is 3/2 RT will come as no surprise. But the calculation of this result further illustrates the use of quantized states and the partition function to obtain macroscopic properties. The partition fu

    		•
  • Q : Particles of quartz Particles of quartz

    Particles of quartz are packed by:(i) Electrical attraction forces  (ii) Vander Waal's forces  (iii) Covalent bond forces  (iv) Strong electrostatic force of attraction Answer: (iii)

    		•
  • Q : How to establish nomenclature for

    In the common chemistry terminologies, aliphatic halogen derivatives are named as alkyl halides. The words, n-, sec-, tert-, iso-, neo-, and amyl are

    		•
  • Q : What are Ethers and its types? Ethers

    Ethers are the compounds with general formula or CnH2n+

    		•
  • Q : Value of molar solution Select the

    Select the right answer of the question. Molar solution contains: (a)1000g of solute (b)1000g of solvent (c)1 litre of solvent (d)1 litre of solution

    		•
  • Q : Question associated to vapour pressure

    Choose the right answer from following. The vapour pressure lowering caused by the addition of 100 g of sucrose(molecular mass = 342) to 1000 g of water if the vapour pressure of pure water at 25degree C is 23.8 mm Hg: (a)1.25 mm Hg (b) 0.125 mm Hg (c) 1.15 mm H

    		•