--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : What are isotonic and hypotonic

    The two solutions which are having equivalent osmotic pressure are called isotonic solutions. The isotonic solutions at the same temperature also have same molar concentration. If we have solutions having different osmotic pressures then the solution having different

  • Q : Explain structure basicity of amines.

    Basic character of amines is related to their structural arrangement. Basic strength of amines depends on the relative ease of formation of the corresponding cation by accepting a proton from the acid. Greater the stability of cation is, more is basic strength of amine.Alkyl a

  • Q : Molarity of solution Help me to go

    Help me to go through this problem. When 7.1gm Na2SO4 (molecular mass 142) dissolves in 100ml H2O , the molarity of the solution is: (a) 2.0 M (b) 1.0 M (c) 0.5 M (d) 0.05 M

  • Q : Relationship between Pressure and

    The pressure-temperature relation for solid-vapor or liquid vapor equilibrium is expressed by the Clausis-Clapeyron equation.We now obtain an expression for the pressure-temperature dependence of the state of equilibrium between two phases. To be specific,

  • Q : Direction of dipole moment expected

    Illustrate the direction of the dipole moment expected for hydrogen bromide?

  • Q : How to calculate solutions ionic

    Transference numbers and molar conductors can be used to calculate ionic mobilities. This tables under is giving the transference numbers for positive ions at 25 degree C and the values obtained by extrapolation to infinite dilution:

    Q : Molarity of Barium hydroxide 25 ml of a

    25 ml of a solution of barium hydroxide on titration with 0.1 molar solution of the hydrochloric acid provide a litre value of 35 ml. The molarity of barium hydroxide solution will be: (i) 0.07 (ii) 0.14 (iii) 0.28 (iv) 0.35

  • Q : Analytical chemistry 37% weight of HCl

    37% weight of HCl and density is 1.1g/ml. find molarity of HCl

  • Q : Infrared Adsorption The adsorption of

    The adsorption of infrared radiation by diatomic molecules increases the vibrational energy fo molecules and gives information about the force constant for the "spring" of the molecule.;The molecular motion that has the next larger energy level spacing aft

  • Q : Question based on normality Provide

    Provide solution of this question. A 5 molar solution of H2SO4 is diluted from 1 litre to 10 litres. What is the normality of the solution : (a) 0.25 N (b) 1 N (c) 2 N (d) 7 N