--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Describe chemical properties of amines.

    Like ammonia, primary, secondary and tertiary amines have a single pair of electrons on N atom. Hence chemical behavior of amines is similar to ammonia. Amines are basic in nature, and in most of the reactions they act as nucleophiles.      1. Reaction wi

  • Q : What do you mean by the term dipole

    What do you mean by the term dipole moment? Briefly describe it.

  • Q : Problem on vapour pressure Choose the

    Choose the right answer from following. If P and P are the vapour pressure of a solvent and its solution respectively N1 and N2 and are the mole fractions of the solvent and solute respectively, then correct relation is: (a) P= PoN1 (b) P= Po N2 (c)P0= N2 (d)

  • Q : Molar mass what is the equation for

    what is the equation for calculating molar mass of non volatile solute

  • Q : Molar conductance what is the molar

    what is the molar conductance of chloropentaamminecobalt(III) chloride?

  • Q : Sugar solution The solution of sugar in

    The solution of sugar in water comprises: (i) Free atoms (ii) Free ions (iii) Free molecules (iv) Free atom and molecules. Choose the right answer from the above.

  • Q : Problem on moles of solution The number

    The number of moles of a solute in its solution is 20 and total no. of moles are 80. The mole fraction of solute wil be: (a) 2.5 (b) 0.25 (c) 1 (d) 0.75

  • Q : Problem on partial pressure i) Show

    i) Show that the equilibrium constant Kp for the reaction CaCo3(s) ↔ CaO(s) +CO2(g)is about unity (i.e. = 1.0) at 895 °C.ii) If two grams of calcium carbonate are pl

  • Q : Neutralization of sodium hydroxide How

    How much of NaOH is needed to neutralise 1500 cm3 of 0.1N HCl (given = At. wt. of Na =23): (i) 4 g  (ii) 6 g (iii) 40 g  (iv) 60 g

  • Q : Define thermal energy The thermal part

    The thermal part of the internal energy and the enthalpy of an ideal gas can be given a molecular level explanation. All the earlier development of internal energy and enthalpy has been "thermodynamic". We have made no use o