--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Question related to molarity Help me to

    Help me to go through this problem. Molarity of a solution containing 1g NaOH in 250ml of solution: (a) 0.1M (b) 1M (c) 0.01M (d) 0.001M

    		•
  • Q : Group IV Cations Chromium(III)

    Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer.

    		•
  • Q : Molar mass of solute The boiling point

    The boiling point of benzene is 353.23 K. If 1.80 gm of a non-volatile solute was dissolved in 90 gm of benzene, the boiling point is increased to 354.11 K. Then the molar mass of the solute is: (a) 5.8g mol-1  (b)

    		•
  • Q : BASIC CHARACTER OF AMINES IN GAS PHASE,

    IN GAS PHASE, BASICITIES OF THE AMINES IS JUST OPPOSITE TO BASICITY OF AMINES IN AQEUOUS PHASE .. EXPLAIN

    		•
  • Q : Explain solid in liquid solutions. The

    The French chemist Francois Marie Raoult (1886) carried out a series of experiments to study the vapour pressure of a number of binary solutions. On the basis of the results of the experiments, he proposed a generalization called Raoult's law which states that, <

    		•
  • Q : Calculating Formulae Superphosphate has

    Superphosphate has the formula CaH4(PO4)2 H2O, what is the calculation to get the percentage of Phosphorus, I need to show the calculation. I know it is 30.9737622 u in weight and 2 atoms of the formula, but not sure how to work the calculation backwards.

    		•
  • Q : The three facts on the evaporation

    Describe briefly the three facts on the evaporation?

    		•
  • Q : Relative lowering of vapour pressure

    Which of the following solutions will have a lower vapour pressure and why? a) A 5% aqueous solution of cane sugar. b) A 5% aqueous solution of urea.

    		•
  • Q : Moles of HCl present in .70 L of a .33

    Detail the moles of HCl which are present in .70 L of a .33 M HCl solution?

    		•
  • Q : Strength of the Hydrochloric acid

    Provide solution of this question. 1.0 gm of pure calcium carbonate was found to need 50 ml of dilute HCL for complete reaction. The strength of the HCL solution is specified by : (a) 4 N (b) 2 N (c) 0.4 N (d) 0.2 N

    		•