--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Statement of Henry law Determine the

    Determine the correct regarding Henry’s law: (1) The gas is in contact with the liquid must behave as an ideal gas (2) There must not be any chemical interaction among the gas and liquid (3) The pressure applied must be high (4) All of these.

  • Q : PH of an Alkyl Halide Briefly state the

    Briefly state the pH of an Alkyl Halide?

  • Q : Calculating total number of moles

    Choose the right answer from following. While 90 gm of water is mixed with 300 gm of acetic acid. The total number of moles will be: (a)5 (b)10 (c)15 (d)20

  • Q : Chem Silicon has three naturally

    Silicon has three naturally occurring isotopes. 28Si, mass = 27.976927; 29Si, mass = 28.976495; 30Si, mass = 29.973770 and 3.10% abundance. What is the abundance of 28Si?

  • Q : Analytical chemistry 37% weight of HCl

    37% weight of HCl and density is 1.1g/ml. find molarity of HCl

  • Q : Solubility product On passing H 2 S gas

    On passing H2S gas through a particular solution of Cu+ and Zn+2 ions, first CuS is precipitated because : (a)Solubility product of CuS is equal to the ionic product of ZnS (b) Solubility product of CuS is equal to the solubility product

  • Q : Strength of any solution Give me answer

    Give me answer of this question. A solution contains 1.2046 x 1024 hydrochloric acid molecules in one dm3 of the solution. The strength of the solution is: (a) 6 N (b) 2 N (c) 4 N (d) 8 N

  • Q : Organic structure of cetearyl alcohol

    Can we demonstration the organic structure of cetearyl alcohol and state me what organic family it is?

  • Q : Problem on mol fraction of naphthalene

    At 20°C the solubility of solid naphthalene in hexane is 0.09 mol/mol of solution. Use this information and the data below to estimate the following for this system: a) The mol fraction of naphthalene in the vapour phase in equ

  • Q : What do you mean by the term dipole

    What do you mean by the term dipole moment? Briefly describe it.