--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Describe various systems for

    Common system According to this system, the individual members are named according to alkyl groups att

  • Q : Henry law question Answer the following

    Answer the following qustion. The definition “The mass of a gas dissolved in a particular mass of a solvent at any temperature is proportional to the pressure of gas over the solvent” is: (i) Dalton’s Law of Parti

  • Q : Analytical chemistry 37% weight of HCl

    37% weight of HCl and density is 1.1g/ml. find molarity of HCl

  • Q : Problem on reversible and irreversible

    The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.   a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a r

  • Q : Question 6 A student was analyzing an

    A student was analyzing an unknown containing only Group IV cations. When the unknown was treated with 3M (NH4)2CO3 solution, a white precipitate formed. Because the acetic acid bottle was empty, the student used 6M HCl to dissolve the precipitate. Following the procedure of this experiment, the stu

  • Q : Why aryl halides are less reactive?

    Aryl halides are much less reactive towards nucleophilic substitution reactions than haloalkanes. The less reactivity of aryl halides can be described

  • Q : Calculation of molecular weight Provide

    Provide solution of this question. In an experiment, 1 g of a non-volatile solute was dissolved in 100 g of acetone (mol. mass = 58) at 298K. The vapour pressure of the solution was found to be 192.5 mm Hg. The molecular weight of the solute is (vapour pressure of ace

  • Q : Q what is the basicity of primary

    what is the basicity of primary secondary and tertiary amines in chlorobenzene

  • Q : Sugar solution The solution of sugar in

    The solution of sugar in water comprises: (i) Free atoms (ii) Free ions (iii) Free molecules (iv) Free atom and molecules. Choose the right answer from the above.

  • Q : Vant Hoff factor The Van't Hoff factor

    The Van't Hoff factor of the compound K3Fe(CN)6 is: (a) 1  (b) 2  (c) 3  (d) 4  Answer: (d) K3[Fe(CN)6] → 3K+