--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Relative lowering of vapour pressure

    explain the process of relative lowering of vapour pressure

    		•
  • Q : Meaning of Molar solution Molar

    Molar solution signifies 1 mole of solute present/existed in: (i) 1000g of solvent (ii) 1 litre of solvent (iii) 1 litre of solution (iv) 1000g of solution

    		•
  • Q : Molecular weight of substance The

    The boiling point of a solution of 0.11 gm of a substance in 15 gm of ether was found to be 0.1oC higher than that of the pure ether. The molecular weight of the substance will be (Kb = 2.16)       (a) 148 &nbs

    		•
  • Q : Modern periodic table and Mendeleevs

    Differentiate between the modern periodic table and Mendeleevs table?

    		•
  • Q : Ddd 4) The addition of S2- ion to

    4) The addition of S2- ion to Fe(OH)2(s). Explain why the addition of S2- ion to Cr(OH)3(s) does not result in the formation of Cr2S3(s).

    		•
  • Q : Molarity of HCl solution 20 ml of HCL

    20 ml of HCL solution needs 19.85 ml of 0.01M NaOH solution for complete neutralization. Morality of the HCL solution is:  (i) 0.0099 (ii) 0.099 (iii) 0.99 (iv) 9.9 Choose the right answer from above.

    		•
  • Q : Calculating density of water using

    What is the percent error in calculating the density of water using the ideal gas law for the following conditions:  a. 110 oC, 1 bar   b. 210 oC 10 bar  c. 374 o

    		•
  • Q : Ionic radius of chloride ion The edge

    The edge length of the unit cell of Nacl crystal lattice is 552 pm. If ionic radius of sodium ion is 95. What is the ionic radius of chloride ion:(a) 190 pm  (b) 368 pm  (c) 181 pm  (d) 276 pm     <

    		•
  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

    		•
  • Q : Cations Chromium(III) hydroxide is

    Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer

    		•