--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

  • Q : Quastion of finding vapour pressure

    Vapour pressure of CCl425Degree C at is 143mm of Hg0.5gm of a non-volatile solute (mol. wt. = 65) is dissolved in 100ml CCl4 .Find the vapour pressure of the solution (Density of CCl4 = = 1.58g /cm2): (a)141.43mm (b)

  • Q : Various cons of eating the organic foods

    Describe the various cons of eating the organic foods? Briefly illustrate it.

  • Q : Strength of dilute acid of Sulfuric acid

    Select the right answer of the question.10ml of conc.H2SO4 (18 molar) is diluted to 1 litre. The approximate strength of dilute acid could be: (a)0.18 N (b)0.09 N (c) 0.36 N (d)1800 N

  • Q : Oxoacids of halogens Why oxidising

    Why oxidising character of oxoacids of halogens decreases as oxidation number increases?

  • Q : Theory of three dimensional motion

    Partition function; that the translational energy of 1 mol of molecules is 3/2 RT will come as no surprise. But the calculation of this result further illustrates the use of quantized states and the partition function to obtain macroscopic properties. The partition fu

  • Q : Extensive property Choose the right

    Choose the right answer from following. Which one of the following is an extensive property: (a) Molar volume (b) Molarity (c) Number of moles (d) Mole fraction

  • Q : Solutions The normality of 10 lit.

    The normality of 10 lit. volume hydrogen peroxide is: (a) 0.176 (b) 3.52 (c) 1.78 (d) 0.88 (e)17.8

  • Q : Cations Explain how dissolving the

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid.

  • Q : Mole fraction and Molality Select the

    Select the right answer of the following question.What does not change on changing temperature : (a) Mole fraction (b) Normality (c) Molality (d) None of these