--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : How haloalkanes are prepared from

    This is the common method for preparing haloalkanes in laboratory. Alcohols can be converted to haloalkanes by substitution of - OH group with a halogen atom. Different reagents can be used to get haloa

    		•
  • Q : Problem on bubble point The following

    The following mixture of hydrocarbons is obtained as one stream in a petroleum refinery.

    Q : What are heterogenous catalysis? Give

    When the catalyst exists in a different phase than that of reactants, it is said to be heterogeneous catalyst, and the catalysis is called heterogeneous catalysis. For example, SO2 can be oxidized to SO3

    		•
  • Q : Tetrahedral holes In zinc blende

    In zinc blende structure, zinc atom fill up:(a) All octahedral holes  (b) All tetrahedral holes  (c) Half number of octahedral holes  (d) Half number of tetrahedral holesAnswer: (d) In zinc blende (ZnS

    		•
  • Q : Particles of quartz Particles of quartz

    Particles of quartz are packed by:(i) Electrical attraction forces  (ii) Vander Waal's forces  (iii) Covalent bond forces  (iv) Strong electrostatic force of attraction Answer: (iii)

    		•
  • Q : Application of colligative properties

    Choose the right answer from following. Colligative properties are used for the determination of: (a) Molar Mass (b) Equivalent weight (c) Arrangement of molecules (d) Melting point and boiling point (d) Both (a) and (b)  

    		•
  • Q : Symmetry Elements The symmetry of the

    The symmetry of the molecules can be described in terms of electrons of symmetry and the corresponding symmetry operations.Clearly some molecules, like H2O and CH4, are symmetric. Now w

    		•
  • Q : Neutralization of sodium hydroxide How

    How much of NaOH is needed to neutralise 1500 cm3 of 0.1N HCl (given = At. wt. of Na =23): (i) 4 g  (ii) 6 g (iii) 40 g  (iv) 60 g

    		•
  • Q : Cons of eating organic foods Illustrate

    Illustrate the cons of eating organic foods?

    		•
  • Q : What do you mean by the term tripod

    What do you mean by the term tripod? Also state its uses?

    		•