--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Metallic chemistry why transation

    why transation metals show charaterstic colours to the flame?

    		•
  • Q : Linde liquefaction process Liquefied

    Liquefied natural gas (LNG) is produced using a Linde liquefaction process from pure methane gas at 3 bar and 280 K (conditions at point 1 in figure below). A three-stage compressor with interceding is used to compress the methane to 100 bar (point 2). The first stage

    		•
  • Q : Short note on the function of

    Write down a short note on the function of mitochondria?

    		•
  • Q : Some basic concepts of chemistry an

    an atom of an element is 10.1 times heavier than the mass of a carbon atom.What is its mass in amu?

    		•
  • Q : PH of an Alkyl Halide Briefly state the

    Briefly state the pH of an Alkyl Halide?

    		•
  • Q : Problem on molality Select the right

    Select the right answer of the question. Calculate the molality of 1 litre solution of 93% H2SO4 (weight/volume). The density of the solution is 1.84 g /ml : (a) 10.43 (b) 20.36 (c) 12.05 (d) 14.05

    		•
  • Q : Molar mass of compound The freezing

    The freezing point of a solution having 4.8 g of a compound in 60 g of benzene is 4.48. Determine the molar mass of the compound (Kf = 5.1 Km-1) , (freezing point of  benzene = 5.5oC)          &n

    		•
  • Q : From where the tin is obtained From

    From where the tin is obtained? Briefly illustrate it.

    		•
  • Q : Iso-electronic species Which ion has

    Which ion has the lowest radius from the following ions(a) Na+  (b) Mg2+  (c) Al3+  (d) Si4+ Answer: (d) All are the iso-electronic species but Si

    		•
  • Q : Relationship between free energy and

    The free energy of a gas depends on the pressure that confines the gas. The standard free energies of formation, like those allow predictions to be made of the possibility of a reaction at 25°C for each reagent at 

    		•