--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Relative lowering of vapour pressure

    Which of the following solutions will have a lower vapour pressure and why? a) A 5% aqueous solution of cane sugar. b) A 5% aqueous solution of urea.

    		•
  • Q : Determining highest normality What is

    What is the correct answer. Which of the given solutions contains highest normality: (i) 8 gm of KOH/litre (ii) N phosphoric acid (iii) 6 gm of NaOH /100 ml (iv) 0.5M H2SO4

    		•
  • Q : Volumes of solution after concentration

    Hydrochloric acid solution A and B encompass concentration of 0.5N and 0.1N  corresspondingly. The volumes of solutions A and B needed to make 2liters of 0.2N of HCL are: (i) 0.5l of A + 1.5l of B (ii) 1.5l of A + 0.5 l of B  (iii) 1.0 l of A + 1.0l of B&nbs

    		•
  • Q : Chemists have not created a periodic

    Explain the reason behind that the chemists have not created a periodic table of compounds?

    		•
  • Q : Donnan Membrane Equilibria The electric

    The electric charge acquired by macromolecules affects the equilibrium set up across a semipermeable membrane.Laboratory studies of macromolecule solutions as in osmotic pressure and dialysis studies confine the macromolecules to one compartment while allo

    		•
  • Q : Solubility are halides are halogens

    are halides are halogens more soluble? why?

    		•
  • Q : Decinormal concentration of Sulfuric

    Give me answer of this question. The volume of water to be added to 100cm3 of 0.5 N N H2SO4 to get decinormal concentration is : (a) 400 cm3 (b) 500cm3 (c) 450cm3 (d)100cm3

    		•
  • Q : How molecule-molecule collisions takes

    An extension of the kinetic molecular theory of gases recognizes that molecules have an appreciable size and deals with molecule-molecule collisions. We begin studies of elementary reactions by investigating the collisions b

    		•
  • Q : Molecular Diameters The excluded volume

    The excluded volume b, introduced by vander Wall's as an empirical correction term, can be related to the size gas molecules. To do so, we assume the excluded volume is the result of the pairwise coming together of molecules. This assumption is justified when b values

    		•
  • Q : Facts on evaporation Illustrate the 3

    Illustrate the 3 facts on evaporation?

    		•