--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Entropy on molecular basis. The

    The equation S = k in W relates entropy to W, a measure of the number of different molecular level arrangements of the system.In the preceding developments it was unnecessary to attempt to reach any "explana

  • Q : Problem on convection coefficient An

    An experiment to determine the convection coefficient associated with airflow over the surface of a thick stainless steel casting involves insertion of thermocouples in the casting at distances of 10 mm and 20 mm from the surface.  When the experiment was perform

  • Q : Molarity of acid solution If 20ml of

    If 20ml of 0.4N, NaoH solution completely neutralises 40ml of a dibasic acid. The molarity of the acid solution is: (a) 0.1M (b) 0.2M  (c) 0.3M (d) 0.4M Choose the right answer fron above.

  • Q : What do you mean by the term medicine

    What do you mean by the term medicine dropper? Explain briefly?

  • Q : Thermodynamics 1 Lab Report I already

    I already did Materials and Methods section. I uploaded it with the instructions. Also, make sure to see Concept Questions and Thinking Ahead in the instructions that I uploaded. deadline is tomorow at 8 am

  • Q : Define the term oxidizing agent Briefly

    Briefly define the term oxidizing agent?

  • Q : Molar solution of sulphuric acid Choose

    Choose the right answer from following. The molar solution of sulphuric acid is equal to: (a) N solution (b) 2Nsolution (c) N/2solution (d) 3Nsolution

  • Q : Calculate molarity of a solution

    Provide solution of this question. Molarity of a solution prepared by dissolving 75.5 g of pure KOH in 540 ml solution is: (a) 3.05 M (b) 1.35 M (c) 2.50 M (d) 4.50 M

  • Q : Concentration of an aqueous solution

    Give me answer of this question. The concentration of an aqueous solution of 0.01M CH3OH solution is very nearly equal to which of the following : (a) 0.01%CH3OH (b) 0.1%CH3OH (c) xCH3OH= 0.01 (d) 0.99MH2O (

  • Q : Acid Solutions Choose the right answer

    Choose the right answer from following. Volume of water needed to mix with 10 ml 10N NHO3 to get 0.1 N HNO3: (a) 1000 ml (b) 990 ml (c) 1010 ml (d) 10 ml