--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Problem related to molality Help me to

    Help me to solve this problem. What is the molality of a solution which contains 18 g of glucose (C6,H12, O6) in 250 g of water:  (a) 4.0 m (b) 0.4 m (c) 4.2 m (d) 0.8 m

  • Q : Mass percent Help me to go through this

    Help me to go through this problem. 10 grams of a solute is dissolved in 90 grams of a solvent. Its mass percent in solution is : (a) 0.01 (b) 11.1 (c)10 (d) 9

  • Q : What are condensation polymers? Give

    These types of polymers are formed as a result of condensation reaction between monomer units. Some common examples are being discussed here: 1. Polyesters 2047_condensat</span></p>
                                        </div>
                                        <!-- /comment-box -->
                                    </li>
   
   </td>
	</tr><tr>
		<td>
       
      <li>
                                        <div class=

    Q : What are Ethers and its types? Ethers

    Ethers are the compounds with general formula or CnH2n+

  • Q : Relative lowering of vapour pressure

    explain the process of relative lowering of vapour pressure

  • Q : Describe Thermodynamics Properties The

    The free energy property leads to convenient expressions for the volume and pressure dependence of internal energy, enthalpy and the heat capacities.All the properties of a chemical system, a sample of a substance, or a mixture of substances have some fixe

  • Q : Define Bond Energies - Bond Charges

    Energy changes in some chemical reactions can be used to deduce the energies of chemical bonds. Our understanding of the molecular basis of thermodynamic properties is extended when we ask why the enthalpy change for a reaction is what it is. We deduce,

  • Q : Describe characteristics of halides and

    Halides characteristics

  • Q : Question 6 A student was analyzing an

    A student was analyzing an unknown containing only Group IV cations. When the unknown was treated with 3M (NH4)2CO3 solution, a white precipitate formed. Because the acetic acid bottle was empty, the student used 6M HCl to dissolve the precipitate. Following the procedure of this experiment, the stu

  • Q : Raoults law Give me answer of this

    Give me answer of this question. Provide solution of this question. Which one of the following is the expression of Raoult's law: (a) P-P1/P = n/n+N (b) P1-P/P = N/ N+n (c)P-P2/P1= N/ N-n (d) P1-P/P2= N-n/N