--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : What is electrolysis? Explain with

    Passage of a current through a solution can produce an electrolysis reaction.Much additional information on the properties of the ions in an aqueous solution can be obtained from studies of the passage of a direct current (dc) through a cell containing a s

  • Q : What are aliphatic amines and its

    In common system, the aliphatic amines are named by using prefix for alkyl group followed by the word amine.In case of mixed amines, the name of alkyl groups are arranged in alphabetical order. This is followed by the word amine. However, for simple secondary or tertiary amines anothe

  • Q : Facts on evaporation Illustrate the 3

    Illustrate the 3 facts on evaporation?

  • Q : Problem on Adiabatic expansion

    Calculate the change in entropy for the system for each of the following cases. Explain the sign that you obtain by a physical argument a) A gas undergoes a reversible, adiabatic expansion from an initial state at 500 K, 1 MPa, and

  • Q : Vapour pressure over mercury Choose the

    Choose the right answer from following. At 300 K, when a solute is added to a solvent its vapour pressure over the mercury reduces from 50 mm to 45 mm. The value of mole fraction of solute will be: (a)0.005 (b)0.010 (c)0.100 (d)0.900

  • Q : Molecular crystals Among the below

    Among the below shown which crystal will be soft and have low melting point: (a) Covalent  (b) Ionic  (c) Metallic  (d) MolecularAnswer: (d) Molecular crystals are soft and have low melting point.

  • Q : Question on colligative property Choose

    Choose the right answer from following. Which of the following is a colligative property: (a) Osmotic pressure (b) Boiling point (c) Vapour pressure (d) Freezing point

  • Q : Meaning of Molar solution Molar

    Molar solution signifies 1 mole of solute present/existed in: (i) 1000g of solvent (ii) 1 litre of solvent (iii) 1 litre of solution (iv) 1000g of solution

  • Q : How to establish nomenclature for

    In the common chemistry terminologies, aliphatic halogen derivatives are named as alkyl halides. The words, n-, sec-, tert-, iso-, neo-, and amyl are

  • Q : Molarity of acid solution If 20ml of

    If 20ml of 0.4N, NaoH solution completely neutralises 40ml of a dibasic acid. The molarity of the acid solution is: (a) 0.1M (b) 0.2M  (c) 0.3M (d) 0.4M Choose the right answer fron above.