--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Problem on physical and thermodynamic

    The shells of marine organisms contain calcium carbonate CaCO3, largely in a crystalline form known as calcite. There is a second crystalline form of calcium carbonate known as aragonite. Physical and thermodynamic properties of calcite and aragonite at 298

    		•
  • Q : Iso-electronic species Which ion has

    Which ion has the lowest radius from the following ions(a) Na+  (b) Mg2+  (c) Al3+  (d) Si4+ Answer: (d) All are the iso-electronic species but Si

    		•
  • Q : Question based on mole concept Help me

    Help me to solve this Question. The number of moles of SO2Cl2 in 13.5 gm is in is : (a) 0.1 (b) 0.2 (c) 0.3 (d) 0.4

    		•
  • Q : What is Distillation Separation by

    Separation by distillation can be described with a boiling point diagram. The important process of distillation can now be investigated. From the boiling point diagram one can see that if a small amount of vapour were removed from a liquid of composit

    		•
  • Q : What is covalent radii? Explain its

    Average covalent radii can be assigned on the basis of molecular structures. The accumulation of structural data by spectroscopic studies and both electron and x-ray diffraction studies allows one to investigate the possibili

    		•
  • Q : Real vapour pressure Choose the right

    Choose the right answer from following. The pressure under which liquid and vapour can coexist at equilibrium is called the : (a) Limiting vapour pressure (b) Real vapour pressure (c) Normal vapour pressure (d) Saturated vapour pressure

    		•
  • Q : P block bif3 is ionic while other

    bif3 is ionic while other trihalides are covalent in nature

    		•
  • Q : Amines arrange in decreasing order of

    arrange in decreasing order of basicity pi pyridine,pyridine,pyrrole, morphine

    		•
  • Q : Problem on Redlich-Kwong equation i)

    i) Welcome to Beaver Gas Co.! Your first task is to calculate the annual gross sales of our superpure-grade nitrogen and oxygen gases. a) The total gross sales of N2 is 30,000 units. Take the volume of the cylinder to be

    		•
  • Q : Solution density of water is 1g/mL.The

    density of water is 1g/mL.The concentration of water in mol/litre is

    		•