--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Finding Normality Can someone please

    Can someone please help me in getting through this problem. Concentrated H2SO4 has a density of 1.98 gm/ml and is 98% H2SO4 by weight. The normality is: (a) 2 N  (b) 19.8 N  (c) 39.6 N  (d) 98

  • Q : Molecular crystals Among the below

    Among the below shown which crystal will be soft and have low melting point: (a) Covalent  (b) Ionic  (c) Metallic  (d) MolecularAnswer: (d) Molecular crystals are soft and have low melting point.

  • Q : Explanation of oxygen family. Group 16

    Group 16 of periodic

  • Q : Diffusion Molecular View When the

    When the diffusion process is treated as the movement of particles through a solvent the diffusion coefficient can be related to the effective size of diffusing particles and the viscosity of the medium.To see how the experimental coefficients can be treat

  • Q : Normality how 0.5N HCL is prepared for

    how 0.5N HCL is prepared for 10 littre solution

  • Q : Chemists have not created a periodic

    Explain the reason behind that the chemists have not created a periodic table of compounds?

  • Q : What is adsorption and its examples. In

    In a liquid a solid substance a molecule present within the bulk of the substance is being attracted infirmly from all sides by the neighbouring molecules. Hence there is no bet force acting on the molecule or there are no unbalanced forces of the molecule. On the oth

  • Q : Chem Explain how dissolving the Group

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid.

  • Q : Equimolar solutions Select the right

    Select the right answer of the question. Equimolar solutions in the same solvent have : (a)Same boiling point but different freezing point (b) Same freezing point but different boiling poin (c)Same boiling and same freezing points (d) Different boiling and differe

  • Q : Problem on preparing of a solution Give

    Give me answer of this question. How many grams of CH3OH should be added to water to prepare 150 solution of@M CH3 OH: (a) 9.6 (b) 2.4 (c) 9.6x 103 (d) 2.4 x103