--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : How molecule-molecule collisions takes

    An extension of the kinetic molecular theory of gases recognizes that molecules have an appreciable size and deals with molecule-molecule collisions. We begin studies of elementary reactions by investigating the collisions b

    		•
  • Q : What is depression in freezing point?

    Freezing point of a substance is the temperature at which solid and liquid phases of the substance coexist. It is defined as the temperature at which its solid and liquid phases have the same vapour pressure. The freezing point o

    		•
  • Q : Infrared Adsorption The adsorption of

    The adsorption of infrared radiation by diatomic molecules increases the vibrational energy fo molecules and gives information about the force constant for the "spring" of the molecule.;The molecular motion that has the next larger energy level spacing aft

    		•
  • Q : How to calculate solutions molar

    The contribution of an electrolyte, or an ion electrolyte, is reported as the molar of a conductance. The definition of the molar conductance is based on the following conductivity cell in which the electrodes are 1 m apart and of sufficient area that th

    		•
  • Q : Problem based on mole concept Choose

    Choose the right answer from following. An aqueous solution of glucose is 10% in strength. The volume in which mole of it is dissolved will be : (a) 18 litre (b) 9 litre (c) 0.9 litre (d) 1.8 litre

    		•
  • Q : Reducible Representations The number of

    The number of times each irreducible representation occurs in a reducible representation can be calculated.Consider the C2v point group as described or Appendix C. you can see that (1) sum of

    		•
  • Q : Reason for medications contain hcl What

    What is the reason behind this that some medications contain hcl?

    		•
  • Q : Molarity of Sulfuric acid Choose the

    Choose the right answer from following. What is the molarity of H2SO4 solution, that has a density 1.84 gm/cc at 35c and contains solute 98% by weight: (a) 4.18 M (b) 8.14 M (c)18.4 M (d)18 M

    		•
  • Q : Question on Mole fraction Mole fraction

    Mole fraction of any solution is equavalent to: (a) No. of moles of solute/ volume of solution in litter (b) no. of gram equivalent of solute/volume of solution in litters (c) no. of  moles of solute/ Mass of solvent in kg (d) no. of moles of any

    		•
  • Q : What are diazonium salts? The diazonium

    The diazonium salts are represented by the general formula ArN2 +X where X- ion may be anion such as (Cl) ¨, B ¨r, HSO

    		•