--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Chemists have not created a periodic

    Explain the reason behind that the chemists have not created a periodic table of compounds?

    		•
  • Q : Mole 2.0gram of dolomite is heated to a

    2.0gram of dolomite is heated to a constant weight of 1.0g. Calculate the total volume of CO2 produced at STP by this reation

    		•
  • Q : Theory of one dimensional motion For

    For motion in one dimension, the distribution of the molecules over quantum states, speeds, and energies can be deduced.Here we show that the energy of a macroscopic gas sample can be described on the basis of our knowledge of the quantum states allowed to

    		•
  • Q : Statement of Henry law Determine the

    Determine the correct regarding Henry’s law: (1) The gas is in contact with the liquid must behave as an ideal gas (2) There must not be any chemical interaction among the gas and liquid (3) The pressure applied must be high (4) All of these.

    		•
  • Q : Problem on Molar solution Can someone

    Can someone please help me in getting through this problem. 2.0 molar solution is acquired, when 0.5 mole solute is dissolved in: (i) 250 ml solvent (ii) 250 g solvent (iii) 250 ml solution (iv) 1000 ml solvent

    		•
  • Q : Polyhalogen compounds introduction for

    introduction for polyhalogen compound

    		•
  • Q : Explain physical properties of

    . Boiling pointsThe boiling points of monohalogen derivatives of benzene, which are all liquids, follow the orderIodo > Bromo > ChloroThe boiling points of isomeric dihalobe

    		•
  • Q : Ionic radius of chloride ion The edge

    The edge length of the unit cell of Nacl crystal lattice is 552 pm. If ionic radius of sodium ion is 95. What is the ionic radius of chloride ion:(a) 190 pm  (b) 368 pm  (c) 181 pm  (d) 276 pm     <

    		•
  • Q : Net charge of a non-ionized atom

    Describe the net charge of a non-ionized atom?

    		•
  • Q : Describe the function of the

    Briefly describe the function of the monosaccharide?

    		•