--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Vitamines 7 enzyme cofactor what is the

    what is the relationship between vitamins and enzyme cofactors

  • Q : Non-ideal Gases Fugacity The fugacity

    The fugacity is a pressure like quantity that is used to treat the free energy of nonideal gases.Now we begin the steps that allow us to relate free energy changes to the equilibrium constant of real, nonideal gases. The thermodynamic reaction 

  • Q : Water under pressure problem-henry law

    Can someone help me in going through this problem. The statement “When 0.003 moles of a gas are dissolved in 900 gm of water under a pressure of 1 atm, 0.006 moles will be dissolved under the pressure of 2 atm", signfies: (a)

  • Q : Means of molal solution Choose the

    Choose the right answer from following. A molal solution is one that contains one mole of a solute in: (a) 1000 gm of the solvent (b) One litre of the solvent (c) One litre of the solution (d) 22.4 litres of the solution

  • Q : Latent heat of vaporization Normal

    Normal butane (C4H10) is stored as a compressed liquid at 90°C and 1400 kPa. In order to use the butane in a low-pressure gas-phase process, it is throttled to 150 kPa and passed through a vaporizer. The butane emerges from the vaporizer as a

  • Q : Question related to colligative

    The colligative properties of a solution depend on: (a) Nature of solute particles present in it (b) Nature of solvent used (c) Number of solute particles present in it (d) Number of moles of solvent only

  • Q : Base parachloroaniline is strong base

    parachloroaniline is strong base than paranitroaniline

  • Q : Explain reactions of carbonyl oxygen

    In these reaction oxygen atom of carbonyl group is replaced by either one divalent group or two monovalent groups. Reaction by ammonia derivatives: aldehydes and ketones react with a number of ammonia derivatives such as hydroxylaminem hydrazine, semicarbazide etc. in weak acidic medium.

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

  • Q : Describe various systems for

    Common system According to this system, the individual members are named according to alkyl groups att