--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Quantum Mechanical Operators The

    The quantum mechanical methods, illustrated previously by the Schrödinger equation, are extended by the use of operators. Or, w

    		•
  • Q : Calculation of concentration of the

    Choose the right answer from following. 200ml of a solution contains 5.85 dissolved sodium chloride. The concentration of the solution will be(Na= 23: cl = 35.5 ) (a) 1 molar (b) 2 molar (c) 0.5 molar (d) 0.25 molar

    		•
  • Q : Structure of a DNA molecule Elaborate

    Elaborate the structure of a DNA molecule?

    		•
  • Q : Vapour pressure of volatile substance

    Provide solution of this question. According to Raoult's law the relative lowering of vapour pressure of a solution of volatile substance is equal to: (a) Mole fraction of the solvent (b) Mole fraction of the solute (c) Weight percentage of a solute (d) Weight perc

    		•
  • Q : How reactive is Trimethylindium towards

    Illustrate the reason, how reactive is Trimethylindium towards oxygen and water?

    		•
  • Q : M ive me answer of this question. When

    ive me answer of this question. When mercuric iodide is added to the aqueous solution of potassium iodide, the: (a) Freezing point is raised (b) Freezing point is lowered (c) Freezing point does not change (d) Boiling point does not change

    		•
  • Q : Chem Silicon has three naturally

    Silicon has three naturally occurring isotopes. 28Si, mass = 27.976927; 29Si, mass = 28.976495; 30Si, mass = 29.973770 and 3.10% abundance. What is the abundance of 28Si?

    		•
  • Q : Significance of the organic chemistry

    Describe some of the significance of the organic chemistry in brief?

    		•
  • Q : Strength of Nacl in solution To 5.85gm

    To 5.85gm of Nacl one kg of water is added to prepare of solution. What is the strength of Nacl in this solution (mol. wt. of nacl = 58.5)? (a) 0.1 Normal (b) 0.1 Molal (c) 0.1 Molar (d) 0.1 FormalAnswer:

    		•
  • Q : Polyhalogen compounds we need 10

    we need 10 examples for the polyhalogen compounds....please help me....need it urgently...

    		•