--%>

Problem on relative volatility

In vapor-liquid equilibrium the relative volatility αij is defined to be the ratio of the separation or K factor for species i to that for species j, that is,

 αij = Ki/Kj = (yi/xi)/(yj/xj)

In approximate distillation column calculations, the relative volatility is sometimes assumed to be a constant (independent of composition, temperature, and pressure). Test this assumption for the ethanol-ethyl acetate system using the following data:

RT ln γi = 8.163 xj2 KJ/mol

lm PvapEOH = (-4728.98/T) + 13.4643

lm PvapEOH = (-3570.58/T) + 10.4575

   Related Questions in Chemistry

  • Q : Laws of Chemical Combination Laws of

    Laws of Chemical Combination- In order to understand the composition of the compounds, it is necessary to have a theory which accounts for both qualitative and quantitative observations during chem

  • Q : Formula of diesel Write a short note on

    Write a short note on the formula of diesel, petrol and also CNG?

  • Q : Mole fraction of water and ethanol Give

    Give me answer of this question. A solution contains 1 mole of water and 4 mole of ethanol. The mole fraction of water and ethanol will be: (a) 0.2 water + 0.8 ethanol (b) 0.4 water + 0.6 ethanol (c) 0.6 water + 0.8 ethanol (d) 0.8 water + 0.2 ethanol

  • Q : Mole fraction of solute The mole

    The mole fraction of the solute in 1 molal aqueous solution is: (a) 0.027 (b) 0.036 (c) 0.018 (d) 0.009What is the correct answer.

  • Q : How haloalkanes are prepared from

    Alkyl halides can be prepared from alkanes through substitution and from alkenes through addition of halogen acids or through allylic substitution.    From alkanesWhen alkanes are treated with halogens, chlo

  • Q : Help 1) Chromium(III) hydroxide is

    1) Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer. 2) Explain how dissolving t

  • Q : What is Elevation in boiling point? The

    The boiling of a liquid may be defused by the temperature at which its vapour pressure which is equal to atmospheric pressure. The effect of addition in a non-volatile solute on the boiling point shown and its solution containing non-volatile solute with tempe

  • Q : Problem on Adiabatic expansion

    Calculate the change in entropy for the system for each of the following cases. Explain the sign that you obtain by a physical argument a) A gas undergoes a reversible, adiabatic expansion from an initial state at 500 K, 1 MPa, and

  • Q : Volume of solution containing solute

    What volume of solution contains 0.1 mole of the solute: (a) 100ml (b) 125ml  (c) 500ml (d) 62.5ml Choose the right answer from above.

  • Q : Calculating total number of moles

    Choose the right answer from following. While 90 gm of water is mixed with 300 gm of acetic acid. The total number of moles will be: (a)5 (b)10 (c)15 (d)20