--%>
Assignment Help - homework help

Problem on relative volatility

In vapor-liquid equilibrium the relative volatility αij is defined to be the ratio of the separation or K factor for species i to that for species j, that is,

 αij = Ki/Kj = (yi/xi)/(yj/xj)

In approximate distillation column calculations, the relative volatility is sometimes assumed to be a constant (independent of composition, temperature, and pressure). Test this assumption for the ethanol-ethyl acetate system using the following data:

RT ln γi = 8.163 xj2 KJ/mol

lm PvapEOH = (-4728.98/T) + 13.4643

lm PvapEOH = (-3570.58/T) + 10.4575

   Related Questions in Chemistry

  • Q : Strength of Nacl in solution To 5.85gm

    To 5.85gm of Nacl one kg of water is added to prepare of solution. What is the strength of Nacl in this solution (mol. wt. of nacl = 58.5)? (a) 0.1 Normal (b) 0.1 Molal (c) 0.1 Molar (d) 0.1 FormalAnswer:

    		•
  • Q : From where the tin is obtained From

    From where the tin is obtained? Briefly illustrate it.

    		•
  • Q : Mole fraction Give me answer of

    Give me answer of following question. The sum of the mole fraction of the components of a solution is : (a) 0 (b) 1 (c) 2 (d) 4.

    		•
  • Q : Group Cations Explain how dissolving

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid, establishes a buffer with a pH of approximately

    		•
  • Q : Problem based on lowering in vapour

    Help me to solve this problem. An aqueous solution of glucose was prepared by dissolving 18 g of glucose in 90 g of water. The relative lowering in vapour pressure is: (a) 0.02 (b)1 (c) 20 (d)180

    		•
  • Q : Explain reactions of carbonyl oxygen

    In these reaction oxygen atom of carbonyl group is replaced by either one divalent group or two monovalent groups. Reaction by ammonia derivatives: aldehydes and ketones react with a number of ammonia derivatives such as hydroxylaminem hydrazine, semicarbazide etc. in weak acidic medium.

    		•
  • Q : Problem on thermodynamic equilibrium In

    In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst: The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410&d

    		•
  • Q : Symmetry Elements The symmetry of the

    The symmetry of the molecules can be described in terms of electrons of symmetry and the corresponding symmetry operations.Clearly some molecules, like H2O and CH4, are symmetric. Now w

    		•
  • Q : Mole fraction of water Give me answer

    Give me answer of this question. A solution contains 25%H2O 25%C2H5OH , and 50% CH3 COOH by mass. The mole fraction of H2O would be: (a) 0.25 (b) 2.5 (c) 0.503 (d) 5.03.

    		•
  • Q : Problem on melting of ice A) It has

    A) It has been suggested that the surface melting of ice plays a role in enabling speed skaters to achieve peak performance. Carry out the following calculation to test this hypothesis. Suppose that the width of the skate in contact with the ice has been reduced by sh

    		•