--%>
Assignment Help - homework help

Problem on relative volatility

In vapor-liquid equilibrium the relative volatility αij is defined to be the ratio of the separation or K factor for species i to that for species j, that is,

 αij = Ki/Kj = (yi/xi)/(yj/xj)

In approximate distillation column calculations, the relative volatility is sometimes assumed to be a constant (independent of composition, temperature, and pressure). Test this assumption for the ethanol-ethyl acetate system using the following data:

RT ln γi = 8.163 xj2 KJ/mol

lm PvapEOH = (-4728.98/T) + 13.4643

lm PvapEOH = (-3570.58/T) + 10.4575

   Related Questions in Chemistry

  • Q : Problem on endothermic or exothermic At

    At low temperatures, mixtures of water and methane can form a hydrate (i.e. a solid containing trapped methane). Hydrates are potentially a very large source of underground trapped methane in the pole regions but are a nuisance when they form in pipelines and block th

    		•
  • Q : Vander Waals forces Wax is an example

    Wax is an example of: (a) Ionic crystal  (b) Covalent crystal  (c) Metallic crystal  (d) Molecular crystalAnswer: (d) Iodine crystals are molecular crystals, in which constituent particles are molecules having inter particle

    		•
  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

    		•
  • Q : Freezing point of equimolal aqueous

    The freezing point of equi-molal aqueous solution will be maximum for:            (a) C6H5NH3+Cl-(aniline hydrochloride)  (b) Ca(NO3

    		•
  • Q : Molarity of cane sugar solution 171 g

    171 g of cane sugar (C12H22O11)  is dissolved in one litre of water. Find the molarity of the solution: (i) 2.0 M (ii) 1.0 M (iii) 0.5 M (iv) 0.25 M Choose the right answer from above.

    		•
  • Q : State octet rule in chemistry Explain

    Explain what is octet rule in chemistry?

    		•
  • Q : Lowering of vapour pressure Help me to

    Help me to go through this problem. Lowering of vapour pressure is highest for: (a) urea (b) 0.1 M glucose (c) 0.1M MgSo4 (d) 0.1M BaCl2

    		•
  • Q : Thermodynamics 1 Lab Report I already

    I already did Materials and Methods section. I uploaded it with the instructions. Also, make sure to see Concept Questions and Thinking Ahead in the instructions that I uploaded. deadline is tomorow at 8 am here is the link to download all instructions because I couldn't attach all of t

    		•
  • Q : What is laser and explain its working?

    Laser action relies on a non-Boltzmann population inversion formed by the absorption of radiation and vibrational deactivation that forms a long lived excited electronic state. An excited state molecule can move to a lower energy state or return to the

    		•
  • Q : Explain the catalyst definition and

    Catalyst is a substance which accelerates the rate of a chemical reaction without undergoing any change in its chemical composition or mass during the reaction. The phenomenon of increasing the rate of a reaction with the help of a catalyst is known as catalysis.

    		•