--%>
Assignment Help - homework help

Problem on empirical van Laar equation

At atmospheric pressure ethyl acetate and ethyl alcohol form an azeotropic mixture containing 53.9% mole of ethyl acetate and boiling at 71.8°C.

a) Estimate the values of A & B in the empirical van Laar equation

log10 γ1 = A/[1+ (Ax1/Bx2)2]

log10 γ1 = B/[1+ (Bx2/Ax1)2]

b) If A & B are constant, calculate the azeotropic composition and the corresponding total pressure for boiling at 56.3°C.

Data: Vapour pressures of pure components (in mmHg):

                             71.8°C     56.3°C
Ethyl Alcohol           587          298
Ethyl Acetate           636          360

   Related Questions in Chemical Engineering

  • Q : Draw a flow diagram and annotate the

    Cumene is produced by the vapour phase reaction of benzene with propylene. The fresh feeds have the following compositions: Benzene: 99% w/w benzene, 1% w/w toluene Propylene: 98% v/v propylene,

    		•
  • Q : Problem on frictional losses A stream

    A stream of propane is throttled from 4.298 bar and 450 K to 0.22 bar. This process is irreversible due to frictional losses at the nozzle. a. In words or equations, why are frictional losses irreversible?

    Q : Materials and energy balance you look

    you look up the specific gravity of 96% H2SO4 and find it is 1.858.calculate the weight

    		•
  • Q : Calculating adiabatic flame temperature

    Calculate the adiabatic flame temperature of acetylenes gas at a pressure of 1 bar under the following conditions. The reactants are initially at 298K. Assume that the acetylene reacts completely to form CO2 and H2O:

    Q : Problem on laboratory solution You are

    You are asked to make up a laboratory solution of 0.10 molar H2SO4 from concentrated (96%) H2SO4 at 56°F. The barometric pressure reads 750 mmHg. You look up the specific gravity of 96% H2SO4 and find it is listed at 1.858. Calculate: (a) th

    		•
  • Q : Calculate the pressure Calculate the

    Calculate the pressure at the bottom of a column of Ethanol 100 ft high using a pressure (force) balance in American Engineering Units.

    		•
  • Q : I need to solve the material and energy

    I need to solve the material and energy balance for the att.

    		•
  • Q : Calculating flow rate of nitrogen The

    The feed of an ammonia synthesis reactor is 25% (lbmole) nitrogen with the balance hydrogen. The flow rate is 3000 kg/h at 65°C and 95 bar. Calculate the flow rate of nitrogen to the reactor in kg/hr.

    		•
  • Q : Problem on ideal gas law A stream of

    A stream of steam at 1 bar and 400 K enters a compressor through a pipe with cross-sectional area of 0.1 m2 at a velocity of 5 m/s. The pressure of the outlet stream is at 5 bar, temperature is at 500 K, and velocity is 1 m/s. Assume the steam can be descri

    		•
  • Q : Problem on steam flow in a pipe A

    A stream of steam at 15 bar and 300 oC is used to produce work using a steam turbine. a. Before the turbine, steam flows in a pipe (4 cm in diameter) at a mass flow rate of 3 g/s. Calculate the mean velocity in the pipe

    		•