--%>
Assignment Help - homework help

Problem on empirical van Laar equation

At atmospheric pressure ethyl acetate and ethyl alcohol form an azeotropic mixture containing 53.9% mole of ethyl acetate and boiling at 71.8°C.

a) Estimate the values of A & B in the empirical van Laar equation

log10 γ1 = A/[1+ (Ax1/Bx2)2]

log10 γ1 = B/[1+ (Bx2/Ax1)2]

b) If A & B are constant, calculate the azeotropic composition and the corresponding total pressure for boiling at 56.3°C.

Data: Vapour pressures of pure components (in mmHg):

                             71.8°C     56.3°C
Ethyl Alcohol           587          298
Ethyl Acetate           636          360

   Related Questions in Chemical Engineering

  • Q : I need to solve the material and energy

    I need to solve the material and energy balance for the att.

    		•
  • Q : Problem on laboratory solution You are

    You are asked to make up a laboratory solution of 0.10 molar H2SO4 from concentrated (96%) H2SO4 at 56°F. The barometric pressure reads 750 mmHg. You look up the specific gravity of 96% H2SO4 and find it is listed at 1.858. Calculate: (a) th

    		•
  • Q : Temprature To determine the temperature

    To determine the temperature that occurred in a ?re in a warehouse, the arson investigator noticed that the relief valve on a methane storage tank had popped open at 3000 psig, the rated value. Before the ?re started, the tank was presumably at ambient conditions and the gage read 1950 psig. If

    		•
  • Q : Problem on frictional losses A stream

    A stream of propane is throttled from 4.298 bar and 450 K to 0.22 bar. This process is irreversible due to frictional losses at the nozzle. a. In words or equations, why are frictional losses irreversible?

    Q : Problem on Clausius-Clapeyron equation

    The Clausius-Clapeyron equation gives us an expression for dP/dT. Now we will derive an analog to the Clausius-Clapeyron equation by obtaining an expression for dT/dµ when two phases are at equilibrium. For simplicity, let’s derive this fo

    		•
  • Q : Production of ethanol Ethanol (1)

    Ethanol (1) Describe the production of ethanol in Scottish Whisky beverages. Be sure to include a discussion on dangers of impurities (2) Explain the impact of ethanol on the human body (3) List th

    		•
  • Q : Chemical flow I) Sulphur dioxide (SO2)

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267+5

    		•
  • Q : Bsc what is the latent heat of

    what is the latent heat of vaporization for hexane

    		•
  • Q : Problem on ideal gas law A stream of

    A stream of steam at 1 bar and 400 K enters a compressor through a pipe with cross-sectional area of 0.1 m2 at a velocity of 5 m/s. The pressure of the outlet stream is at 5 bar, temperature is at 500 K, and velocity is 1 m/s. Assume the steam can be descri

    		•
  • Q : Draw a flow diagram and annotate the

    Cumene is produced by the vapour phase reaction of benzene with propylene. The fresh feeds have the following compositions: Benzene: 99% w/w benzene, 1% w/w toluene Propylene: 98% v/v propylene,

    		•