--%>
Assignment Help - homework help

Problem on empirical van Laar equation

At atmospheric pressure ethyl acetate and ethyl alcohol form an azeotropic mixture containing 53.9% mole of ethyl acetate and boiling at 71.8°C.

a) Estimate the values of A & B in the empirical van Laar equation

log10 γ1 = A/[1+ (Ax1/Bx2)2]

log10 γ1 = B/[1+ (Bx2/Ax1)2]

b) If A & B are constant, calculate the azeotropic composition and the corresponding total pressure for boiling at 56.3°C.

Data: Vapour pressures of pure components (in mmHg):

                             71.8°C     56.3°C
Ethyl Alcohol           587          298
Ethyl Acetate           636          360

   Related Questions in Chemical Engineering

  • Q : Matlab/Simulink assignment Modeling eye

    Modeling eye movements is commonly performed in the Matlab/Simulink pacakage. Based on the Physiological evidence, oculomotor plants have been designed to simulate various eye movements. Choose two eye movement models, one for saccades and the other for pursuit, and simulate the following amplitudes

    		•
  • Q : Calculating adiabatic flame temperature

    Calculate the adiabatic flame temperature of acetylenes gas at a pressure of 1 bar under the following conditions. The reactants are initially at 298K. Assume that the acetylene reacts completely to form CO2 and H2O:

    Q : Problem on weight fraction A gas

    A gas contains 350 ppm of H2S in CO2 at 72°F and 1.53 atm pressure. If the gas is liquified, what is the weight fraction H2S?

    		•
  • Q : Draw a flow diagram and annotate the

    Cumene is produced by the vapour phase reaction of benzene with propylene. The fresh feeds have the following compositions: Benzene: 99% w/w benzene, 1% w/w toluene Propylene: 98% v/v propylene,

    		•
  • Q : How to balance Chemical Reaction

    Consider a chemical reaction: a CH3-CH=CH2 + b NH3 + c O2 → d CH2=CH-C≡N + e H2O 1.  &

    		•
  • Q : Problem on heat of sublimation Using

    Using the vapor pressure data provided below, estimatei) the heat of sublimation of ice,ii) the heat of vaporization of water,iii) the heat of fusion of ice and compare your estimate with the published value of 6010 J/moLiv) the triple point of wate

    		•
  • Q : Chemical flow I) Sulphur dioxide (SO2)

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267+5

    		•
  • Q : Problem on ideal gas law A stream of

    A stream of steam at 1 bar and 400 K enters a compressor through a pipe with cross-sectional area of 0.1 m2 at a velocity of 5 m/s. The pressure of the outlet stream is at 5 bar, temperature is at 500 K, and velocity is 1 m/s. Assume the steam can be descri

    		•
  • Q : Mass transfer adsorption how to

    how to calculate amount of ammonia adsorbed per kg of adsobent in ammonia calcium chloride adsorption process?

    		•
  • Q : Thermodynamics I) Sulphur dioxide (SO2)

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267+5

    		•