--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : Acid Solutions Choose the right answer

    Choose the right answer from following. Volume of water needed to mix with 10 ml 10N NHO3 to get 0.1 N HNO3: (a) 1000 ml (b) 990 ml (c) 1010 ml (d) 10 ml

    		•
  • Q : What is Flash Photolysis Reactions.

    An example illustrates the type of mechanism that can be written to explain the development of flash photolysis reactions. Often, as the reactions in the ozone layer of the earth's atmosphere, we are interested in the kinetic behavior of species that are not a

    		•
  • Q : Meaning of molality of a solution The

    The molality of a solution will be: (i) Number of moles of solute per 1000 ml of solvent (ii) Number of moles of solute per 1000 gm of solvent (iii) Number of moles of solute per 1000 ml of solution (iv) Number of gram equivalents of solute per 1000 m

    		•
  • Q : Explain Ionic Bond with examples. The

    The bonding in ionic molecules can be described with a coulombic attractive term.For some diatomic molecules we take quite a different approach from that used in preceding sections to describe the bonding. Ionic bonds are interpreted in terms of the coulom

    		•
  • Q : Problem based on molecular weight

    Select the right answer of the question. Molecular weight of urea is 60. A solution of urea containing 6g urea in one litre is : (a)1 molar (b)1.5 molar (c) 0.1 molar (d) 0.01 molar

    		•
  • Q : Relative lowering in vapour pressure of

    Give me answer of this question. "Relative lowering in vapour pressure of solution containing non-volatile solute is directly proportional to mole fraction of solute". Above statement is: (a) Henry law (b) Dulong and Petit law (c) Raoult's law (d) Le-Chatelier's pri

    		•
  • Q : Explain physical properties of

    . Boiling pointsThe boiling points of monohalogen derivatives of benzene, which are all liquids, follow the orderIodo > Bromo > ChloroThe boiling points of isomeric dihalobe

    		•
  • Q : F-centres If a electron is present in

    If a electron is present in place of anion in a crystal lattice, then it is termed as: (a) Frenkel defect  (b) Schottky defect  (c) Interstitial defects (d) F-centre Answer: (d) When electrons are trapped in anion vacancies, thes

    		•
  • Q : Examples of reversible reaction

    Describe some examples of a reversible reaction?

    		•
  • Q : What is solvent dielectric effect?

    Ionic dissociation depends on the dielectric constant of the solvent.The Arrhenius that ions are in aqueous solutions in equilibrium with parent molecular species allows many of the properties of ionic solutions to be understood. But difficulties began to

    		•