--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : Explain the process of adsorption of

    The extent of adsorption of a gas on a solid adsorbent is affected by the following factors: 1. Nature of the gas Since physical adsorption is non-specific in nature, every gas will get adsorbed on the

    		•
  • Q : Question based on lowering of vapour

    Choose the right answer from following. The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000 g of water is 0.00713. The molecular weight of the substance will be:  (a) 18.0 (b) 342 (c) 60 (d) 180

    		•
  • Q : Molarity of cane sugar solution 171 g

    171 g of cane sugar (C12H22O11)  is dissolved in one litre of water. Find the molarity of the solution: (i) 2.0 M (ii) 1.0 M (iii) 0.5 M (iv) 0.25 M Choose the right answer from above.

    		•
  • Q : Biodegradable polymers what are the

    what are the examples of biodegradable polymers

    		•
  • Q : Vapour pressure of benzene Give me

    Give me answer of this question. The vapour pressure of benzene at a certain temperature is 640mm of Hg. A non-volatile and non-electrolyte solid weighing 2.175g is added to 39.08g of benzene. The vapour pressure of the solution is 600,mm of Hg . What is the mo

    		•
  • Q : Colligative property related question

    Select the right answer of the question. Which of the following is not a colligative property : (a) Osmotic pressure (b) Elevation in B.P (c) Vapour pressure (d) Depression in freezing point

    		•
  • Q : Calculating molarity of a solution

    Select the right answer of the question .The molarity of a 0.2 N N2Co3 solution will be: (a) 0.05 M (b) 0.2 M (c) 0.1 M (d)0.4 M

    		•
  • Q : Ddd 4) The addition of S2- ion to

    4) The addition of S2- ion to Fe(OH)2(s). Explain why the addition of S2- ion to Cr(OH)3(s) does not result in the formation of Cr2S3(s).

    		•
  • Q : Describe First Order Rate Equation The

    The integrated forms of the first order rate equations are conveniently used to compare concentration time results with this rate equation. Rate equations show the dependence of the rate of the reaction on concentration can be integrated to give expressions fo

    		•
  • Q : Mole fraction of hydrogen chloride

    Normal 0