--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : Importance of organic chemistry

    Describe the importance of organic chemistry?

    		•
  • Q : Thermodynamics I) Sulphur dioxide (SO2)

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267

    		•
  • Q : Describe the function of the

    Briefly describe the function of the monosaccharide?

    		•
  • Q : Explain polyhalogen compounds with

    Carbon compounds containing more than one halogen atom are called polyhalogen compounds. Most of these compounds are valuable in industry and agriculture. Some important polyhalogen compounds are described as follows:

    Q : Numerical The volume of water to be

    The volume of water to be added to 100cm3 of 0.5 N N H2SO4 to get decinormal concentration is : (a) 400 cm3 (b) 500cm3 (c) 450cm3 (d)100cm3

    		•
  • Q : Problem on physical and thermodynamic

    The shells of marine organisms contain calcium carbonate CaCO3, largely in a crystalline form known as calcite. There is a second crystalline form of calcium carbonate known as aragonite. Physical and thermodynamic properties of calcite and aragonite at 298

    		•
  • Q : Henry law question Answer the following

    Answer the following qustion. The definition “The mass of a gas dissolved in a particular mass of a solvent at any temperature is proportional to the pressure of gas over the solvent” is: (i) Dalton’s Law of Parti

    		•
  • Q : Normality how 0.5N HCL is prepared for

    how 0.5N HCL is prepared for 10 littre solution

    		•
  • Q : Basic concepts Determination of correct

    Determination of correct mol. Mass from Roult's law is applicable to :

    		•
  • Q : Ddd 4) The addition of S2- ion to

    4) The addition of S2- ion to Fe(OH)2(s). Explain why the addition of S2- ion to Cr(OH)3(s) does not result in the formation of Cr2S3(s).

    		•