--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : Molarity Give me answer of this

    Give me answer of this question. If 20ml of 0.4N, NaoH solution completely neutralises 40ml of a dibasic acid. The molarity of the acid solution is:(a) 0.1M (b) 0.2M (c)0.3M (d)0.4M

    		•
  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

    		•
  • Q : Death cap musrooms the death cap

    the death cap mushroom based on your knowledge of the biochemistry of dna and rna

    		•
  • Q : Problem on preparing of a solution Give

    Give me answer of this question. How many grams of CH3OH should be added to water to prepare 150 solution of@M CH3 OH: (a) 9.6 (b) 2.4 (c) 9.6x 103 (d) 2.4 x103

    		•
  • Q : How alkyl group reactions takes place?

    Halogenations: ethers react with chlorine and bromine to give substitution products. The extent of halogenations depends upon the conditions of reacti

    		•
  • Q : What is heat capacity and how to

    The temperature reliance of internal energy and enthalpy depends on the heat capacities at constant volume and constant pressure. The internal energy and enthalpy of chemical systems and the energy changes that accompany chemical reactions depend on the

    		•
  • Q : Calculation of molecular weight Provide

    Provide solution of this question. In an experiment, 1 g of a non-volatile solute was dissolved in 100 g of acetone (mol. mass = 58) at 298K. The vapour pressure of the solution was found to be 192.5 mm Hg. The molecular weight of the solute is (vapour pressure of ace

    		•
  • Q : Volume of solution containing solute

    What volume of solution contains 0.1 mole of the solute: (a) 100ml (b) 125ml  (c) 500ml (d) 62.5ml Choose the right answer from above.

    		•
  • Q : What is laser and explain its working?

    Laser action relies on a non-Boltzmann population inversion formed by the absorption of radiation and vibrational deactivation that forms a long lived excited electronic state. An excited state molecule can move to a lower energy state or return to the

    		•
  • Q : Polyhalogen compounds introduction for

    introduction for polyhalogen compound

    		•