--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : Calculating weight of acid Give me

    Give me answer of this question. The formula weight of H2SO4 is 98. The weight of the acid in 400mi of solution is: (a)2.45g (b) 3.92g (c) 4.90g (d) 9.8g

    		•
  • Q : Crystals of covalent compounds Crystals

    Crystals of the covalent compounds always contain:(i) Atoms as their structural units  (ii) Molecules as structural units  (iii) Ions held altogether by electrostatic forces (iv) High melting pointsAnswer: (i)

    		•
  • Q : Normality of acetic acid Give me answer

    Give me answer of this question. The normality of 10% (weight/volume) acetic acid is: (a)1 N (b)10 N (c)1.7 N (d) 0.83 N

    		•
  • Q : Tetrahedral holes In zinc blende

    In zinc blende structure, zinc atom fill up:(a) All octahedral holes  (b) All tetrahedral holes  (c) Half number of octahedral holes  (d) Half number of tetrahedral holesAnswer: (d) In zinc blende (ZnS

    		•
  • Q : Non-ideal Gases Fugacity The fugacity

    The fugacity is a pressure like quantity that is used to treat the free energy of nonideal gases.Now we begin the steps that allow us to relate free energy changes to the equilibrium constant of real, nonideal gases. The thermodynamic reaction 

    		•
  • Q : Entropy on molecular basis. The

    The equation S = k in W relates entropy to W, a measure of the number of different molecular level arrangements of the system.In the preceding developments it was unnecessary to attempt to reach any "explana

    		•
  • Q : Haloalkanes define primary secondary

    define primary secondary and tertiary alkyl halides with examples

    		•
  • Q : Calculating total number of moles

    Choose the right answer from following. While 90 gm of water is mixed with 300 gm of acetic acid. The total number of moles will be: (a)5 (b)10 (c)15 (d)20

    		•
  • Q : What are the chemical properties of

    Haloalkanes are extremely reactive category of aliphatic compounds. Their reactivity is due to the presence of polar carbon-halogen bond in their mole

    		•
  • Q : Theory of one dimensional motion For

    For motion in one dimension, the distribution of the molecules over quantum states, speeds, and energies can be deduced.Here we show that the energy of a macroscopic gas sample can be described on the basis of our knowledge of the quantum states allowed to

    		•