--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : Organic and inorganic chemistry Write

    Write down a short note on the differences between the organic and inorganic chemistry?

    		•
  • Q : Organic and inorganic substances living

    living beings are made up of organic and inorganic substances.according to their complexity of their molecules how can ach of these substances be classified?

    		•
  • Q : Molality of Sulfuric acid Choose the

    Choose the right answer from following. The molality of 90% H2SO4 solution is: [density=1.8 gm/ml]  (a)1.8 (b) 48.4 (c) 9.18 (d) 94.6

    		•
  • Q : Explain Second Order Rate Equations.

    Integration of the second order rate equations also produces convenient expressions for dealing with concentration time results.A reaction is classified as second order if the rate of the reaction is proportional to the square of the concentration of one o

    		•
  • Q : Question based on mole concept Help me

    Help me to solve this Question. The number of moles of SO2Cl2 in 13.5 gm is in is : (a) 0.1 (b) 0.2 (c) 0.3 (d) 0.4

    		•
  • Q : Problem on Osmotic Pressure of solution

    The osmotic pressure of a 5% solution of cane sugar at 150oC  is (mol. wt. of cane sugar = 342)(a) 4 atm (b) 3.4 atm (c) 5.07 atm (d) 2.45 atmAnswer: (c) Π = (5 x 0.0821 x 1000 x 423)/(342 x 100) = 5.07 atm

    		•
  • Q : Problem related to molarity Provide

    Provide solution of this question. Increasing the temperature of an aqueous solution will cause: (a) Decrease in molality (b) Decrease in molarity (c) Decrease in mole fraction (d) Decrease in % w/w

    		•
  • Q : Microwave Adsorption The absorption of

    The absorption of microwave radiation increases the rotational energy of molecules and gives information about the moment of inertia of the molecules.Now we can begin the study of the spectroscopy that explores the different ways in which the energy of the

    		•
  • Q : Electrochemistry ( electrolysis of

    1. Define Faraday's first law of electrolysis 2. define Faraday's second law of electrolysis

    		•
  • Q : Molar concentration Choose the right

    Choose the right answer from following. Molar concentration (M) of any solution : a) No. of moles of solute/Volume of solution in litre (b) No. of gram equivalent of solute / volume of solution in litre (c) No. of moles os solute/ Mass of solvent in kg  (

    		•