--%>

Problem on Clausius equation of state

If a gas can be described by the Clausius equation of state:

P (V-b) = RT

Where b is a constant, then:
 
(a) Obtain an expression for the residual volume.
 
(b) Obtain an expression for the residual enthalpy.
 
(c) Obtain an expression for the residual entropy.
 
(d) Calculate the enthalpy and entropy of the gas at 40 oC, 25 bar if b = 1 x 10-4 m3/mol. At 25 oC and 1 bar H and S = 0. For simplicity, let’s assume Cp = 35 J/mol/K and is constant.

   Related Questions in Chemistry

  • Q : Degree of dissociation The degree of

    The degree of dissociation of Ca(No3)2 in a dilute aqueous solution containing 14g of the salt per 200g of water 100oc is 70 percent. If the vapor pressure of water at 100oc is 760 cm. Calculate the vapor pr

  • Q : Number of electrons in the benzene

    Describe the number of electrons in the benzene? Write a short note on it?

  • Q : What is Spectroscopy? This is a very

    This is a very important aspect of Physical Chemistry in which knowledge of the size, shape, rigidity and electronic structure of molecules deduced from the experimental methods treated here goes hand in hand with the theoretical approaches of chemical reactions. Spec

  • Q : How to calculate solutions ionic

    Transference numbers and molar conductors can be used to calculate ionic mobilities. This tables under is giving the transference numbers for positive ions at 25 degree C and the values obtained by extrapolation to infinite dilution:

    Q : Problem on colligative properties

    Choose the right answer from following. The magnitude of colligative properties in all colloidal dispersions is : (a) Lowerthan solution (b)Higher than solution(c) Both (d) None

  • Q : Anti-aromatic and the non-aromatic

    What is main difference among anti-aromatic and the non-aromatic compounds?

  • Q : What is Henry law constant and its

    1. The units of Henry Law constant are same as those of pressure, i.e. torr or h bar. 2. Different gases have dissimilar values of Henry law constant. The values of KH for some gases in water are given in tabl

  • Q : Explain the molecular mass with respect

    During the formation of polymers, different macromolecules have different degree of polymerisation i.e. they have varied chain lengths. Thus, the molecular masses of the individual macromolecules in a particular sample of the polymer are different. Hence, an average value of the molecular mass is

  • Q : Modern periodic table and Mendeleevs

    Differentiate between the modern periodic table and Mendeleevs table?

  • Q : Relative lowering of the vapour pressure

    Choose the right answer from following.The relative lowering of the vapour pressure is equal to the ratio between the number of: (a) Solute moleules and solvent molecules (b) Solute molecules and the total molecules in the solution (c) Solvent molecules and the tota