--%>

Problem on Clausius equation of state

If a gas can be described by the Clausius equation of state:

P (V-b) = RT

Where b is a constant, then:
 
(a) Obtain an expression for the residual volume.
 
(b) Obtain an expression for the residual enthalpy.
 
(c) Obtain an expression for the residual entropy.
 
(d) Calculate the enthalpy and entropy of the gas at 40 oC, 25 bar if b = 1 x 10-4 m3/mol. At 25 oC and 1 bar H and S = 0. For simplicity, let’s assume Cp = 35 J/mol/K and is constant.

   Related Questions in Chemistry

  • Q : Which solution will have highest

    Which solution will have highest boiling point:(a) 1% solution of glucose in water  (b) 1% solution of sodium chloride in water  (c) 1% solution of zinc sulphate in water  (d) 1% solution of urea in waterAnswer: (b) Na

  • Q : Problem on vapor-liquid equilibrium Two

    Two tanks which contain water are connected to each other through a valve. The initial conditions are as shown (at equilibrium): 683_tank question.jpg

  • Q : Vapour pressure of methanol in water

    Give me answer of this question. An aqueous solution of methanol in water has vapour pressure: (a) Equal to that of water (b) Equal to that of methanol (c) More than that of water (d) Less than that of water

  • Q : Mass percent Help me to go through this

    Help me to go through this problem. 10 grams of a solute is dissolved in 90 grams of a solvent. Its mass percent in solution is : (a) 0.01 (b) 11.1 (c)10 (d) 9

  • Q : How molecule-molecule collisions takes

    An extension of the kinetic molecular theory of gases recognizes that molecules have an appreciable size and deals with molecule-molecule collisions. We begin studies of elementary reactions by investigating the collisions b

  • Q : What are the various types of drugs

    Drugs are broadly classified into following types depending on the purpose for which they are used. 1. Antipyretics

  • Q : Liquid Vapour Free Energies The free

    The free energy of a component of a liquid solution is equal to its free energy in the equilibrium vapour.Partial molal free energies let us deal with the free energy of the components of a solution. We use these free energies, or simpler concentration ter

  • Q : Molecular energies and speeds The

    The average translational kinetic energies and speeds of the molecules of a gas can be calculated.The result that the kinetic energy of 1 mol of the molecules of a gas is equal to 3/2 RT can be used to obtain numerical values for the

  • Q : Molal concentration Select the right

    Select the right answer of the question. If one mole of any substance is present in of solvent, then: (a) It shows molar concentration (b) It shows molal concentration (c) It shows normality (d) It shows strength.

  • Q : Relative lowering of vapour pressure

    explain the process of relative lowering of vapour pressure