--%>
Assignment Help - homework help

Problem on Clausius-Clapeyron equation

The Clausius-Clapeyron equation gives us an expression for dP/dT. Now we will derive an analog to the Clausius-Clapeyron equation by obtaining an expression for dT/dµ when two phases are at equilibrium. For simplicity, let’s derive this for vapor-liquid (V-L) equilibrium.

a. Write three conditions for V-L equilibrium.
 
b. Obtain an expression for dP in terms of dT and dµ.
 
c. Combine (some) of your results from part (a) and your result from part (b) to find an expression for dT/dµ in terms of T, ρL, ρV (ρ = N/V), SL/VL and SV/VV.

   Related Questions in Chemical Engineering

  • Q : Rate of flow of nitrogen The feed to an

    The feed to an ammonia synthesis reactor contain 25 mole% nitrogen and the balance hydrogen. The flow rate of the stream is 3000 kg/hr. Calculate the rate of flow of nitrogen into the reactor in kg/hr. (Hint: First calculate the average molecular weight of the mixture).

    		•
  • Q : Draw a flow diagram and annotate the

    Cumene is produced by the vapour phase reaction of benzene with propylene. The fresh feeds have the following compositions: Benzene: 99% w/w benzene, 1% w/w toluene Propylene: 98% v/v propylene,

    		•
  • Q : Problem on heat of sublimation Using

    Using the vapor pressure data provided below, estimatei) the heat of sublimation of ice,ii) the heat of vaporization of water,iii) the heat of fusion of ice and compare your estimate with the published value of 6010 J/moLiv) the triple point of wate

    		•
  • Q : Chemical flow I) Sulphur dioxide (SO2)

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267+5

    		•
  • Q : Problem on steam flow in a pipe A

    A stream of steam at 15 bar and 300 oC is used to produce work using a steam turbine. a. Before the turbine, steam flows in a pipe (4 cm in diameter) at a mass flow rate of 3 g/s. Calculate the mean velocity in the pipe

    		•
  • Q : Problem on molar flow rate I) Sulphur

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may as

    		•
  • Q : I need to solve the material and energy

    I need to solve the material and energy balance for the att.

    		•
  • Q : Hh to determine the temperature that

    to determine the temperature that occurred in a fire in a warehouse, the arson investigator noticed that the relief valve on a methane storage tank had popped open at 3000 psig, the rated value. Before the fire started, the tank was presumably at ambient conditions and the gage read 1950 psig. If th

    		•
  • Q : Problem on entropy A heater (heat

    A heater (heat source temperature = 527 K) and turbine are connected in series as shown below:

    Q : Problem on heat required for process A

    A steady-state flow process is used to heat methanol in a tank. The incoming stream is at 2 bar and 25 oC and has a flow rate of 5 kg/s. The outgoing stream is at 1 bar, 100 oC. Heating is provided by a heating coil immersed in a tank. Given the

    		•