Negative deviation
Which one of the following non-ideal solutions shows the negative deviation: (a) CH3COCH3 + CS2 (b) C6H6 + CH3COCH3 (c) CCl4 + CHCl3 (d) CH3COCH3 + CHCl3Answer: (d) CH3COCH3 + CHCl3 is non ideal solution which shows negative deviation.
In some two component, solid liquid systems, a solid compound forms.In systems in which the components have an interaction for such other, a solid state compound of the two compounds of the two components can form.Formic acid and formaide form a solid state, one-to-one com
Polyatomic molecules vibrate in a number of ways, and some of these vibrations can be studied by infrared absorption spectroscopy and some by Raman spectroscopy. The characters of transformation matrices for all 3n translation rotation vibration motio
The main objective of this particular aspect of Physical Chemistry is to examine the relation between free energies and the mechanical energy of electromotive force of electrochemical cells. The ionic components of aqueous solutions can be treated on the basis of the
Which one of the following pairs of solutions can we expect to be isotonic at the same temperature:(i) 0.1M Urea and 0.1M Nacl (ii) 0.1M Urea and 0.2M Mgcl2 (iii) 0.1M Nacl and 0.1M Na2SO4 (iv) 0.1M Ca(NO3<
Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer
Silicon has three naturally occurring isotopes. 28Si, mass = 27.976927; 29Si, mass = 28.976495; 30Si, mass = 29.973770 and 3.10% abundance. What is the abundance of 28Si?
Certain sols have the property of setting to a semi-solid, jelly-like form by enclosing the entire amount of liquid within itself when they are present at high concentrations. This process is called gelation and colloidal systems with jelly-like appearance are known as gels. Some common examples
In these reaction oxygen atom of carbonyl group is replaced by either one divalent group or two monovalent groups. Reaction by ammonia derivatives: aldehydes and ketones react with a number of ammonia derivatives such as hydroxylaminem hydrazine, semicarbazide etc. in weak acidic medium.
Superphosphate has the formulate: CaH4 (PO4)2 H2O calculate the percentage of Phosphorus in this chemical. Show your calculations
How much of NaOH is needed to neutralise 1500 cm3 of 0.1N HCl (given = At. wt. of Na =23): (i) 4 g (ii) 6 g (iii) 40 g (iv) 60 g
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