--%>

How to establish nomenclature for halides?

In the common chemistry terminologies, aliphatic halogen derivatives are named as alkyl halides. The words, n-, sec-, tert-, iso-, neo-, and amyl are usually used in written in the common names. In IUPAC system, they are considered as derivatives of corresponding alkanes and are named as haloalkanes. It may be noted that the common name of any alkyl halide is written as two separate words whereas the IUPAC name of the alkyl halide is written as one word.

The dihalogen derivatives having same type of halogen atoms on the same carbon are known as germinal dihalides and are assigned common name alkylidene halides or alkylidene dihalides.

The dihalogen derivatives having the two similar halogen atoms on adjacent carbon atoms are known as vicinal dihalides and are assigned common name alkylene or alkylene dihalides.

Trihalomethnanes are called haloforms in trivial system.

Fully halogenated hydrocarbons are known as perhalohydrocarbons. For example, C2Cl6 is known as percholoroethane.

Haloarenes are named by prefixing the halogen and its position, if necessary, to the name of the parent aromatic compound.

In writing the common names, the relative positions of the substituents at 1, 2-; 1, 3- and 1, 4- positions are indicated by prefixes ortho (o-), meta (m-) and para (p-), respectively. 

Isomerism in haloalkanes

Haloalkanes can exhibit the following kinds of isomerism:
    
Chain isomerism

The haloalkanes with four or more carbon atoms exhibit this kind of isomerism. For example,

1267_halides.png 
    
Position isomerism

The haloalkanes with three or more carbons show this kind of isomerism.

For example C3H7Br has two position isomers.

863_halides1.png

   Related Questions in Chemistry

  • Q : Volume hydrogen peroxide Choose the

    Choose the right answer from following. The normality of 10 lit. volume hydrogen peroxide is: (a) 0.176 (b) 3.52 (c) 1.78 (d) 0.88 (e)17.8

  • Q : Question based on normality Provide

    Provide solution of this question. A 5 molar solution of H2SO4 is diluted from 1 litre to 10 litres. What is the normality of the solution : (a) 0.25 N (b) 1 N (c) 2 N (d) 7 N

  • Q : Solubility of a gas The solubility of a

    The solubility of a gas in water depends on: (a) Nature of the gas (b) Temperature (c) Pressure of the gas (d) All of the above. Can someone help me in finding out the right answer.

  • Q : Number of moles present in water

    Provide solution of this question. How many moles of water are present in 180 of water: (a)1 mole (b)18 mole (c)10 mole (d)100 mole

  • Q : Calculation of molecular weight Provide

    Provide solution of this question. In an experiment, 1 g of a non-volatile solute was dissolved in 100 g of acetone (mol. mass = 58) at 298K. The vapour pressure of the solution was found to be 192.5 mm Hg. The molecular weight of the solute is (vapour pressure of ace

  • Q : Mass percent Help me to go through this

    Help me to go through this problem. 10 grams of a solute is dissolved in 90 grams of a solvent. Its mass percent in solution is : (a) 0.01 (b) 11.1 (c)10 (d) 9

  • Q : Problem on partial pressure i) Show

    i) Show that the equilibrium constant Kp for the reaction CaCo3(s) ↔ CaO(s) +CO2(g)is about unity (i.e. = 1.0) at 895 °C.ii) If two grams of calcium carbonate are pl

  • Q : Solubility are halides are halogens

    are halides are halogens more soluble? why?

  • Q : Explain the process of adsorption of

    The extent of adsorption of a gas on a solid adsorbent is affected by the following factors: 1. Nature of the gas Since physical adsorption is non-specific in nature, every gas will get adsorbed on the

  • Q : Equimolar solutions Select the right

    Select the right answer of the question. Equimolar solutions in the same solvent have : (a)Same boiling point but different freezing point (b) Same freezing point but different boiling poin (c)Same boiling and same freezing points (d) Different boiling and differe