--%>
Assignment Help - homework help

How alkyl group reactions takes place?

Halogenations: ethers react with chlorine and bromine to give substitution products. The extent of halogenations depends upon the conditions of reactions.

In dark, diethyl ether produces 1, 1'-dichloro diethyl ether
                                         
                                          
943_alkyl group.png 

In the presence of sunlight all the hydrogen's of ether are substituted by halogen atoms.

163_alkyl group1.png 
    
Peroxide formation: ethers in contact with air and light undergo oxidation to produce peroxides which hare unstable compounds and explode on heating.

Serious accidents are likely to occur if during distillation of old samples of ethers, peroxides are not removed.

374_alkyl group2.png 

Presence of peroxides in ethers can be detected by the addition of freshly prepared FeSO4 and KSCN. Appearance of red colour indicates peroxides. Ethers can be freed from peroxides by shaking with ferrous salt solution or distilling with concentrated H2SO4.

2133_alkyl group3.png

   Related Questions in Chemistry

  • Q : Problem on equilibrium composition The

    The catalytic dehydrogenation of 1-butene to 1,3-butadiene, C4H8(g) = C4H6(g)+H2(g) is carried out at 900 K and 1 atm.

    Q : Lab question Explain how dissolving the

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid, establishes a buffer with a pH of approximately 5.

    		•
  • Q : Can protein act as the buffer Can

    Can protein act as the buffer? Briefly comment on that statement.

    		•
  • Q : Molar and Volumetric flow rate problem

    Cyclohexane (C6H12) is produced by mixing Benzene and hydrogen. A process including a reactor, separator, and recycle stream is used to produce Cyclohexane. The fresh feed contains 260L/min C6H6 with 950 L/min of H2

    		•
  • Q : Describe First Order Rate Equation The

    The integrated forms of the first order rate equations are conveniently used to compare concentration time results with this rate equation. Rate equations show the dependence of the rate of the reaction on concentration can be integrated to give expressions fo

    		•
  • Q : Normality of solution containing

    Can someone please help me in getting through this problem. Determine the normality of a solution having 4.9 gm H3PO4 dissolved in 500 ml water: (a) 0.3  (b) 1.0  (c) 3.0   (d) 0.1

    		•
  • Q : Vapour pressure of methanol in water

    Give me answer of this question. An aqueous solution of methanol in water has vapour pressure: (a) Equal to that of water (b) Equal to that of methanol (c) More than that of water (d) Less than that of water

    		•
  • Q : Henry law question Answer the following

    Answer the following qustion. The definition “The mass of a gas dissolved in a particular mass of a solvent at any temperature is proportional to the pressure of gas over the solvent” is: (i) Dalton’s Law of Parti

    		•
  • Q : Concentration of urea Help me to go

    Help me to go through this problem. 6.02x 1020 molecules of urea are present in 100 ml of its solution. The concentration of urea solution is: (a) 0.02 M (b) 0.01 M (c) 0.001 M (d) 0.1 M (Avogadro constant, N4= 6.02x 1023mol -1)<

    		•
  • Q : Describe physical adsorption and its

    When the forces of attraction existing between adsorbate and adsorbent are van der Waal's forces, the adsorption is called physical adsorption. This type of adsorption is also known as physisorption or van der Waal's adsorption. Since the forces existing between adsorbent and adsorbate are very w

    		•