--%>

Explain the catalyst definition and process with examples.

Catalyst is a substance which accelerates the rate of a chemical reaction without undergoing any change in its chemical composition or mass during the reaction. The phenomenon of increasing the rate of a reaction with the help of a catalyst is known as catalysis.

For example, decomposition of potassium chlorate to give dioxygen occurs at high temperature in the range of 653 - 873 K
                                                      
2KClO3  2458_enzyme catalysis3.png  2KCl + 3O2

However, if a small amount of MnO2 is added to KClO3, its decomposition becomes faster and occurs at lower temperature range 473 - 633 K. the mass and chemical composition of MnO2 remains unaltered at the end of reaction. Thus, MnO2 acts as catalyst for the decomposition of KClO3.

Catalytic action

Since the catalysts are not consumed during the reaction, therefore, only a small amount of catalyst is sufficient to catalyse the reaction. According to modern views, a catalyst speeds up the reaction by providing an alternate path of lower activation energy to the reactants. The catalyst lowers the activation energy by interacting with the reactants leading to the formation of some intermediate complex of lower potential energy. In due course, the intermediate complex decomposes to give the products and also the catalyst.

Promotors and poisons

Promotors are the substances which enhance the activity of catalysts. For example, in the Hber's process for the manufacture of ammonia, molybdenum (Mo) is used as promoter which increases the activity of iron (Fe) used as catalyst
                                              
2218_catalysis.png  

Poisons are the substances which decrease the activity of catalyst. For example, during the Rosemnud's reaction involving the hydrogenation of acetyl chloride, Pd is used as catalyst while BaSO4/quinoline acts as poison. This activity of catalyst is purposely decreased to check the reduction of RCOCl to RCHO stage. If this is not done the desired compound RCHO will further undergo reduction to form alcohol RCH2OH.
                                           
1558_catalysis1.png

   Related Questions in Chemistry

  • Q : What do you mean by the term tripod

    What do you mean by the term tripod? Also state its uses?

  • Q : Problem on preparing of a solution Give

    Give me answer of this question. How many grams of CH3OH should be added to water to prepare 150 solution of@M CH3 OH: (a) 9.6 (b) 2.4 (c) 9.6x 103 (d) 2.4 x103

  • Q : Biodegradable polymers what are the

    what are the examples of biodegradable polymers

  • Q : Solution density of water is 1g/mL.The

    density of water is 1g/mL.The concentration of water in mol/litre is

  • Q : Explanation of oxygen family. Group 16

    Group 16 of periodic

  • Q : Explain Solid Compound Formation. In

    In some two component, solid liquid systems, a solid compound forms.In systems in which the components have an interaction for such other, a solid state compound of the two compounds of the two components can form.Formic acid and formaide form a solid state, one-to-one com

  • Q : Problem on thermodynamic equilibrium In

    In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst: The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410&d

  • Q : Relationship between Pressure and

    The pressure-temperature relation for solid-vapor or liquid vapor equilibrium is expressed by the Clausis-Clapeyron equation.We now obtain an expression for the pressure-temperature dependence of the state of equilibrium between two phases. To be specific,

  • Q : Means of molal solution Choose the

    Choose the right answer from following. A molal solution is one that contains one mole of a solute in: (a) 1000 gm of the solvent (b) One litre of the solvent (c) One litre of the solution (d) 22.4 litres of the solution

  • Q : Oxoacids of halogens Why oxidising

    Why oxidising character of oxoacids of halogens decreases as oxidation number increases?