--%>

Explain the catalyst definition and process with examples.

Catalyst is a substance which accelerates the rate of a chemical reaction without undergoing any change in its chemical composition or mass during the reaction. The phenomenon of increasing the rate of a reaction with the help of a catalyst is known as catalysis.

For example, decomposition of potassium chlorate to give dioxygen occurs at high temperature in the range of 653 - 873 K
                                                      
2KClO3  2458_enzyme catalysis3.png  2KCl + 3O2

However, if a small amount of MnO2 is added to KClO3, its decomposition becomes faster and occurs at lower temperature range 473 - 633 K. the mass and chemical composition of MnO2 remains unaltered at the end of reaction. Thus, MnO2 acts as catalyst for the decomposition of KClO3.

Catalytic action

Since the catalysts are not consumed during the reaction, therefore, only a small amount of catalyst is sufficient to catalyse the reaction. According to modern views, a catalyst speeds up the reaction by providing an alternate path of lower activation energy to the reactants. The catalyst lowers the activation energy by interacting with the reactants leading to the formation of some intermediate complex of lower potential energy. In due course, the intermediate complex decomposes to give the products and also the catalyst.

Promotors and poisons

Promotors are the substances which enhance the activity of catalysts. For example, in the Hber's process for the manufacture of ammonia, molybdenum (Mo) is used as promoter which increases the activity of iron (Fe) used as catalyst
                                              
2218_catalysis.png  

Poisons are the substances which decrease the activity of catalyst. For example, during the Rosemnud's reaction involving the hydrogenation of acetyl chloride, Pd is used as catalyst while BaSO4/quinoline acts as poison. This activity of catalyst is purposely decreased to check the reduction of RCOCl to RCHO stage. If this is not done the desired compound RCHO will further undergo reduction to form alcohol RCH2OH.
                                           
1558_catalysis1.png

   Related Questions in Chemistry

  • Q : What is Distillation Separation by

    Separation by distillation can be described with a boiling point diagram. The important process of distillation can now be investigated. From the boiling point diagram one can see that if a small amount of vapour were removed from a liquid of composit

  • Q : Explain Phase Rule The relation between

    The relation between the number of phases, components and the degrees of freedom is known as the phase rule. One constituent systems: the identification of an area on a P-versus-T with one phase of a component system illustrates the two degrees of freedom that

  • Q : Precipitation Addition of conc. HCl to

    Addition of conc. HCl to saturated Bacl2 solution precipitates Bacl2 ; because of the following reason : (a) It follows from Le Chatelier's principle (b) Of common-ion effect (c) Ionic product (Ba++)(cl) remains constant in a saturated sol

  • Q : Distribution law Help me to go through

    Help me to go through this problem. The distribution law is applied for the distribution of basic acid between : (a) Water and ethyl alcohol (b) Water and amyl alcohol (c) Water and sulphuric acid (d) Water and liquor ammonia

  • Q : Significance of the organic chemistry

    Describe some of the significance of the organic chemistry in brief?

  • Q : Cations Chromium(III) hydroxide is

    Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer

  • Q : Solution density of water is 1g/mL.The

    density of water is 1g/mL.The concentration of water in mol/litre is

  • Q : Problem on physical and thermodynamic

    The shells of marine organisms contain calcium carbonate CaCO3, largely in a crystalline form known as calcite. There is a second crystalline form of calcium carbonate known as aragonite. Physical and thermodynamic properties of calcite and aragonite at 298

  • Q : Chemists have not created a periodic

    Explain the reason behind that the chemists have not created a periodic table of compounds?

  • Q : Meaning of molality of a solution The

    The molality of a solution will be: (i) Number of moles of solute per 1000 ml of solvent (ii) Number of moles of solute per 1000 gm of solvent (iii) Number of moles of solute per 1000 ml of solution (iv) Number of gram equivalents of solute per 1000 m