--%>

Explain the catalyst definition and process with examples.

Catalyst is a substance which accelerates the rate of a chemical reaction without undergoing any change in its chemical composition or mass during the reaction. The phenomenon of increasing the rate of a reaction with the help of a catalyst is known as catalysis.

For example, decomposition of potassium chlorate to give dioxygen occurs at high temperature in the range of 653 - 873 K
                                                      
2KClO3  2458_enzyme catalysis3.png  2KCl + 3O2

However, if a small amount of MnO2 is added to KClO3, its decomposition becomes faster and occurs at lower temperature range 473 - 633 K. the mass and chemical composition of MnO2 remains unaltered at the end of reaction. Thus, MnO2 acts as catalyst for the decomposition of KClO3.

Catalytic action

Since the catalysts are not consumed during the reaction, therefore, only a small amount of catalyst is sufficient to catalyse the reaction. According to modern views, a catalyst speeds up the reaction by providing an alternate path of lower activation energy to the reactants. The catalyst lowers the activation energy by interacting with the reactants leading to the formation of some intermediate complex of lower potential energy. In due course, the intermediate complex decomposes to give the products and also the catalyst.

Promotors and poisons

Promotors are the substances which enhance the activity of catalysts. For example, in the Hber's process for the manufacture of ammonia, molybdenum (Mo) is used as promoter which increases the activity of iron (Fe) used as catalyst
                                              
2218_catalysis.png  

Poisons are the substances which decrease the activity of catalyst. For example, during the Rosemnud's reaction involving the hydrogenation of acetyl chloride, Pd is used as catalyst while BaSO4/quinoline acts as poison. This activity of catalyst is purposely decreased to check the reduction of RCOCl to RCHO stage. If this is not done the desired compound RCHO will further undergo reduction to form alcohol RCH2OH.
                                           
1558_catalysis1.png

   Related Questions in Chemistry

  • Q : Soluation of Ideal Gas Law problems

    Explain the method, how do you solve Ideal Gas Law problems?

  • Q : Negative deviation Which one of the

    Which one of the following non-ideal solutions shows the negative deviation: (a) CH3COCH3 + CS2   (b) C6H6 + CH3COCH3   (c) CCl4 + CHCl3  

  • Q : Molarity of sodium hydroxide Can

    Can someone please help me in getting through this problem. Determine the molarity of a solution having 5g of sodium hydroxide in 250ml  solution is: (i) 0.5  (ii) 1.0  (iii) 2.0   (d) 0.1Answer: The right answer i

  • Q : Preparation of ammonium sulphate Select

    Select the right answer of the question. Essential quantity of ammonium sulphate taken for preparation of 1 molar solution in 2 litres is: (a)132gm (b)264gm (c) 198gm (d) 212gm

  • Q : Gibberella fusarium in bioremediation

    in bioremediation gibberella fusarium is used to break down____?

  • Q : How to establish nomenclature for

    In the common chemistry terminologies, aliphatic halogen derivatives are named as alkyl halides. The words, n-, sec-, tert-, iso-, neo-, and amyl are

  • Q : Means of molal solution Choose the

    Choose the right answer from following. A molal solution is one that contains one mole of a solute in: (a) 1000 gm of the solvent (b) One litre of the solvent (c) One litre of the solution (d) 22.4 litres of the solution

  • Q : What is schrodinger wave equation? The

    The Schrodinger wave equation generalizes the fitting-in-of-waves procedure.The waves that "fit" into the region to which the particle is contained can be recognized "by inspection" only for a few simple systems. For other problem a mathematical procedure

  • Q : Problem on mol fraction of naphthalene

    At 20°C the solubility of solid naphthalene in hexane is 0.09 mol/mol of solution. Use this information and the data below to estimate the following for this system: a) The mol fraction of naphthalene in the vapour phase in equ

  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal