Explain preparation and properties of phosphorus trichloride
It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2 4OCl3 + 4SO2 + 2S2Cl2 Lab. Method: it is more conveniently prepared in the laboratory by heating white phosphorus in a current of dry chlorine when phosphorus trichloride distils over.P4 + 6Cl2 4PCl3Phosphorus is gently heated in a retort on a water bath and current dry chlorine is passed. Phosphorus trichloride distils over and is collected in a receiver cooled in freezing mixture.It is redistilled over white phosphorus to remove any phosphorus pentachloride present an impurity.Properties It is colourless fuming liquid. It reacts violently with water forming phosphorus acid.PCl3 + 3HOH H3PO3 + 3HCl It reacts with concentrated H2SO4 forming chlorosulphonic acid. Or, 2H2SO4 + PCl3 HSO3Cl + HPO3 + SO2 + HCl It reacts with organic compounds containing hydroxyl group. It directly combines with Cl2, O2 and S. this indicates that it is an unsaturated compound.PCl3 + Cl2 PCl52PCl3 + O2 2POCl3PCl3 + S PSCl3 It acts as a reducing agent.PCl3 + SO2Cl2 PCl5 + SO2PCL3 + SO3 POCL3 + SO23PCl3 + S2Cl2 PCL5 + 2PSCl3It reacts with finely divided metals when hot.12Ag + 4PCl3 12AgCl + P46Na + PCl3 3NaCl + Na2P
Can someone please help me in getting through this problem. The normality of a solution of sodium hydroxide 100 ml of which includes 4 grams of NaOH is: (a) 0.1 (b) 40 (c) 1.0 (d) 0.4
Give me answer of this question. A solution contains 1 mole of water and 4 mole of ethanol. The mole fraction of water and ethanol will be: (a) 0.2 water + 0.8 ethanol (b) 0.4 water + 0.6 ethanol (c) 0.6 water + 0.8 ethanol (d) 0.8 water + 0.2 ethanol
While a substance is dissolved in a solvent, the vapour pressure of the solvent is decreased. This results in: (a) An increase in the boiling point of the solution (b) A decrease in the boiling point of solvent (c) The solution having a higher freezing point than
Mole fraction of any solution is equavalent to: (a) No. of moles of solute/ volume of solution in litter (b) no. of gram equivalent of solute/volume of solution in litters (c) no. of moles of solute/ Mass of solvent in kg (d) no. of moles of any
Provide solution of this question. According to Raoult's law the relative lowering of vapour pressure of a solution of volatile substance is equal to: (a) Mole fraction of the solvent (b) Mole fraction of the solute (c) Weight percentage of a solute (d) Weight perc
Choose the right answer from following. Which one of the statements written below concerning properties of solutions, explain a colligative effect: (a) Boiling point of pure water decreases by the addition of ethano (b) Vapour pressure of pure water d
Write a short note on the IUPAC name of the benzene?
Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction: N2O4(g) ↔ 2 NO2(g)<
Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal
arrange in decreasing order of basicity pi pyridine,pyridine,pyrrole, morphine
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