Explain preparation and properties of phosphorus trichloride
It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2 4OCl3 + 4SO2 + 2S2Cl2 Lab. Method: it is more conveniently prepared in the laboratory by heating white phosphorus in a current of dry chlorine when phosphorus trichloride distils over.P4 + 6Cl2 4PCl3Phosphorus is gently heated in a retort on a water bath and current dry chlorine is passed. Phosphorus trichloride distils over and is collected in a receiver cooled in freezing mixture.It is redistilled over white phosphorus to remove any phosphorus pentachloride present an impurity.Properties It is colourless fuming liquid. It reacts violently with water forming phosphorus acid.PCl3 + 3HOH H3PO3 + 3HCl It reacts with concentrated H2SO4 forming chlorosulphonic acid. Or, 2H2SO4 + PCl3 HSO3Cl + HPO3 + SO2 + HCl It reacts with organic compounds containing hydroxyl group. It directly combines with Cl2, O2 and S. this indicates that it is an unsaturated compound.PCl3 + Cl2 PCl52PCl3 + O2 2POCl3PCl3 + S PSCl3 It acts as a reducing agent.PCl3 + SO2Cl2 PCl5 + SO2PCL3 + SO3 POCL3 + SO23PCl3 + S2Cl2 PCL5 + 2PSCl3It reacts with finely divided metals when hot.12Ag + 4PCl3 12AgCl + P46Na + PCl3 3NaCl + Na2P
The second law states that dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process. a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a r
Briefly state the wavelengths which the human eye can see?
Can someone please help me in getting through this problem. How many grams of dibasic acid (having mol. wt. 200) must be present in 100ml of its aqueous solution to provide decinormal strength: (i) 1g (ii)2g (iii) 10g (iv) 20g<
Give me answer of this question. How many grams of CH3OH should be added to water to prepare 150 solution of@M CH3 OH: (a) 9.6 (b) 2.4 (c) 9.6x 103 (d) 2.4 x103
Two tanks which contain water are connected to each other through a valve. The initial conditions are as shown (at equilibrium):
Integration of the second order rate equations also produces convenient expressions for dealing with concentration time results.A reaction is classified as second order if the rate of the reaction is proportional to the square of the concentration of one o
show how a mathematical definition of entropy can be obtauined from a consideration of carnot cycle?
What weight of hydrated oxalic acid should be added for complete neutralisation of 100 ml of 0.2N - NaOH solution? (a) 0.45 g (b)0.90 g (c) 1.08 g (d) 1.26 g Answer
Can someone please help me in getting through this problem. The normality of a solution of sodium hydroxide 100 ml of which includes 4 grams of NaOH is: (a) 0.1 (b) 40 (c) 1.0 (d) 0.4
Give me answer of this question. The concentration of an aqueous solution of 0.01M CH3OH solution is very nearly equal to which of the following : (a) 0.01%CH3OH (b) 0.1%CH3OH (c) xCH3OH= 0.01 (d) 0.99MH2O (
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