Explain preparation and properties of phosphorus trichloride
It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2 4OCl3 + 4SO2 + 2S2Cl2 Lab. Method: it is more conveniently prepared in the laboratory by heating white phosphorus in a current of dry chlorine when phosphorus trichloride distils over.P4 + 6Cl2 4PCl3Phosphorus is gently heated in a retort on a water bath and current dry chlorine is passed. Phosphorus trichloride distils over and is collected in a receiver cooled in freezing mixture.It is redistilled over white phosphorus to remove any phosphorus pentachloride present an impurity.Properties It is colourless fuming liquid. It reacts violently with water forming phosphorus acid.PCl3 + 3HOH H3PO3 + 3HCl It reacts with concentrated H2SO4 forming chlorosulphonic acid. Or, 2H2SO4 + PCl3 HSO3Cl + HPO3 + SO2 + HCl It reacts with organic compounds containing hydroxyl group. It directly combines with Cl2, O2 and S. this indicates that it is an unsaturated compound.PCl3 + Cl2 PCl52PCl3 + O2 2POCl3PCl3 + S PSCl3 It acts as a reducing agent.PCl3 + SO2Cl2 PCl5 + SO2PCL3 + SO3 POCL3 + SO23PCl3 + S2Cl2 PCL5 + 2PSCl3It reacts with finely divided metals when hot.12Ag + 4PCl3 12AgCl + P46Na + PCl3 3NaCl + Na2P
2.0gram of dolomite is heated to a constant weight of 1.0g. Calculate the total volume of CO2 produced at STP by this reation
What do you mean by the term enzymes? Briefly illustrate it.
20 g of hydrogen is present in 5 litre of vessel. Determine he molar concentration of hydrogen: (a) 4 (b) 1 (c) 3 (d) 2 Choose the right answer from above.
Explain what is octet rule in chemistry?
Aryl halides are much less reactive towards nucleophilic substitution reactions than haloalkanes. The less reactivity of aryl halides can be described
Can someone please help me in getting through this problem. 2.0 molar solution is acquired, when 0.5 mole solute is dissolved in: (i) 250 ml solvent (ii) 250 g solvent (iii) 250 ml solution (iv) 1000 ml solvent
Which one is polar HCl or HF?
why allyl halide and haloarenes are more reactive than alkyl halide towards nucleophilic substitution
The second law states that dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process. a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a r
Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction: N2O4(g) ↔ 2 NO2(g)<
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