Explain preparation and properties of phosphorus trichloride
It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2 4OCl3 + 4SO2 + 2S2Cl2 Lab. Method: it is more conveniently prepared in the laboratory by heating white phosphorus in a current of dry chlorine when phosphorus trichloride distils over.P4 + 6Cl2 4PCl3Phosphorus is gently heated in a retort on a water bath and current dry chlorine is passed. Phosphorus trichloride distils over and is collected in a receiver cooled in freezing mixture.It is redistilled over white phosphorus to remove any phosphorus pentachloride present an impurity.Properties It is colourless fuming liquid. It reacts violently with water forming phosphorus acid.PCl3 + 3HOH H3PO3 + 3HCl It reacts with concentrated H2SO4 forming chlorosulphonic acid. Or, 2H2SO4 + PCl3 HSO3Cl + HPO3 + SO2 + HCl It reacts with organic compounds containing hydroxyl group. It directly combines with Cl2, O2 and S. this indicates that it is an unsaturated compound.PCl3 + Cl2 PCl52PCl3 + O2 2POCl3PCl3 + S PSCl3 It acts as a reducing agent.PCl3 + SO2Cl2 PCl5 + SO2PCL3 + SO3 POCL3 + SO23PCl3 + S2Cl2 PCL5 + 2PSCl3It reacts with finely divided metals when hot.12Ag + 4PCl3 12AgCl + P46Na + PCl3 3NaCl + Na2P
When the forces of attraction existing between adsorbate and adsorbent are van der Waal's forces, the adsorption is called physical adsorption. This type of adsorption is also known as physisorption or van der Waal's adsorption. Since the forces existing between adsorbent and adsorbate are very w
Give me answer of this question. A solution contains 1.2046 x 1024 hydrochloric acid molecules in one dm3 of the solution. The strength of the solution is: (a) 6 N (b) 2 N (c) 4 N (d) 8 N
Give me answer of this question. The volume of water to be added to 100cm3 of 0.5 N N H2SO4 to get decinormal concentration is : (a) 400 cm3 (b) 500cm3 (c) 450cm3 (d)100cm3
Help me to go through this problem. 1000 gms aqueous solution of CaCO3 contains 10 gms of carbonate. Concentration of the solution is : (a)10 ppm (b)100 ppm (c)1000 ppm (d)10000 ppm
In vapor-liquid equilibrium the relative volatility αij is defined to be the ratio of the separation or K factor for species i to that for species j, that is, αij = Ki/Kj
Help me to solve this Question. The number of moles of SO2Cl2 in 13.5 gm is in is : (a) 0.1 (b) 0.2 (c) 0.3 (d) 0.4
Can someone please help me in getting through this problem. Concentrated H2SO4 has a density of 1.98 gm/ml and is 98% H2SO4 by weight. The normality is: (a) 2 N (b) 19.8 N (c) 39.6 N (d) 98
Provide solution of this question. Determination of correct molecular mass from Raoult's law is applicable to: (a) An electrolyte in solution (b) A non-electrolyte in a dilute solution (c) A non-electrolyte in a concentrated solution (d) An electrolyte in a liquid so
The molality of a solution will be: (i) Number of moles of solute per 1000 ml of solvent (ii) Number of moles of solute per 1000 gm of solvent (iii) Number of moles of solute per 1000 ml of solution (iv) Number of gram equivalents of solute per 1000 m
Can someone please help me in getting through this problem. Determine the normality of a solution having 4.9 gm H3PO4 dissolved in 500 ml water: (a) 0.3 (b) 1.0 (c) 3.0 (d) 0.1
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