--%>
Assignment Help - homework help

Explain physical properties of haloarenes.

. Boiling points

The boiling points of monohalogen derivatives of benzene, which are all liquids, follow the order

Iodo > Bromo > Chloro

The boiling points of isomeric dihalobenzenes are nearly the same. However, their melting points are fairly dissimilar. The melting point of para isomer is generally 70-100 degrees higher than the melting points of ortho and meta isomers. The higher melting point of para isomer is due to its symmetry which leads to more close packing of its molecules in the crystal lattice and consequently strong intermolecular attractive forces.

Boiling point:    453 K              446 K            448 K

Melting point:   256 K              249 K            323 K

2. Solubility

Haloarenes are insoluble in water, acids or bases but are soluble in organic solvents.

Haloarenes are insoluble in water because they cannot form hydrogen bonds with water molecules.

3. Density 

These are all heavier than water. Their densities follow the order given below.

Iodo > Bromo > Chloro

   Related Questions in Chemistry

  • Q : Benefits of soapy detergents over the

    What are the benefits of soapy detergents over the soap less detergents? Briefly state the benefits?

    		•
  • Q : Molecular weight of solute Select right

    Select right answer of the question. A dry air is passed through the solution, containing the 10 gm of solute and 90 gm of water and then it pass through pure water. There is the depression in weight of solution wt by 2.5 gm and in weight of pure solvent by 0.05 gm. C

    		•
  • Q : Explain Rotational Vibrational Spectra

    The infrared spectrum of gas samples shows the effect of rotational-energy changes along with the vibrational energy change.As we know from the interpretations given to thermodynamic properties of gases, gas molecules are simultaneously rotating and vibrating. It follows that an absor

    		•
  • Q : Solubility product On passing H 2 S gas

    On passing H2S gas through a particular solution of Cu+ and Zn+2 ions, first CuS is precipitated because : (a)Solubility product of CuS is equal to the ionic product of ZnS (b) Solubility product of CuS is equal to the solubility product

    		•
  • Q : Non-ideal Gases Fugacity The fugacity

    The fugacity is a pressure like quantity that is used to treat the free energy of nonideal gases.Now we begin the steps that allow us to relate free energy changes to the equilibrium constant of real, nonideal gases. The thermodynamic reaction 

    		•
  • Q : Problem on decinormal strength Can

    Can someone please help me in getting through this problem. How many grams of dibasic acid (having mol. wt. 200) must be present in 100ml  of its aqueous solution to provide decinormal strength: (i) 1g  (ii)2g  (iii) 10g  (iv) 20g<

    		•
  • Q : Strength of dilute acid of Sulfuric acid

    Select the right answer of the question.10ml of conc.H2SO4 (18 molar) is diluted to 1 litre. The approximate strength of dilute acid could be: (a)0.18 N (b)0.09 N (c) 0.36 N (d)1800 N

    		•
  • Q : Problems related to entropy change A)

    A) Two compartments each of 1 m3 capacity are joined by a valve and insulated from the surroundings and from one another. One compartment has saturated steam at 683.6 kPa and the other contains steam at the same temperature but at a pressure of 101.3 kPa. T

    		•
  • Q : Explain preparation and properties of

    It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2    4

    		•
  • Q : Molarity of cane sugar solution 171 g

    171 g of cane sugar (C12H22O11)  is dissolved in one litre of water. Find the molarity of the solution: (i) 2.0 M (ii) 1.0 M (iii) 0.5 M (iv) 0.25 M Choose the right answer from above.

    		•